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Cinnamic acid

Description Sources
Cinnamic acid
Cinnamic acid structure
CAS No.
119-84-6
Chemical Name:
Cinnamic acid
Synonyms
Tonkamel;FEMA 2381;MELILOTIN;MELILOTOL;usafdo-12;MELILOTINE;NCI-C55890;oxochroman;USAF do-12;AKOS 222-08
CBNumber:
CB4413174
Molecular Formula:
C9H8O2
Formula Weight:
148.16
MOL File:
119-84-6.mol

Cinnamic acid Properties

Melting point:
24-25 °C(lit.)
Boiling point:
272 °C(lit.)
Density 
1.169 g/mL at 25 °C(lit.)
refractive index 
n20/D 1.556(lit.)
FEMA 
2381 | DIHYDROCOUMARIN
Flash point:
>230 °F
storage temp. 
Store below +30°C.
Specific Gravity
1.169
Water Solubility 
insoluble
JECFA Number
1171
BRN 
4584
CAS DataBase Reference
119-84-6(CAS DataBase Reference)
NIST Chemistry Reference
2H-1-Benzopyran-2-one, 3,4-dihydro-(119-84-6)
EPA Substance Registry System
2H-1-Benzopyran- 2-one, 3,4-dihydro-(119-84-6)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  Xn
Risk Statements  22-36/37/38
Safety Statements  26-36
WGK Germany  3
RTECS  MW5775000
TSCA  Yes
HS Code  29322980
Hazardous Substances Data 119-84-6(Hazardous Substances Data)
Symbol(GHS):
Signal word: Warning
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H319 Causes serious eye irritation Serious eye damage/eye irritation Category 2A Warning P264, P280, P305+P351+P338,P337+P313P
H335 May cause respiratory irritation Specific target organ toxicity, single exposure;Respiratory tract irritation Category 3 Warning
Precautionary statements:
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.
P501 Dispose of contents/container to..…

Cinnamic acid price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich D104809 Dihydrocoumarin 99% 119-84-6 5g $28 2018-11-13 Buy
Sigma-Aldrich 07552 Dihydrocoumarin analytical standard 119-84-6 1ml $60.2 2018-11-13 Buy
TCI Chemical D1223 3,4-Dihydrocoumarin >98.0%(GC) 119-84-6 25g $19 2018-11-22 Buy
TCI Chemical D1223 3,4-Dihydrocoumarin >98.0%(GC) 119-84-6 500g $110 2018-11-22 Buy
Alfa Aesar B21229 Dihydrocoumarin, 99% 119-84-6 100g $26.1 2018-11-13 Buy

Cinnamic acid Chemical Properties,Uses,Production

Description

With a sweet, creamy, and herbal, fragrance, with a slightly burnt taste, dihydrocoumarin (DHC) is used as a flavoring agent in food, tobacco, soap, and perfume, etc. Its exotic flavor is well suited for caramel, nuts, dairy, vanilla, tropical fruit, and alcohol. It is a eukaryotic metabolite found in tonka beans grown in northern South America, from which it was isolated as early as the 1820s, as well as sweet clover. Other uses include as an organic solvent and pharmaceutical intermediary. It has been shown to influence the epigenetic process of human cells in vitro.

Sources

http://www.ebi.ac.uk/chebi/searchId.do?chebiId=CHEBI:16151
http://www.bojensen.net/EssentialOilsEng/EssentialOils29/EssentialOils29.htm#Tonka
https://books.google.kg/books?id=pUEqBgAAQBAJ&pg=PA427&lpg=PA427&dq=dihydrocoumarin+uses&source=bl&ots=HTZrffvsXu&sig=GPGKqrMRXQaRJ-qgHk7aULeBmGw&hl=en&sa=X&redir_esc=y#v=onepage&q=dihydrocoumarin%20uses&f=false
https://products.symrise.com/aroma-molecules/product-search/dihydrocoumarin/action/pdf/
http://www.lookchem.com/3-4-Dihydrocoumarin/
https://www.ncbi.nlm.nih.gov/pmc/articles/PMC1315280/

Chemical Properties

clear light yellow to brown liquid after melting

Chemical Properties

Dihydrocoumarin forms colorless crystals (mp 24°C) with a sweet, herbal odor. Dihydrocoumarin is prepared by hydrogenation of coumarin, for example, in the presence of a Raney nickel catalyst. Another process employs the vapor-phase dehydrogenation of hexahydrocoumarin in the presence of Pd or Pt-Al2O3 catalysts . Hexahydrocoumarin is prepared by cyanoethylation of cyclohexanone and hydrolysis of the nitrile group, followed by ring closure to the lactone.

Chemical Properties

Dihydrocoumarin has an odor similar to coumarin at room temperature or reminiscent of nitrobenzene at higher temperature. It has a burning taste

Occurrence

Reported found in Melilotus officinalis, from which it may be extracted by water distillation.

Uses

Perfumery.

Preparation

By reduction of coumarin under pressure in the presence of nickel at 160 to 200°C or in the presence of Pd-BaSO4 in alcoholic solution.

Definition

ChEBI: A chromanone that is the 3,4-dihydro derivative of coumarin.

General Description

White to pale yellow clear oily liquid with a sweet odor. Solidifies around room temperature.

Air & Water Reactions

Solutions of the chemical in water are stable for less than two hours. Insoluble in water.

Reactivity Profile

Hydrocoumarin is a lactone (behaves as an ester). Esters react with acids to liberate heat along with alcohols and acids. Strong oxidizing acids may cause a vigorous reaction that is sufficiently exothermic to ignite the reaction products. Heat is also generated by the interaction of esters with caustic solutions. Flammable hydrogen is generated by mixing esters with alkali metals and hydrides. Hydrocoumarin may hydrolyze under alkaline or acidic conditions.

Fire Hazard

Hydrocoumarin is combustible.

Cinnamic acid Preparation Products And Raw materials

Raw materials

Preparation Products


Cinnamic acid Suppliers

Global( 221)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Shenzhen Sendi Biotechnology Co.Ltd.
0755-23311925 18102838259
0755-23311925 Abel@chembj.com CHINA 3202 55
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 21759 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20672 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32447 55
Shanghai Zheyan Biotech Co., Ltd.
18017610038
zheyansh@163.com CHINA 3623 58
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 27142 58
Chengdu Biopurify Phytochemicals Ltd.
18080483897
maggie@biopurify.com CHINA 2236 58
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 23964 58
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 sales@jushengtech.com CHINA 28237 58
Xiamen AmoyChem Co., Ltd
+86 592-605 1114
sales@amoychem.com CHINA 6370 58

View Lastest Price from Cinnamic acid manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-17 Cinnamic acid
119-84-6
US $1.00 / kg 1kg 99% 100KG career henan chemical co

Cinnamic acid Spectrum


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