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Emamectin benzoate

CAS No.
137512-74-4
Chemical Name:
Emamectin benzoate
Synonyms
Proclaim;Emamectine Benzoate;EMaMectin Benzoate Tech;Shot-Wan;Sch 58854;Proclaim 5SG;EMAMECTIN MIN,:60%;EMAMECTIN MIN.:90%;PROCLAIM(BANLEPTM);Avermectin Benzoate
CBNumber:
CB4428208
Molecular Formula:
C49H77NO13
Molecular Weight:
888.13
MDL Number:
MFCD32206651
MOL File:
137512-74-4.mol
MSDS File:
SDS
Last updated:2023-09-13 17:49:43

Emamectin benzoate Properties

Melting point 146-150°C
alpha D -6.9° (c = 0.5% in methanol)
vapor pressure 4 x 10-7mPa
storage temp. Refrigerator
solubility Chloroform (Slightly), Methanol (Slightly)
form Solid
pka 4.2; 7.6(at 25℃)
Water Solubility 320 mg l-1 (pH 5), 24 mg l-1 (pH 7), 0.1 mg l-1 (pH 9)
color Pale Yellow to Light Yellow
FDA UNII HVM3G4A01W

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS09,GHS06
Signal word  Danger
Hazard statements  H330-H400-H410-H301
Precautionary statements  P273-P391-P501-P260-P271-P284-P304+P340-P310-P320-P403+P233-P405-P501-P273-P391-P501-P264-P270-P301+P310-P321-P330-P405-P501
Toxicity LD50 in mallard ducks, northern bobwhite quail (mg/kg): 76, 264 orally (Chukwudebe)

Emamectin benzoate price More Price(3)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC E520503 EmamectinB1Benzoate(MixtureofB1aandB1b) 137512-74-4 500mg $95 2021-12-16 Buy
American Custom Chemicals Corporation PST0000086 EMAMECTIN BENZOATE 95.00% 137512-74-4 100MG $447 2021-12-16 Buy
American Custom Chemicals Corporation PST0000086 EMAMECTIN BENZOATE 95.00% 137512-74-4 250MG $478 2021-12-16 Buy
Product number Packaging Price Buy
E520503 500mg $95 Buy
PST0000086 100MG $447 Buy
PST0000086 250MG $478 Buy

Emamectin benzoate Chemical Properties,Uses,Production

Chemical Properties

White Crystalline Powder

Uses

Insecticide.

Uses

A mixture of semi-synthetic Avermectins. Exists as the anhydrous and various hydrated forms having different crystal morphologies. Insecticide

Uses

Emamectin benzoate is a second-generation avermectin insecticide highly effective against a broad range of lepidopteran larvae and certain other insects.

Metabolic pathway

In laboratory studies, emamectin benzoate is relatively stable to aqueous hydrolysis (acid, neutral and alkaline) under dark conditions. Emamectin benzoate degrades extensively in soil via microbial action to multiple degradation products including the 8a-oxidation and 8a-hydroxylation products. CO2 and soil-bound residues were the major terminal residues which are incorporated into humic and fulvic acid fractions. In plants, emamectin benzoate degrades extensively to multiple polar components including the N-demethylated, N-formylated and conjugated products. Probably due to rapid elimination in faeces, the metabolic transformation of emamectin benzoate in animals is minimal. However, N-demethylation was observed as the major metabolic pathway. The hydrolytic, photolytic and overall metabolic pathways of emamectin benzoate in soils, plants and animals are presented in Schemes 1,2 and 3.

Degradation

Emamectin benzoate (1) was relatively stable to hydrolysis in acidic, neutral and alkaline solutions (pH 5, 7 and 9) at 25 °C, with less than 10% degradation occurring after 30 days. It hydrolysed most rapidly in acidic solution (pH 5) at 25 °C with a DT50 of 136 days (Chukwudebe, 1992). Two polar components (each <10%) eluted close to the void volume under reversed phase chromatographic conditions.
The photodegradation half-lives of emamectin benzoate (10-12 mg 1-1) in buffered distilled water (pH 7) containing 1% (v/v) acetonitrile, ethanol or acetone as cosolvent under continuous exposure to a xenon lamp were 65,9 and 0.5 days, respectively. In both buffered and natural pond water, the major photodegradation products included 8,9-MAB1a (2), 8a-hydroxylated MAB1a (3) and minor unknown polar residues (Scheme 1). In sensitised buffered water, 8a-oxo-MAB1a (4) and 10,11-14,15-MAB1a diepoxide (5) were found as additional residual products (Mushtaq et al., 1997).

Emamectin benzoate Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 152)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12470 58
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15965 58
Hangzhou Bayee Chemical Co., Ltd.
0086-571-86990109 rachelhoo@bayeechem.com China 104 55
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21689 55
Shanxi Naipu Import and Export Co.,Ltd
+86-13734021967 +8613734021967 kaia@neputrading.com China 1011 58
Klong Industrial Co., Ltd
0086-519-68231162 info@klongchem.com CHINA 131 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8822 58
Xiamen AmoyChem Co., Ltd
+86-592-6051114 +8618959220845 sales@amoychem.com China 6387 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22968 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58

View Lastest Price from Emamectin benzoate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Proclaim 5SG pictures 2023-09-13 Proclaim 5SG
137512-74-4
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
Emamectin Benzoate pictures 2022-03-17 Emamectin Benzoate
137512-74-4
US $100.00 / bag 1bag 99 500 Shanxi Naipu Import and Export Co.,Ltd
Emamectin Benzoate pictures 2021-07-13 Emamectin Benzoate
137512-74-4
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
  • Proclaim 5SG pictures
  • Proclaim 5SG
    137512-74-4
  • US $0.00 / KG
  • 99%
  • Hebei Mojin Biotechnology Co., Ltd
  • Emamectin Benzoate pictures
  • Emamectin Benzoate
    137512-74-4
  • US $15.00-10.00 / KG
  • 99%+ HPLC
  • Zhuozhou Wenxi import and Export Co., Ltd
Epimethylamino-4’’-deoxyavermectinb1aandb1bbenzoates EMAMECTIN MIN.:90% EMAMECTIN MIN,:60% Proclaim 5SG Sch 58854 Shot-Wan Emamectin benzoate [iso] (4''R)-4''-Deoxy-4''-(methylamino)-avermectin B1 benzoate(salt) Methylamino abamectin benzoate(salt) MethylaMino abaMectin benzoate powder PROCLAIM(BANLEPTM) 4''-Deoxy-4''-epi-N-(methylamino)avermectin B1 Benzoate Methylamino abamectin benzoate emamectinbenzoate(casalso emamectinbenzoate(casalsoquotedas155569-91-8) emamectinbenzoate(subjecttopatentfree) Avermectin Benzoate TIANFU CEHM 137512-74-4 Emamectin benzoate EMaMectin Benzoate Tech Emamectine Benzoate Proclaim Emamectin B1 Benzoate (Mixture of B1a and B1β) 137512-74-4 155569-91-8;137 C49H77NO13 C56H81NO15 C49H75NO13C7H6O2C48H Chiral Reagents Heterocycles