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Bromoacetaldehyde diethyl acetal

CAS No.
2032-35-1
Chemical Name:
Bromoacetaldehyde diethyl acetal
Synonyms
2-BROMO-1,1-DIETHOXYETHANE;2-Bromoacetaldehyde diethyl acetal;Bromacetal;BROMOACETAL;1,1-DIETHOXY-2-BROMOETHANE;1-Bromo-2,2-diethoxyethane;BADEA;NSC 8036;Diethyl bromoacetal;-Bromodiethylacetal
CBNumber:
CB4437547
Molecular Formula:
C6H13BrO2
Molecular Weight:
197.07
MDL Number:
MFCD00000214
MOL File:
2032-35-1.mol
MSDS File:
SDS
Last updated:2024-04-09 22:15:29

Bromoacetaldehyde diethyl acetal Properties

Boiling point 66-67 °C18 mm Hg(lit.)
Density 1.31 g/mL at 25 °C(lit.)
refractive index n20/D 1.439(lit.)
Flash point 125 °F
storage temp. 2-8°C
solubility Chloroform (Slightly), Methanol (Slightly)
form Oil
color Clear Colourless
Specific Gravity 1.310
Water Solubility immiscible
Sensitive Moisture Sensitive
BRN 635754
InChIKey LILXDMFJXYAKMK-UHFFFAOYSA-N
CAS DataBase Reference 2032-35-1(CAS DataBase Reference)
FDA UNII M4DGX2BMU9
NIST Chemistry Reference Ethane, 2-bromo-1,1-diethoxy-(2032-35-1)
EPA Substance Registry System Ethane, 2-bromo-1,1-diethoxy- (2032-35-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS06
Signal word  Danger
Hazard statements  H301-H315-H319-H330
Precautionary statements  P301+P310+P330-P302+P352-P304+P340+P310-P305+P351+P338
Hazard Codes  Xi,T
Risk Statements  10-36-36/38-23-22
Safety Statements  16-26-45-38-37/39-28A-36/37
RIDADR  UN 1993 3/PG 3
WGK Germany  3
8-9-21
Hazard Note  Toxic/Irritant
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  29110000
NFPA 704
2
1 0

Bromoacetaldehyde diethyl acetal price More Price(36)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 123986 Bromoacetaldehyde diethyl acetal 97% 2032-35-1 100g $38.2 2024-03-01 Buy
Sigma-Aldrich 123986 Bromoacetaldehyde diethyl acetal 97% 2032-35-1 1kg $231 2024-03-01 Buy
TCI Chemical B0957 Bromoacetaldehyde Diethyl Acetal >95.0%(GC) 2032-35-1 25mL $41 2024-03-01 Buy
TCI Chemical B0957 Bromoacetaldehyde Diethyl Acetal >95.0%(GC) 2032-35-1 100mL $103 2024-03-01 Buy
Alfa Aesar A13276 Bromoacetaldehyde diethyl acetal, 97% 2032-35-1 100g $38 2024-03-01 Buy
Product number Packaging Price Buy
123986 100g $38.2 Buy
123986 1kg $231 Buy
B0957 25mL $41 Buy
B0957 100mL $103 Buy
A13276 100g $38 Buy

Bromoacetaldehyde diethyl acetal Chemical Properties,Uses,Production

Chemical Properties

Colorless to light yellow liqui

Uses

Synthetic building block1,2

Uses

Bromoacetaldehyde diethyl acetal, is used as a synthetic building block. It is mainly used for synthesis of antibiotics such as erythromycin and cephalosporins and to other drugs. It also can be used as pharmaceutical intermediates. Besides, this chemical can be used to pruduce drugs such as methylthio imidazole, chlorpheniramine and others for thyroid. It also acts as a Useful intermediate for the preparation of other ?-heterosubstituted acetaldehyde acetals.

Preparation

To a flask containing 118.0 gm (1.0 mole) of diethyl acetal and 55 gm (0.55 mole) of calcium carbonate is dropwise added 55 ml (1.0 mole) of bromine over a 30-45 min period while keeping the reaction temperature at 5°-10°C. The reaction mixture is allowed to stand 24 hr, steam is introduced to dissolve the salts, the oil separated, dried over potassium carbonate, and distilled to afford 61-83 gm (31-42%), b.p. 167°-170°C. The product is further purified by shaking with potassium carbonate and distilling it under reduced pressure, b.p. 48°-49°C (3 mm Hg). The pure acetal is unstable and becomes colored in a few hours and black after several days. However, the crude acetal boiling at 167°-170°C is stable for several months.
Preparation of Bromoacetaldehyde Diethyl Acetal

General Description

May darken in storage

Global( 568)Suppliers
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Hebei Mojin Biotechnology Co., Ltd
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View Lastest Price from Bromoacetaldehyde diethyl acetal manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Bromoacetaldehyde diethyl acetal pictures 2024-04-19 Bromoacetaldehyde diethyl acetal
2032-35-1
US $3.00 / kg 1kg 99% 500mt Jinan Finer Chemical Co., Ltd
Bromoacetaldehyde diethyl acetal pictures 2024-04-12 Bromoacetaldehyde diethyl acetal
2032-35-1
US $30.00 / kg 1kg 98% 2000kg hebei hongtan Biotechnology Co., Ltd
bromoacetaldehyde diethyl acetal pictures 2024-04-09 bromoacetaldehyde diethyl acetal
2032-35-1
US $0.00-0.00 / Kg 1Kg 99.9% 200tons airuikechemical co., ltd.
BroMoacetaldehyde diethyl acetal, 97% 500ML NSC 8036 2-Bromo-1,1-diethoxyethane 2,2-Diethoxyethyl Bromide 2-bromo-1,1-diethoxy-ethan Acetaldehyde, bromo-, diethyl acetal bromoacetaldehydedlethylacetal -Bromodiethylacetal Diethyl bromoacetal Diethyl bromoacetaldehyde acetal BROMOACETALDEHYDE DIETHYL ACETAL FOR SYN Br generation of acetaldehyde condensation two ethanol 1,1-Diethoxy-2-bromoethane≥ 98.5% (GC) 2,2-DIETHOXYETHYL BROMIDE BADEA BROMO ACETYL DIACETAL BROMOACETALDEHYDE DIETHYL ACETAL Betabromoacetaldehyde diethylacetal BROMOACETALDEHYDE DIETHYL ACETAL, STAB. Bromoacetaldehydediethylacetate bromoacetataldehyde diethyl acetal Ethane, 2-bromo-1,1-diethoxy- 2-Bromo-1,1-diethoxyethane, Bromoacetal Bromacetaldehyde diethyl acetal Bromoacetaldehyde diethyl acetal,97% Bromoacetaldehyde diethyl acetal,99% Bromoacetaldehyde diethyl aceta BroMoacetaldehyde diethyl... BroMoacetaldehyde diethyl acetal, 97% 100ML 2-bromo-1,1-diethoxyethane(bromoacetaldehydediethylacetal) Bromoacetaldehyde diethyl/dimethyl acetal Bromoacetaldehyde diethanol BromoacetaldehydeDiethylAcetal> BROMOACETALDEHYDE DIETHYL ACETAL (BADEA) 2-Bromoacetaldehyde diethyl acetal Bromacetal 1,1-DIETHOXY-2-BROMOETHANE BROMOACETAL 2-BROMO-1,1-DIETHOXYETHANE 1-Bromo-2,2-diethoxyethane Venadaparib Impurity 44 Bromo acetaldehyde diethyl acetal or 2-bromo-1,1-diethoxy ethane 2032-35-1 2032-35-2 5470-72-2 2032-32-1 BrCH2CHOC2H52 C6H13BrO2 BrCH2CHOCH2CH32 Acetals/Ketals/Ortho Esters Oxygen Compounds Organic Building Blocks Building Blocks Acetals/Ketals/Ortho Esters Building Blocks Chemical Synthesis Organic Building Blocks Oxygen Compounds Pharmaceutical Intermediates