ChemicalBook >> CAS DataBase List >>1-Bromohexane
1-Bromohexane
- CAS No.
- 111-25-1
- Chemical Name:
- 1-Bromohexane
- Synonyms
- N-HEXYL BROMIDE;Bromohexane;Hexylbromid;1-Bromhexan;1-bromo-hexan;N-BROMOHEXANE;HEXYL BROMIDE;1-BROMOHEXANE;JACS-111-25-1;1-hexylbromide
- CBNumber:
- CB4447030
- Molecular Formula:
- C6H13Br
- Molecular Weight:
- 165.07
- MDL Number:
- MFCD00000271
- MOL File:
- 111-25-1.mol
- MSDS File:
- SDS
Last updated:2023-12-25 13:23:17
| Melting point | −85 °C(lit.) |
|---|---|
| Boiling point | 154-158 °C(lit.) |
| Density | 1.176 g/mL at 25 °C(lit.) |
| vapor density | 5.7 (vs air) |
| vapor pressure | <10 mm Hg ( 20 °C) |
| refractive index |
n |
| Flash point | 135 °F |
| storage temp. | Store below +30°C. |
| solubility | <1g/l |
| form | Liquid |
| color | Clear |
| Water Solubility | Immiscible with water. |
| BRN | 1731290 |
| Dielectric constant | 5.8（24℃） |
| Stability | Stable. Incompatible with strong oxidizing agents, strong bases. Combustible. |
| InChIKey | MNDIARAMWBIKFW-UHFFFAOYSA-N |
| CAS DataBase Reference | 111-25-1(CAS DataBase Reference) |
| FDA UNII | WVA0FAX7GA |
| NIST Chemistry Reference | Hexane, 1-bromo-(111-25-1) |
| EPA Substance Registry System | Hexane, 1-bromo- (111-25-1) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS02,GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H226-H315-H319-H335 | |||||||||
| Precautionary statements | P210-P233-P240-P241-P303+P361+P353-P305+P351+P338 | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38-10 | |||||||||
| Safety Statements | 26-36-16 | |||||||||
| RIDADR | UN 1993 3/PG 3 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | MO0925000 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 3 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29033036 | |||||||||
| Toxicity | LD50 orally in Rabbit: > 2000 mg/kg | |||||||||
| NFPA 704 |
|
1-Bromohexane price More Price(15)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | B68240 | 1-Bromohexane 98% | 111-25-1 | 100g | $23.5 | 2024-03-01 | Buy |
| Sigma-Aldrich | B68240 | 1-Bromohexane 98% | 111-25-1 | 1kg | $171 | 2024-03-01 | Buy |
| Sigma-Aldrich | 8.01603 | 1-Bromohexane for synthesis | 111-25-1 | 100mL | $40 | 2024-03-01 | Buy |
| Sigma-Aldrich | 8.01603 | 1-Bromohexane for synthesis | 111-25-1 | 500mL | $67.3 | 2024-03-01 | Buy |
| TCI Chemical | B0600 | 1-Bromohexane >98.0%(GC) | 111-25-1 | 25g | $25 | 2024-03-01 | Buy |
1-Bromohexane Chemical Properties,Uses,Production
Chemical nature
1-Bromohexane is organobromine compound with formula Br(CH2)5CH3. It is a colorless liquid.
Synthesis and reactions
Most 1-bromoalkanes are prepared by free-radical addition of hydrogen bromide to the 1-alkene. These conditions lead to anti-Markovnikov addition, giving the 1-bromo derivative.
1-Bromohexane undergoes reactions expected of simple alkyl bromides. It can form Grignard reagents. It reacts with potassium fluoride to give the corresponding fluorocarbons.
Chemical Properties
1-Bromohexane is a colourless liquid organohalide. It is a solvent that is frequently used in grignard reactions. It is also used as Intermediate, for introduction of hexyl group.
Uses
1-Bromohexane is utilized in the preparation of pharmaceuticals and organic chemicals. It is involved in Grignard reactions as an alkylating agent and in the synthesis of bromo-cyclic compounds.
Application
1-Bromohexane is a very useful synthetic intermediate，it can be used to react with Mg to prepare Grignard reagents which play an important role in formation of carbon-carbon bond.
Synthesis Reference(s)
Chemistry Letters, 7, p. 833, 1978
Synthetic Communications, 6, p. 21, 1976 DOI: 10.1080/00397917608062128
Tetrahedron, 40, p. 641, 1984 DOI: 10.1016/S0040-4020(01)91092-0
Purification Methods
Shake the bromide with H2SO4, wash with water, dry (K2CO3) and fractionally distil. [Beilstein 1 IV 352.]
1-Bromohexane Preparation Products And Raw materials
Raw materials
Preparation Products
2-(2-HEXYLOXYETHOXY)ETHANOL
TRIHEXYLPHOSPHINE
Sodium 1-hexanesulfonate
Sodium 1-hexanesulfonate monohydrate
1-(3 5-DIMETHOXYPHENYL)HEPTAN-1-ONE 96
1of3
Global( 382)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Yancheng Longshen Chemical Co.,Ltd. | +86-0515-88706880; +8618352073383 | sales@longshenchem.com | China | 79 | 55 |
| Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503259 +86-19930503259 | cherry@crovellbio.com | China | 18457 | 58 |
| Jinan Qinmu Fine Chemical Co.,Ltd. | +8618660799346 | sales@qinmuchem.com | China | 1009 | 58 |
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12453 | 58 |
| Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5993 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 7534 | 58 |
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| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21695 | 55 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9350 | 55 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +86-18949832763 | info@tnjchem.com | China | 2989 | 55 |
View Lastest Price from 1-Bromohexane manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-12-26 | 1-Bromohexane
111-25-1
|
US $100.00-1.00 / KG | 1KG | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
 |
2023-10-14 | 1-Bromohexane
111-25-1
|
US $0.00 / kg | 1kg | 0.99 | 20tons | Hebei Yanxi Chemical Co., Ltd. | |
 |
2023-10-08 | 1-Bromohexane
111-25-1
|
US $30.00 / KG | 1KG | 99% | 20T | Firsky International Trade (Wuhan) Co., Ltd |
-
- 1-Bromohexane
111-25-1
- US $100.00-1.00 / KG
- 99%
- Henan Fengda Chemical Co., Ltd
-
- 1-Bromohexane
111-25-1
- US $0.00 / kg
- 0.99
- Hebei Yanxi Chemical Co., Ltd.
-
- 1-Bromohexane
111-25-1
- US $30.00 / KG
- 99%
- Firsky International Trade (Wuhan) Co., Ltd
111-25-1(1-Bromohexane)Related Search:
1-BROMOHEXANE
HEXYL BROMIDE
N-BROMOHEXANE
1-bromo-hexan
1-Hexyl bromide
1-hexylbromide
1-BROMO HEXANE (N-HEXYL BROMIDE)
bromohexane hexyl bromide
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Hexylbromid
hexylbromide(1-bromohexane)
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Pentane, bromomethyl-
BroMine hexane
JACS-111-25-1
hexyl bromide? (111-25-1?)??,
1-BROMOHEXANE, 98%1-BROMOHEXANE, 98%1-BROMOHEXANE, 98%1-BROMOHEXANE, 98%
1-Bromohexane >
1-Bromohexane ISO 9001：2015 REACH
1-BROMOHEXANE For Synthesis
Bromohexane
N-HEXYL BROMIDE
111-25-1
CH2CH24CH2Br
CH3CH25Br
111251
CH3CH2CH2CH2CH2CH2Br
HALOGEN
Monofunctional & 伪,蠅-Bifunctional Alkanes
Alkyl Bromides
Monofunctional Alkanes
Halogenated Hydrocarbons
Organic Building Blocks
Building Blocks
Alkyl
Alkyl
Building Blocks
Chemical Synthesis
Halogenated Hydrocarbons
Organic Building Blocks
Intermediates
ALKYL BROMIDE
Bromine Compounds
Alkyl Bromides
Monofunctional & alpha,omega-Bifunctional Alkanes
Monofunctional Alkanes
Industrial/Fine Chemicals