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1-Bromohexane

Chemical nature Synthesis and reactions
1-Bromohexane
1-Bromohexane structure
CAS No.
111-25-1
Chemical Name:
1-Bromohexane
Synonyms
Bromohexane;Hexylbromid;1-Bromhexan;HEXYL BROMIDE;1-BROMOHEXANE;1-bromo-hexan;N-BROMOHEXANE;JACS-111-25-1;1-hexylbromide;N-Hexyl romide
CBNumber:
CB4447030
Molecular Formula:
C6H13Br
Formula Weight:
165.07
MOL File:
111-25-1.mol

1-Bromohexane Properties

Melting point:
−85 °C(lit.)
Boiling point:
154-158 °C(lit.)
Density 
1.176 g/mL at 25 °C(lit.)
vapor density 
5.7 (vs air)
vapor pressure 
<10 mm Hg ( 20 °C)
refractive index 
n20/D 1.448(lit.)
Flash point:
135 °F
storage temp. 
Store below +30°C.
solubility 
<1g/l
form 
Liquid
color 
Clear
Water Solubility 
Immiscible with water.
BRN 
1731290
Stability:
Stable. Incompatible with strong oxidizing agents, strong bases. Combustible.
InChIKey
MNDIARAMWBIKFW-UHFFFAOYSA-N
CAS DataBase Reference
111-25-1(CAS DataBase Reference)
FDA UNII
WVA0FAX7GA
NIST Chemistry Reference
Hexane, 1-bromo-(111-25-1)
EPA Substance Registry System
Hexane, 1-bromo- (111-25-1)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS02,GHS07,GHS09
Signal word  Warning
Hazard statements  H303-H401-H411-H226-H315-H319-H335
Precautionary statements  P261-P305+P351+P338-P280-P337+P313-P403+P235-P273-P280g-P210-P233-P240-P241+P242+P243-P264-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P501
Hazard Codes  Xi
Risk Statements  36/37/38-10
Safety Statements  26-36-16
RIDADR  UN 1993 3/PG 3
WGK Germany  2
RTECS  MO0925000
TSCA  Yes
HazardClass  3
PackingGroup  III
HS Code  29033036
Toxicity LD50 orally in Rabbit: > 2000 mg/kg

1-Bromohexane price More Price(13)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich B68240 1-Bromohexane 98% 111-25-1 100g $21.4 2021-03-22 Buy
Sigma-Aldrich 8.01603 1-Bromohexane for synthesis 111-25-1 100 mL $29.51 2021-03-22 Buy
Sigma-Aldrich 8.01603 1-Bromohexane for synthesis 111-25-1 500 mL $49.58 2021-03-22 Buy
Sigma-Aldrich B68240 1-Bromohexane 98% 111-25-1 1kg $141 2021-03-22 Buy
TCI Chemical B0600 1-Bromohexane >98.0%(GC) 111-25-1 25g $14 2021-03-22 Buy

1-Bromohexane Chemical Properties,Uses,Production

Chemical nature

1-Bromohexane is organobromine compound with formula Br(CH2)5CH3. It is a colorless liquid.

Synthesis and reactions

Most 1-bromoalkanes are prepared by free-radical addition of hydrogen bromide to the 1-alkene. These conditions lead to anti-Markovnikov addition, giving the 1-bromo derivative.
1-Bromohexane undergoes reactions expected of simple alkyl bromides. It can form Grignard reagents. It reacts with potassium fluoride to give the corresponding fluorocarbons.

Chemical Properties

colourless liquid

Uses

Intermediate, for introduction of hexyl group.

Synthesis Reference(s)

Chemistry Letters, 7, p. 833, 1978
Synthetic Communications, 6, p. 21, 1976 DOI: 10.1080/00397917608062128
Tetrahedron, 40, p. 641, 1984 DOI: 10.1016/S0040-4020(01)91092-0

Purification Methods

Shake the bromide with H2SO4, wash with water, dry (K2CO3) and fractionally distil. [Beilstein 1 IV 352.]

1-Bromohexane Preparation Products And Raw materials

Raw materials

Preparation Products


1-Bromohexane Suppliers

Global( 296)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Yancheng Longshen Chemical Co.,Ltd.
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HEBEI YINGONG NEW MATERIAL TECHNOLOGY CO.,LTD
+8619933070948
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SHANDONG ZHI SHANG CHEMICAL CO.LTD
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Xi'an Kono chem co., Ltd.,
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View Lastest Price from 1-Bromohexane manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2021-07-02 1-Bromohexane 98%
111-25-1
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
2021-04-28 Hexylbromid
111-25-1
US $160.00 / ASSAYS 10g/ml 99.9% 10 mt HEBEI YINGONG NEW MATERIAL TECHNOLOGY CO.,LTD
2020-11-24 1-Bromohexane
111-25-1
US $1.00 / BOU/Drum 1KG 98% 1kg HONG KONG IPURE BIOLOGY CO.,LIMITED

1-Bromohexane Spectrum


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