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TETRAPROPYLAMMONIUM PERRUTHENATE

CAS No.
114615-82-6
Chemical Name:
TETRAPROPYLAMMONIUM PERRUTHENATE
Synonyms
TPAP;TETRA-N-PROPYLAMMONIUM PERRUTHENATE;Tetrapropylammonium tetraoxoruthenate;TerapropylaMMoniuMperruthenate;etrapropylammoniumperruthenate;TETRAPROPYLAMMONIUM PERRUTHENATE;TetrapropylaMMoniuM perruthenate 97%;tetrapropylammonium perruthenate(VII);Tetrapropylammonium Perruthenate (TPAP);TETRA-N-PROPYLAMMONIUM PERRUTHENATE (VII)
CBNumber:
CB4468073
Molecular Formula:
C12H28NO4Ru
Molecular Weight:
351.43
MDL Number:
MFCD00074914
MOL File:
114615-82-6.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

TETRAPROPYLAMMONIUM PERRUTHENATE Properties

Melting point ~160 °C (dec.) (lit.)
storage temp. Inert atmosphere,2-8°C
solubility Methanol (Slightly)
form crystal
color green
Water Solubility Insoluble in water.
Sensitive Hygroscopic
Stability store cold
InChIKey NQSIKKSFBQCBSI-UHFFFAOYSA-N
FDA UNII Y4N78L8V1T

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS03,GHS07
Signal word  Danger
Hazard statements  H272-H315-H319-H335
Precautionary statements  P210a-P405-P501a-P220-P261-P305+P351+P338-P210-P221-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P501
Hazard Codes  O,Xi
Risk Statements  5-8-36/37/38
Safety Statements  17-26-36
RIDADR  UN 1479 5.1/PG 2
WGK Germany  3
3-10
HazardClass  5.1
PackingGroup  III
HS Code  28439000
NFPA 704
1
2 3
OX

TETRAPROPYLAMMONIUM PERRUTHENATE price More Price(45)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 330744 Tetrapropylammonium perruthenate 97% 114615-82-6 250mg $72.6 2024-03-01 Buy
Sigma-Aldrich 330744 Tetrapropylammonium perruthenate 97% 114615-82-6 1g $252 2024-03-01 Buy
TCI Chemical T1559 Tetrapropylammonium Perruthenate 114615-82-6 1g $93 2024-03-01 Buy
TCI Chemical T1559 Tetrapropylammonium Perruthenate 114615-82-6 5g $270 2024-03-01 Buy
Alfa Aesar B24511 Tetra-n-propylammonium perruthenate(VII) 98% 114615-82-6 0.5g $82 2024-03-01 Buy
Product number Packaging Price Buy
330744 250mg $72.6 Buy
330744 1g $252 Buy
T1559 1g $93 Buy
T1559 5g $270 Buy
B24511 0.5g $82 Buy

TETRAPROPYLAMMONIUM PERRUTHENATE Chemical Properties,Uses,Production

Uses

A mild oxidant for the selective transformation of primary alcohols to aldehydes and secondary alcohols to ketones.

Chemical Properties

dark green solid

Uses

Tetrapropylammonium Perruthenate is used in sustainable oxidation reactions and has potential for chemical recycling.

Definition

ChEBI: A quaternary ammonium salt having tetrapropylammonium as the cation and perruthenate as the anion.

General Description

Tetrapropylammonium perruthenate is a mild oxidizing agent used for the oxidation of alcohols to corresponding carbonyl compounds. It is a non-volatile, air-stable, and readily soluble reagent, which can be used either stoichiometrically or catalytically with a suitable co-oxidant.

Purification Methods

It is a strong oxidant and may explode on heating. It can be washed with aqueous n-propanol, then H2O and dried over KOH in a vacuum. It is stable at room temperature but best stored in a refrigerator. It is soluble in CH2Cl2 and MeCN. [Dengel et al. Transition Met Chem 10 98 1985, Griffith et al. J Chem Soc, Chem Commun 1625 1987.] § Polymer supported reagent is available commercially.

Global( 228)Suppliers
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Capot Chemical Co.,Ltd.
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Henan Tianfu Chemical Co.,Ltd.
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CONIER CHEM AND PHARMA LIMITED
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Shanghai Daeyeon Chemicals Co., Ltd
021-64478606 +8615900664856 daeyeon001@vip.163.com China 2062 58

View Lastest Price from TETRAPROPYLAMMONIUM PERRUTHENATE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
TETRAPROPYLAMMONIUM PERRUTHENATE pictures 2019-12-24 TETRAPROPYLAMMONIUM PERRUTHENATE
114615-82-6
US $1.00 / KG 1KG 99% 1000KGS Career Henan Chemical Co

TETRAPROPYLAMMONIUM PERRUTHENATE Spectrum

TETRAPROPYLAMMONIUM PERRUTHENATE TETRA-N-PROPYLAMMONIUM PERRUTHENATE (VII) TerapropylaMMoniuMperruthenate TetrapropylaMMoniuM perruthenate,97% TPAP, (n-C3H7)4NRuO4 TetrapropylaMMoniuM perruthenate,TPAP,(n-C3H7)NRuO4 TetrapropylaMMoniuM perruthenate 97% Tetrapropylammonium perruthenate, min. 97% Tetrapropylammoniumperruthenate,min.97%TPAP 1-Propanaminium, N,N,N-tripropyl-, (T-4)-tetraoxoruthenate(1-) Tetrapropylammonium Perruthenate (TPAP) Tetra-n-propylammonium perruthenate(VII), 98+% Tetra n-propylammonium perruthenate Oxidation tetrapropylammonium perruthenate(VII) 1-Propanaminium, N,N,N-tripropyl-, (T-4)-tetraoxoru 1-Propanaminium, N,N,N-tripropyl-, (T-4)-tetraoxoruthenate(1-) (1:1) etrapropylammoniumperruthenate TETRA-N-PROPYLAMMONIUM PERRUTHENATE TPAP Tetrapropylammonium tetraoxoruthenate 114615-82-6 C12H28NRuO4 C3H74NRuO4 CH3CH224NRuO4 CH3CH2CH24NRuO4 C12H28NO4Ru Quaternary Ammonium Compounds Classes of Metal Compounds Oxidation Transition Metal Compounds Transition Metal Complexes (Environmentally-friendly Oxidation) Catalysts for Organic Synthesis Metal Complexes Ammonium Polyhalides, etc. (Quaternary) Homogeneous Catalysts Ru (Ruthenium) Compounds Environmentally-friendly Oxidation Others Synthetic Reagents Boron, Nitrile, Thio,& TM-Cpds Ammonium Polyhalides, etc. (Quaternary) Catalysts for Organic Synthesis Classes of Metal Compounds Environmentally-friendly Oxidation Homogeneous Catalysts Metal Complexes Oxidation Quaternary Ammonium Compounds Ru (Ruthenium) Compounds Synthetic Organic Chemistry Transition Metal Complexes (Environmentally-friendly Oxidation) Transition Metal Compounds Ru Alkylammonium salt