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ChemicalBook >> CAS DataBase List >>(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP

(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP

(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP Structure
(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP structure
CAS No.
828927-97-5
Chemical Name:
(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP
Synonyms
(R,R)-PINAP;4-[2-(Diphenylphosphino)-1-naphthyl]-N-(1-phenylethyl)phthalazin-1-amine;4-(2-diphenylphosphanylnaphthalen-1-yl)-N-[(1R)-1-phenylethyl]phthalazin-1-amine;(R)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(1R)-1-PHENYLETHYL]-1-PHTHALAZINAMINE;1-Phthalazinamine, 4-[2-(diphenylphosphino)-1-naphthalenyl]-N-[(1R)-1-phenylethyl]-, (1R)-;(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinaMine (R,R)-N-PINAP;(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP;(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[?-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP;(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinamine,min.97%(R)-N-PINAP;(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinamine, min. 97% (R,R)-N-PINAP
CBNumber:
CB4505705
Molecular Formula:
C38H30N3P
Molecular Weight:
559.64
MDL Number:
MFCD09264274
MOL File:
828927-97-5.mol
Last updated:2023-04-23 13:52:06
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(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP Properties

Melting point 185-188°C
alpha +127.3° (c 0.39, CHCl3)
Boiling point 732.0±60.0 °C(Predicted)
pka 5.35±0.30(Predicted)
form crystal
color colorless
Sensitive air sensitive

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338

(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 15-1784 (R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinamine, min. 97% (R,R)-N-PINAP 828927-97-5 100mg $106 2021-12-16 Buy
Strem Chemicals 15-1784 (R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinamine, min. 97% (R,R)-N-PINAP 828927-97-5 500mg $424 2021-12-16 Buy
American Custom Chemicals Corporation ING0001306 (R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHYL]-1-PHTHALAZINAMINE 95.00% 828927-97-5 250MG $787.5 2021-12-16 Buy
American Custom Chemicals Corporation ING0001306 (R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(R)-1-PHENYLETHYL]-1-PHTHALAZINAMINE 95.00% 828927-97-5 1G $1950 2021-12-16 Buy
Ambeed A729275 (R)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinamine 98% 828927-97-5 1g $705 2021-12-16 Buy
Product number Packaging Price Buy
15-1784 100mg $106 Buy
15-1784 500mg $424 Buy
ING0001306 250MG $787.5 Buy
ING0001306 1G $1950 Buy
A729275 1g $705 Buy

(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP Chemical Properties,Uses,Production

Reactions

  1. The PINAP family of P,N ligands is a synthetically more accessible but a similarly performing analog of the QUINAP (15-1777, 15-1778) ligand in enantioselective hydroboration, alkyne addition, and azomethine cycloaddition reactions.
  2. With copper, enantioselective addition of alkynes to aldehydes to synthesize propargylamines.
  3. With copper, catalytic, enantioselective, conjugate alkyne addition in aqueous media.
Reactions of 828927-97-5

(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP Suppliers

Global( 13)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21695 55
Shanghai Acmec Biochemical Technology Co., Ltd. 		+undefined18621343501 product@acmec-e.com China 33349 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 94838 76
Bide Pharmatech Ltd. 400-1647117 15221909166 product02@bidepharm.com China 41438 60
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2654 58
Aikon International Limited 025-66113011 18112977050 sales01@aikonchem.com China 16028 58
Energy Chemical 021-58432009 400-005-6266 marketing@energy-chemical.com China 44941 58
Beijing Jin Ming Biotechnology Co., Ltd. 010-60605840 15801484223 psaitong@jm-bio.com China 29834 58
Jiangsu Nanchuang Chemical and Life Health Research Institute Co., Ltd. 025-025-58280381 15720605021 zhang_lei@jsnchem.com China 1456 58
Shanghai Haohong Pharmaceutical Co., Ltd. 400-8210725 4008210725 malulu@leyan.com China 39997 58
Supplier Advantage
Henan Tianfu Chemical Co.,Ltd. 		55
Shanghai Acmec Biochemical Technology Co., Ltd. 		58
J & K SCIENTIFIC LTD. 76
Bide Pharmatech Ltd. 60
LaaJoo 58
Aikon International Limited 58
Energy Chemical 58
Beijing Jin Ming Biotechnology Co., Ltd. 58
Jiangsu Nanchuang Chemical and Life Health Research Institute Co., Ltd. 58
Shanghai Haohong Pharmaceutical Co., Ltd. 58
(R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[?-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP (R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinamine,min.97%(R)-N-PINAP (R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinamine, min. 97% (R,R)-N-PINAP (R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(R)-1-phenylethyl]-1-phthalazinaMine (R,R)-N-PINAP (R)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[(1R)-1-PHENYLETHYL]-1-PHTHALAZINAMINE 4-(2-diphenylphosphanylnaphthalen-1-yl)-N-[(1R)-1-phenylethyl]phthalazin-1-amine (R,R)-PINAP (R)-(+)-4-[2-(DIPHENYLPHOSPHINO)-1-NAPHTHALENYL]-N-[-1-PHENYLETHYL]-1-PHTHALAZINAMINE, MIN.(R)-N-PINAP 1-Phthalazinamine, 4-[2-(diphenylphosphino)-1-naphthalenyl]-N-[(1R)-1-phenylethyl]-, (1R)- 4-[2-(Diphenylphosphino)-1-naphthyl]-N-(1-phenylethyl)phthalazin-1-amine 828927-97-5 C38H30N3P Chiral Phosphine PINAP Series