ChemicalBook >> CAS DataBase List >>(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS

(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS

(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS structure

CAS No.: 325168-89-6

Chemical Name:: (R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS

Synonyms: (R)-XylPhanePHOS;(R)-Xylyl-PHANEPhos;(R)-5,11-Bis(3,5-xylylphosphino)tricyclo[8.2.24,7]hexadeca-hexaene;(R)-4,12-Bis(1,1-bis(3,5-dimethylphenyl)phosphine)-[2.2]paracyclophane;(R)-Xylyl-PHANEPhos, (R)-5,11-Bis(3,5-xylylphosphino)tricyclo[8.2.2.24,7]hexadeca-hexaene;(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS;(R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, Min. 97% CTH-(R)-3,5-xylyl-PHANEPHOS;Phosphine, 1,1'-tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diylbis[1,1-bis(3,5-dimethylphenyl)-, stereoisomer

CBNumber:: CB4634847

Molecular Formula:: C48H50P2

Molecular Weight:: 688.86

MDL Number:: MFCD03840578

MOL File:: 325168-89-6.mol

MSDS File:: SDS

Last updated:2023-04-23 13:52:06

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(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS Properties

Melting point	234-238 °C
Boiling point	785.2±60.0 °C(Predicted)
form	Powder
color	white
optical activity	[α]22/D -61.0, c = 0.1 in ethanol

SAFETY

Risk and Safety Statements

Symbol(GHS)	GHS07
Signal word	Warning
Hazard statements	H315-H319
Precautionary statements	P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313
Hazard Codes	Xi
Risk Statements	36/38
Safety Statements	26
WGK Germany	3

(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS price More Price(8)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	682306	(R)-(–)-4,12-Bis[di(3,5-xylyl)phosphino]-[2.2]-paracyclophane 95%	325168-89-6	100mg	$137	2023-06-20	Buy
Sigma-Aldrich	682306	(R)-(–)-4,12-Bis[di(3,5-xylyl)phosphino]-[2.2]-paracyclophane 95%	325168-89-6	500mg	$543	2023-06-20	Buy
Strem Chemicals	15-0730	(R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, min. 97% CTH-(R)-3,5-xylyl-PHANEPHOS	325168-89-6	100mg	$110	2024-03-01	Buy
Strem Chemicals	15-0730	(R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, min. 97% CTH-(R)-3,5-xylyl-PHANEPHOS	325168-89-6	500mg	$435	2024-03-01	Buy
American Custom Chemicals Corporation	ING0001279	(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE 95.00%	325168-89-6	100MG	$664.95	2021-12-16	Buy

Product number	Packaging	Price	Buy
682306	100mg	$137	Buy
682306	500mg	$543	Buy
15-0730	100mg	$110	Buy
15-0730	500mg	$435	Buy
ING0001279	100MG	$664.95	Buy

(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS Chemical Properties,Uses,Production

Reaction

Chiral ligand employed in the enantioselective hydrogenation of various ketones.
Chiral ligand employed in the enantioselective hydroxycarbonylation and alkoxycarbonylation of alkenes.
Chiral ligand employed in the enantioselective [2+2] cycloaddition of oxabicyclic alkenes with terminal alkynes.
Chiral ligand employed in the gold-catalyzed enantioselective Cope rearrangement of achiral 1,5-dienes.

Uses

Efficient ligand for asymmetric hydrogenation of dehydroamino acids, methyl esters and ketones.

(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS Suppliers

Global( 26)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hangzhou MolCore BioPharmatech Co.,Ltd.	+86-057181025280; +8617767106207	sales@molcore.com	China	49739	58
J & K SCIENTIFIC LTD.	010-82848833 400-666-7788	jkinfo@jkchemical.com	China	96815	76
Alfa Aesar	400-6106006	saleschina@alfa-asia.com	China	30132	84
Energy Chemical	021-021-58432009 400-005-6266	sales8178@energy-chemical.com	China	44751	61
Daicel Chiral Technologies (China)CO.,LTD	021-50460086-9 15921403865	han_yajun@dctc.daicel.com	China	6818	65
Beijing Guofang Dingsheng Technology Co., Ltd.	18610472091 18610472091	gfdskj@163.com	China	494	58
Sigma-Aldrich	021-61415566 800-8193336	orderCN@merckgroup.com	China	51471	80
Codow Chemical Co.,Ltd.	18620099427	amy@howeipharm.com	China	17698	55
Shanghai Xilong Biochemical Technology Co., Ltd.	021-52907766-8042		China	9947	58
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.	0371-0371-65511006 18625597674	sales@kingorgchem.com	China	949	55

Supplier	Advantage
Hangzhou MolCore BioPharmatech Co.,Ltd.	58
J & K SCIENTIFIC LTD.	76
Alfa Aesar	84
Energy Chemical	61
Daicel Chiral Technologies (China)CO.,LTD	65
Beijing Guofang Dingsheng Technology Co., Ltd.	58
Sigma-Aldrich	80
Codow Chemical Co.,Ltd.	55
Shanghai Xilong Biochemical Technology Co., Ltd.	58
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd.	55

325168-89-6((R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS)Related Search:

[2.2]Paracyclophane

(R)-(-)-4,12-BIS(DI(3,5-XYLYL)PHOSPHINO)-[2.2]-PARACYCLOPHANE, MIN. 95% CTH-(R)-3,5-XYLYL-PHANEPHOS (R)-Xylyl-PHANEPhos, (R)-5,11-Bis(3,5-xylylphosphino)tricyclo[8.2.2.24,7]hexadeca-hexaene (R)-5,11-Bis(3,5-xylylphosphino)tricyclo[8.2.24,7]hexadeca-hexaene (R)-Xylyl-PHANEPhos (R)-(-)-4,12-Bis(di(3,5-xylyl)phosphino)-[2.2]-paracyclophane, Min. 97% CTH-(R)-3,5-xylyl-PHANEPHOS (R)-XylPhanePHOS (R)-4,12-Bis(1,1-bis(3,5-dimethylphenyl)phosphine)-[2.2]paracyclophane Phosphine, 1,1'-tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene-5,11-diylbis[1,1-bis(3,5-dimethylphenyl)-, stereoisomer 325168-89-6 PHANEPhos Series Chiral Phosphine organophosphine ligand