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Triclopyr

CAS No.
55335-06-3
Chemical Name:
Triclopyr
Synonyms
Rely;opyr;Mutan;TricL;M 3724;Exetor;Garlon;Redeem;Remedy;TRIDENT
CBNumber:
CB4666264
Molecular Formula:
C7H4Cl3NO3
Molecular Weight:
256.47
MDL Number:
MFCD00072514
MOL File:
55335-06-3.mol
MSDS File:
SDS
Last updated:2023-06-20 14:22:13

Triclopyr Properties

Melting point 148-150°C
Boiling point 290°C
Density 1.7626 (rough estimate)
refractive index 1.6200 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility Chloroform (Slightly), Ethyl Acetate (Slightly), Methanol (Slightly)
form Liquid
pka 2.68(at 25℃)
color Fluffy solid
Water Solubility 0.43g/L(temperature not stated)
Merck 13,9730
BRN 225301
CAS DataBase Reference 55335-06-3(CAS DataBase Reference)
FDA UNII MV06PHJ6I0
NIST Chemistry Reference Acetic acid, [(3,5,6-trichloro-2-pyridinyl)oxy]-(55335-06-3)
Pesticides Freedom of Information Act (FOIA) Triclopyr
EPA Substance Registry System Triclopyr (55335-06-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H319-H371-H373-H410
Precautionary statements  P501-P273-P260-P270-P264-P280-P391-P337+P313-P305+P351+P338-P308+P311-P301+P312+P330-P405
Hazard Codes  Xn
Risk Statements  22
Safety Statements  22-24/25
RIDADR  UN3082 (liquid)
WGK Germany  3
RTECS  AJ9000000
HS Code  2933.39.2500
Toxicity LD50 orally in rats: 713 mg/kg (Kenaga)
NFPA 704
0
2 0

Triclopyr price More Price(19)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 32016 Triclopyr PESTANAL 55335-06-3 250mg $35.3 2024-03-01 Buy
TCI Chemical T3742 Triclopyr 55335-06-3 5G $77 2024-03-01 Buy
TCI Chemical T3742 Triclopyr 55335-06-3 25G $231 2024-03-01 Buy
Chem-Impex 39365 Triclopyr,96%(Assaybytitration,GC) 96%(Assaybytitration,GC) 55335-06-3 25G $286.72 2021-12-16 Buy
American Custom Chemicals Corporation AGR0000048 TRICLOPYR 95.00% 55335-06-3 1G $203.7 2021-12-16 Buy
Product number Packaging Price Buy
32016 250mg $35.3 Buy
T3742 5G $77 Buy
T3742 25G $231 Buy
39365 25G $286.72 Buy
AGR0000048 1G $203.7 Buy

Triclopyr Chemical Properties,Uses,Production

Chemical Properties

White to Off-White Solid

Uses

Triclopyr is a selective post-emergence herbicide.

Uses

Selective postemergence herbicide to control many woody and broad-leaved weeds.

Definition

ChEBI: A monocarboxylic acid that is (pyridin-2-yloxy)acetic acid substituted by chloro groups at positions 3, 5 and 6. It is an agrochemical used as a herbicide.

Agricultural Uses

Herbicide: Triclopry is a systemic herbicide used on rice, range land and pasture, rights-of-way, forestry and grasslands, including home lawns, for control of broadleaf weeds and woody plants. Triclopry is usually available as a triclopyr butoxyethyl ester (BEE) or as a triclopry triethylamine salt (TEA). Registered for use in the U.S. Some products may be classified as Restricted Use Pesticides (RUP). Registered for use in EU countries . U.S. Maximum Allowable Residue Levels for Triclopyr and its metabolites 3,5,6,-trichloro-2-pyridinol and 2-methoxy-3,5,6-trichloropyridine [40 CFR 180.417 (a)(1)]: for the combined residues of the herbicide in or on the following raw agricultural commodities: fish 3.0 ppm; grass, forage 500 ppm; grass, forage, hay 500 ppm;shellfish3.5 ppm.[40 CFR 180.417 (a)(2)]: in or on the following agricultural commodities: egg 0.05 ppm; meat, fat, and meat byproducts, except kidney and liver, of cattle, goat, hog, horse and sheep 0.05 ppm; meat, fat, and meat byproducts, except kidney, of poultry 0.1 ppm; milk 0.01 ppm; liver and kidney of cattle, goat, hog, horse and sheep 0.5 ppm; rice, grain 0.3 ppm; rice, straw10.0 ppm.

Trade name

[Note: See the following record, Triclopyr, triethylamine salt, for trade names containing the salt of triclopry] ACCESS®; CROSSBOW®, (triclopyr + 2,4-D ester); ET®; GARLON®; GRAZON® Triclopyr; PATHFINDER®; REDEEM®; RELY®; REMEDY®; RIVERDALE TAHOE® Nufarm (Australia); TURFLON®

Safety Profile

Moderately toxic by ingestion. Anexperimental teratogen. Experimental reproductiveeffects. Used as an herbicide. When heated todecomposition it emits toxic fumes of Clí and NOx.

Environmental Fate

Soil. In soil, triclopyr degraded to 3,5,6-trichloro-2-pyridinol and 2-methoxy-3,5,6- trichloropyridine (Norris et al., 1987). The major route of dissipation from soil is likely due to microbial degradation (Newton et al., 1990).
Fifty-four days after triclopyr was applied to soil at a rate of 5.6 kg/ha, the majority (65%) remained in the top 10 cm of soil (Lee et al., 1986a).
Ashton and Monaco (1991) reported triclopyr had an average half-life of 46 days and is in?uenced by soil type and climatic conditions.
Plant. Lewer and Owen (1989) found 3,5,6-trichloro-2-pyridinol as the major metab- olite in plants. Cultured soybean cells metabolized triclopyr to dimethyl triclopyr-aspartate and dimethyl triclopyr-glutamate which can be rehydrolyzed to form the parent compound.
At an application rate of 3.4 kg/ha, the dissipation half-life was 3.7 days. At an application rate of 3.3 kg/ka, the dissipation half-lives of triclopyr in brown, browse and litter samples were 73.5, 202.3 and 31 days, respectively (Norris et al., 1987).

Metabolic pathway

After 7 days in a soybean cell suspension culture, the major metabolites of trichlopyr are formed and identified as the aspartate (major) and glutamate (minor) amide conjugates.

Metabolism

The average half-life of triclopyr in soil is 46 days. Because triclopyr is sensitive to light, the length of time that it remains on the surface may moderate its persistence. Adsorption to soil is limited and is governed by the anion exchange capacity. Insignificant amounts are lost via volatilization. The propensity of triclopyr to translocate in the environment with soil water, is unknown.

Toxicity evaluation

The acute oral LD50 of triclopyr is 692 mg/kg and 577 mg/kg for male and female rat, respectively. It does not appear to undergo significant transformation and is excreted in the urine primarily unchanged.

60825-26-5
55335-06-3
Synthesis of Triclopyr from TRICLOPYR METHYL ESTERSUFFIX ADDED TO CAS TO DIFFERENTIATE FROM NON-DEUTERATED/DERIVATIZED COMPOUND.

Triclopyr Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 192)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12453 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21695 55
Hefei TNJ Chemical Industry Co.,Ltd.
+86-0551-65418679 +86-18949832763 info@tnjchem.com China 2989 55
Hubei Jusheng Technology Co.,Ltd.
18871490254 linda@hubeijusheng.com CHINA 28180 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8822 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22968 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 47465 58
career henan chemical co
+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
SIMAGCHEM CORP
+86-13806087780 sale@simagchem.com China 17367 58

View Lastest Price from Triclopyr manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Triclopyr pictures 2023-06-20 Triclopyr
55335-06-3
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
Triclopyr pictures 2021-11-09 Triclopyr
55335-06-3
US $10.00 / KG 100KG 99% 100 mt Hebei Guanlang Biotechnology Co., Ltd.
Triclopyr pictures 2019-12-25 Triclopyr
55335-06-3
US $1.00 / g 1g 99% 1000KGS Career Henan Chemical Co
  • Triclopyr pictures
  • Triclopyr
    55335-06-3
  • US $0.00 / KG
  • 99%
  • Hebei Mojin Biotechnology Co., Ltd
  • Triclopyr pictures
  • Triclopyr
    55335-06-3
  • US $10.00 / KG
  • 99%
  • Hebei Guanlang Biotechnology Co., Ltd.
  • Triclopyr pictures
  • Triclopyr
    55335-06-3
  • US $1.00 / g
  • 99%
  • Career Henan Chemical Co
3,5,6-TPA Garlon 2 Garlon 250 NSC 190671 TIMTEC-BB SBB003109 TRIDENT TRICLOPYR (3,5,6-trichloro-2-pyridyloxy)-aceticaci [(3,5,6-trichloropyridin-2-yl)oxy]ethanoicacid 3,5,6-trichloro-2-pyridinyloxyethanoicacid Ace-brush Acetic acid, ((3,5,6-trichloro-2-pyridyl)oxy)- Crossbow 3,5,6-TRICHLORO-2-PYRIDINE OXYACETIC ACID 3,4,6-trichloro-2-pyridinyloxyacetic acid [(3,5,6-trichloropyridin-2-yl)oxy]acetic acid TRICLOPYR ACID TRICLOPYR, 500MG, NEAT TRICLOPYR PESTANAL (3,5,6-TRICHLORO-2-PY TRICLOPYR [3.5.6-TRICHOLOR-2-PYRIDINE OXYACETIC ACID ] 3.5.6-tricholor-2-pyridine oxyacetic acid Hca-60% Acetic acid, (3,5,6-trichloro-2-pyridinyl)oxy- TRICHLORPYR M 3724 3,5,6-Trichloro-2-pyridinyloxyacetic acid - Parent, esters, salts 2-(3,5,6-trichloropyridin-2-yl)oxyacetic acid 2-(3,5,6-trichloropyridin-2-yl)oxyethanoic acid 2-[(3,5,6-trichloro-2-pyridyl)oxy]acetic acid Triclopyr 500mg [55335-06-3] [(3,5,6-tTichloro-2-pyridyl)oxy]acetic Acid 2-[(3,5,6-Trichloro-2-pyridinyl)oxy]acetic Acid Triclopyr Standard CrossbowTurflon Curtail Dowco 233 dowco233 Exetor Garlon grazonet Mutan Redeem Rely Remedy Timbrel Trichlopyr Tticlopyr Turflon GARLON(R) [(3,5,6-TRICHLORO-2-PYRIDINYL)OXY]-ACETIC ACID [(3,5,6-Trichloro-2-pyridyl)oxy]aceticacid 2-((3,5,6-Trichloropyridin-2-yl) Triclopyr Solution, 1000ppm Crossbow(TM) Triclopyr @100 μg/mL in AcCN TriclopyrSolution,1,000mg/L,1ml Triclopyr @100 μg/mL in MeOH TriclopyrSolution,100mg/L,1ml