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Tetraethyl orthocarbonate

CAS No.
78-09-1
Chemical Name:
Tetraethyl orthocarbonate
Synonyms
TETRAETHOXYMETHANE;ethyl orthocarbonate;Tetraethyl orthocarb;Four ethyl carbonate;Tetraethyl-2-carbonate;Ethane, 1,1‘,1‘‘,1‘‘‘-;triethoxymethoxy-ethane;TRIETHYL ORTHOCARBONATE;Tetraehtylorthocarbonate;Teraethyl orthocarbonate
CBNumber:
CB4702616
Molecular Formula:
C9H20O4
Molecular Weight:
192.25
MDL Number:
MFCD00009221
MOL File:
78-09-1.mol
MSDS File:
SDS
Last updated:2023-09-15 15:02:29

Tetraethyl orthocarbonate Properties

Melting point 222 °C
Boiling point 159 °C (lit.)
Density 0.919 g/mL at 25 °C (lit.)
refractive index n20/D 1.392(lit.)
Flash point 127 °F
storage temp. Inert atmosphere,Room Temperature
solubility soluble in Chloroform, Methanol
form clear liquid
color Colorless to Almost colorless
Specific Gravity 0.919
Water Solubility Insoluble
Sensitive Moisture Sensitive
BRN 1747401
CAS DataBase Reference 78-09-1(CAS DataBase Reference)
FDA UNII W2P2570012
NIST Chemistry Reference Ethane, 1,1',1'',1'''-[methanetetrayltetrakis(oxy)]tetrakis-(78-09-1)
EPA Substance Registry System Ethane, 1,1',1'',1'''-[methanetetrayltetrakis(oxy)]tetrakis- (78-09-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS02,GHS07
Signal word  Warning
Hazard statements  H315-H319-H226
Precautionary statements  P241-P280a-P303+P361+P353-P501a-P210-P233-P240-P241+P242+P243-P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P370+P378-P403+P235-P501
Hazard Codes  Xi,F
Risk Statements  10-36/37/38
Safety Statements  37/39-26-16-36-24/25
RIDADR  UN 3272 3/PG 3
WGK Germany  3
21
HazardClass  3
PackingGroup  III
HS Code  29209010
NFPA 704
2
2 0

Tetraethyl orthocarbonate price More Price(17)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 163627 Tetraethyl orthocarbonate 97% 78-09-1 5g $32.34 2024-03-01 Buy
Sigma-Aldrich 163627 Tetraethyl orthocarbonate 97% 78-09-1 25g $97.2 2024-03-01 Buy
TCI Chemical T1107 Tetraethoxymethane >97.0%(GC) 78-09-1 5mL $45 2024-03-01 Buy
TCI Chemical T1107 Tetraethoxymethane >97.0%(GC) 78-09-1 25mL $132 2024-03-01 Buy
Alfa Aesar A17835 Tetraethyl orthocarbonate 97+% 78-09-1 25g $163 2024-03-01 Buy
Product number Packaging Price Buy
163627 5g $32.34 Buy
163627 25g $97.2 Buy
T1107 5mL $45 Buy
T1107 25mL $132 Buy
A17835 25g $163 Buy

Tetraethyl orthocarbonate Chemical Properties,Uses,Production

Chemical Properties

clear colorless liquid

Uses

Tetraethyl Orthocarbonate is used in the synthesis of chemokine receptor-5 inhibitors against HIV-1, benzobisoxazoles and in the preparation of organic semiconductors. It is also employed in the synthesis of 2,7-dimethylene-1,4,6,9-tetraoxaspiro[4,4]nonane and in the synthesis of cross linked poly(orthocarbonate)s used as organic solvent absorbent.

Purification Methods

Likely impurities are hydrolysis products. Shake the orthocarbonate with brine (saturated NaCl, dilute with a little Et2O if amount of material is small) and dry (MgSO4). The organic layer is filtered off and evaporated, and the residue is distilled through a helices packed fractionating column with a total reflux partial take-off head. All distillations can be done at atmospheric pressure in an inert atmosphere (e.g. N2). [Roberts & McMahon Org Synth Coll Vol IV 457 1963, Connolly & Dyson J Chem Soc 828 1937, Tieckelmann & Post J Org Chem 13 266 1948, for review see Kantlehner et al. Justus Liebigs Ann Chem 507 207 1982, Beilstein 3 IV 6.]

64-17-5
76-06-2
78-09-1
Synthesis of Tetraethyl orthocarbonate from Ethanol and Trichloronitromethane
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View Lastest Price from Tetraethyl orthocarbonate manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Tetraethyl orthocarbonate pictures 2024-03-28 Tetraethyl orthocarbonate
78-09-1
US $0.00 / Kg/Drum 1KG 99% 500mt Jinan Finer Chemical Co., Ltd
Tetraethyl orthocarbonate pictures 2023-09-15 Tetraethyl orthocarbonate
78-09-1
US $100.00 / bag 1bag 99 5000 Hebei Fengqiang Trading Co., LTD
Tetraethyl orthocarbonate pictures 2023-08-23 Tetraethyl orthocarbonate
78-09-1
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
ORTHOCARBONIC ACID TETRAETHYL ESTER TETRAETHOXYMETHANE TETRAETHYL ORTHOCARBONATE 1-(Triethoxymethoxy)ethane 1,1’,1’’,1’’’-[methanetetrayltetrakis(oxy)]tetrakis-ethan Tetraehtylorthocarbonate Tetraethyl-2-carbonate Tetraethyl orthocarbonate, 98+% Ethane, 1,1,1,1-methanetetrayltetrakis(oxy)tetrakis- Tetraethyl orthocarbonate 98%min CAS[78-09-1 ethyl orthocarbonate triethoxymethoxy-ethane Tetraethyl orthocarbonate (TEOC) TRIETHYL ORTHOCARBONATE Tetraethyl orthocarbonate,97% Tetraethyl orthocarb ETHYL ORTHOCARBONATE CAS NO Tetraethyl orthocarbonate, 97% 5GR The original four ethyl carbonate Tetraethyl orthocarbonate 97% TetraethyI orthocarbonate Tetraethyl orthocarbonate≥ 99% (GC) [methanetetrayltetrakis(oxy)]tetrakis- Ethane, 1,1‘,1‘‘,1‘‘‘- Teraethyl orthocarbonate Four ethyl carbonate Tetraethyl orthocarbonate 78-09-1 78-09-1 1978-09-01 78-090-1 1978-09-1 C9H20O4 COC2H54 C2H5O4C Building Blocks Oxygen Compounds Organic Building Blocks Acetals/Ketals/Ortho Esters Acetals/Ketals/Ortho Esters Organic Building Blocks Oxygen Compounds 78-09-1