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LITHIUM NITRIDE

LITHIUM NITRIDE
LITHIUM NITRIDE structure
CAS No.
26134-62-3
Chemical Name:
LITHIUM NITRIDE
Synonyms
Li3-N;LITHIUM NITRIDE;Nitrilotrilithium;Trilithionitrogen;Nitrilotrislithium;trilithium nitride;LITHIUM NITRIDE, ANH;lithiumnitride(li3n);Li3N99.5%(metalsbasis);Lithium nitride (Li3N)
CBNumber:
CB4705682
Molecular Formula:
Li3N
Formula Weight:
34.83
MOL File:
26134-62-3.mol

LITHIUM NITRIDE Properties

Melting point:
845°C
Density 
1.3 g/mL at 25 °C(lit.)
solubility 
Insoluble in organic solvents.
form 
Powder
color 
reddish-brown
Specific Gravity
1.38
Water Solubility 
reacts with H2O, yielding LiOH and ammonia; insoluble polyethers [HAW93]
Sensitive 
Moisture Sensitive
CAS DataBase Reference
26134-62-3(CAS DataBase Reference)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  F,C
Risk Statements  11-14-29-34-14/15
Safety Statements  16-22-26-27-36/37/39-45
RIDADR  UN 2806 4.3/PG 1
WGK Germany  3
TSCA  Yes
HazardClass  4.3
PackingGroup  I
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H260 In contact with water releases flammable gases which may ignite spontaneously Substances And Mixtures Which, In Contact With Water,Emit Flammable Gases Category 1 Danger P223, P231+P232, P280, P335+ P334,P370+P378, P402+P404, P501
H314 Causes severe skin burns and eye damage Skin corrosion/irritation Category 1A, B, C Danger P260,P264, P280, P301+P330+ P331,P303+P361+P353, P363, P304+P340,P310, P321, P305+ P351+P338, P405,P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
Precautionary statements:
P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P231+P232 Handle under inert gas. Protect from moisture.
P303+P361+P353 IF ON SKIN (or hair): Remove/Take off Immediately all contaminated clothing. Rinse SKIN with water/shower.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P370+P378 In case of fire: Use … for extinction.
P405 Store locked up.
P422 Store contents under …

LITHIUM NITRIDE price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 399558 Lithium nitride 80 mesh, ≥99.5% 26134-62-3 5g $47.1 2018-11-13 Buy
Sigma-Aldrich 399558 Lithium nitride 80 mesh, ≥99.5% 26134-62-3 10g $81.9 2018-11-13 Buy
Alfa Aesar 035479 Lithium nitride, 99.4% (metals basis) 26134-62-3 10g $56.2 2018-11-16 Buy
Alfa Aesar 035479 Lithium nitride, 99.4% (metals basis) 26134-62-3 50g $218 2018-11-16 Buy
Strem Chemicals 93-0340 Lithium nitride (99.5%-Li) 26134-62-3 5g $29 2018-11-13 Buy

LITHIUM NITRIDE Chemical Properties,Uses,Production

Chemical Properties

reddish brown crystal(s) or freely flowing powder(s); slowly decomposed by atmospheric moisture; ruby red; hexagonal, a=0.3658 nm, c=0.3882nm; conductivity, 227°C, 0.04 (ohm· cm)?1; one of most effective solid ionic conductors; can be prepared by direct reaction of Li and nitrogen; used as a nitriding agent in metallurgy [HAW93] [STR93] [CIC73] [KIR81]

General Description

A reddish brown powder. Insoluble in most organic solvents. Used in metallurgy and chemical synthesis.

Reactivity Profile

LITHIUM NITRIDE is a strongly basic reducing agent. Incompatible with oxidizing agents such as atmospheric oxygen. Violently incompatible with acids, particularly oxidizing acids. Reacts violently with copper(I) chloride to produce metallic copper [Mellor, 1940, vol.8, 100]. Reacts exothermically with silicon tetrafluoride, leading to explosion [Chem. Brit., 1979, 15, 282-283].

Health Hazard

Inhalation or contact with vapors, substance or decomposition products may cause severe injury or death. May produce corrosive solutions on contact with water. Fire will produce irritating, corrosive and/or toxic gases. Runoff from fire control may cause pollution.

Fire Hazard

Produce flammable gases on contact with water. May ignite on contact with water or moist air. Some react vigorously or explosively on contact with water. May be ignited by heat, sparks or flames. May re-ignite after fire is extinguished. Some are transported in highly flammable liquids. Runoff may create fire or explosion hazard.

Safety Profile

A powerful reducing agent. Upon contact with moisture, it decomposes into lithmm hydroxide, lithium compounds, and ammonia. The powder may ignite spontaneously in moist air. Flammable at elevated temperatures; ignites and burns intensely in air. Violent reaction with dicon tetrafluoride, copperp) chloride + heat. To fight fire, use dry chemical, sand, graphite; avoid use of water or carbon tetrachloride. When heated to decomposition it emits very toxic fumes of Liz0 and NOx. Used as a strong reducing agent in organic synthesis and a solid electrolyte in lithium batteries. See also LITHIUM COMPOUNDS and NITRIDES.

LITHIUM NITRIDE Preparation Products And Raw materials

Raw materials

Preparation Products


LITHIUM NITRIDE Suppliers

Global( 45)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Mainchem Co., Ltd.
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J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
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Alfa Aesar 400-610-6006; 021-67582000
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