Carbohydrazide
- CAS No.
- 497-18-7
- Chemical Name:
- Carbohydrazide
- Synonyms
- CARBAZIDE;Carbonohydrazide;1,3-DIAMINOUREA;Carbodihydrazide;carbonyl dihydrazine;Cabazide;Karbazid;CARBOHYDRZIDE;CARBOHYDRAZIDE;1,3-diamino-ure
- CBNumber:
- CB4752419
- Molecular Formula:
- CH6N4O
- Molecular Weight:
- 90.08
- MDL Number:
- MFCD00007591
- MOL File:
- 497-18-7.mol
- MSDS File:
- SDS
| Melting point | 150-153 °C (lit.) |
|---|---|
| Boiling point | 167.26°C (rough estimate) |
| Density | 1.02 |
| vapor pressure | 0Pa at 25℃ |
| refractive index | 1.4164 (estimate) |
| storage temp. | Keep in dark place,Inert atmosphere,2-8°C |
| solubility | DMSO (Slightly), Water (Slightly) |
| form | Crystalline Powder |
| pka | 11.81±0.20(Predicted) |
| color | White |
| Water Solubility | Soluble in water. |
| Merck | 14,1804 |
| BRN | 1747069 |
| Stability | Stable, but may explode if heated. Incompatible with strong acids, strong oxidizing agents. |
| InChIKey | XEVRDFDBXJMZFG-UHFFFAOYSA-N |
| LogP | -2.94 at 21.6℃ |
| CAS DataBase Reference | 497-18-7(CAS DataBase Reference) |
| EWG's Food Scores | 1 |
| FDA UNII | W8V7FYY4WH |
| NIST Chemistry Reference | Carbonic dihydrazide(497-18-7) |
| EPA Substance Registry System | Carbohydrazide (497-18-7) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |   GHS07,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H302-H315-H317-H411 | |||||||||
| Precautionary statements | P273-P280-P301+P312+P330-P302+P352 | |||||||||
| Hazard Codes | Xi,N,Xn | |||||||||
| Risk Statements | 5-22-51/53-36/37/38-20/21/22-43-38 | |||||||||
| Safety Statements | 61-36/37/39-36/37 | |||||||||
| RIDADR | UN3077 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | FF2625000 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 9 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29280000 | |||||||||
| NFPA 704 |
|
Carbohydrazide price More Price(20)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | C11006 | Carbohydrazide 98% | 497-18-7 | 25g | $57.9 | 2024-03-01 | Buy |
| Sigma-Aldrich | C11006 | Carbohydrazide 98% | 497-18-7 | 100g | $162 | 2024-03-01 | Buy |
| TCI Chemical | C0803 | Carbohydrazide >98.0%(T) | 497-18-7 | 25g | $53 | 2024-03-01 | Buy |
| TCI Chemical | C0803 | Carbohydrazide >98.0%(T) | 497-18-7 | 500g | $272 | 2024-03-01 | Buy |
| Alfa Aesar | A11145 | Carbohydrazide 97% | 497-18-7 | 25g | $45.65 | 2024-03-01 | Buy |
Carbohydrazide Chemical Properties,Uses,Production
Product Features
Carbohydrazide is a white crystalline thin and short columnar crystal or white powder at room temperature. It is insoluble in alcohol, easily soluble in water with dissolution absorbing heat. It is insoluble in alcohol, ether, and benzene. Owing to that, it is a kind of derivative of hydrazine and thus having strong reduction ability. It is non-toxic, and can replace hydrazine and oximes. It has a broad range of application in industry. For example, it can be used as the oxygen scavenging agent of boiler water in the field of water treatment and is regarded as most advanced materials for oxygen scavenging of boiler water. It has a low toxicity and high melting point with its deoxidizing efficiency being far greater than the current materials used and is a idea product for both safety and environmental protection; it can also be used as a rocket propellant components; moreover, owing to that its hydrogen atoms attached to the nitrogen atom is easily substituted by other groups, it can be used as the cross-linking agents of elastic fibers in the textile field, the formaldehyde scavenger, as well as the antioxidant of carotene pigment. In addition, adding an appropriate amount of carbohydrazide to the phenol fungicides containing can play a role on preventing discoloration and rancidity. As a chemical raw material and chemical industry intermediates, it is widely used in medicine, herbicides, plant growth regulators, dyes and other industries.
Oxygen scavenger of the boiler water
When acting as the oxygen scavenger of boiler water, carbohydrazide may be directly added into the water while its aqueous solution can also be used. The usage amount of carbohydrazide for scavenging 1mol O2 is 0.5mol, and should be appropriately in excess. The proper temperature range is 87.8-176.7 ℃. The optimal time for applying carbohydrazide is after the thermal scavenging of oxygen. The reaction of oxygen and carbohydrazide is as follows: CON4H6 + 2O2 = 2N2 + 3H2O + CO2
Reference quality standards
Item Index
Appearance: fine white crystals or white short columnar crystals
Purity% ≥98.0%
Free hydrazine ≤250.0mg/L
Loss of weight by drying ≤0.2%
PH (12% aqueous solution) 8.45 ± 1.25
Uses
It is widely used in the production of pharmaceuticals, herbicides, plant growth regulators, dyes, etc.(1) carbohydrazide is a derivative of hydrazine with a strong reduction. It can be not only used as the intermediates for producing energy-containing materials, but also can be used directly as the components of explosives and propellants. (2) it can be used as the preservative of refinery equipment and can also be used as the oxygen scavenger of boiler water treatment agent (3) It can be used as the cross-linking agent of the elastic fiber in the field of chemical fiber industry (4) it can be used as the chemical raw materials and chemical industrial intermediates and is widely used in medicine, herbicides, plant growth regulators, dyes and other industries.
It can be used as the component of the rocket propellant, the stabilizer of color development and soap quality, the antioxidants of rubber, the oxygen scavenger of boiler water, and the passivation agent of metal.
Carbohydrazide is a derivative of hydrazine with a strong reduction. It can be used as the intermediate of producing energy-containing materials and also be used directly for the components of explosives and rocket propellant. It can also be used as the oxygen scavenger of boiler water and is the most advanced materials for scavenging oxygen of boiler water in the world today. It has low toxicity, high melting point and a deoxidation efficiency being far greater than the materials currently used. It is an ideal product for both safety and environmental protection. In addition, it can be used as the cross-linking agent of the elastic fiber in the field of chemical fiber industry. It can also be used as the chemical raw materials and chemical industrial intermediates and is widely used in medicine, herbicides, plant growth regulators, dyes and other industries.
The above information is edited by the chemicalbook of Dai Xiongfeng.
Category
toxic substances
Toxicity grading
poisoning
Acute toxicity
Intraperitoneal-mouse LD50: 167 mg/kg; Intravenous-Mouse LD50: 120 mg/kg.
Explosive and hazardous characteristics
it is explosive upon heating; it can generate explosive diazide compound upon reaction with nitrous acid.
Flammability and hazard characteristics
thermal decomposition into toxic nitric oxide gas.
Storage characteristics
Treasury: ventilation, low-temperature and drying; it should be stored separately from strong acids and strong oxidants.
Extinguishing agent
Water, carbon dioxide, dry powder, foam.
Chemical Properties
white powder
Uses
Organic intermediate and photographic chemical.
Uses
Carbohydrazide is widely utilized as a curing agent for epoxide-type resins and as an oxygen scrubber in boiler systems. It is applied in photography to stabilize color developers that produce images of the azo-methine and azine classes. It is used to develop ammunition propellants and stabilize soaps. It is also a useful reagent in organic synthesis.
Definition
ChEBI: A carbohydrazide obtained by formal condensation between hydrazinecarboxylic acid and hydrazine.
Flammability and Explosibility
Non flammable
Safety Profile
Poison by intravenous and intraperitoneal routes. Reacts with nitrous acid to form the explosive carbonic dazide. When heated to decomposition it emits toxic fumes of NOx.
Carbohydrazide Preparation Products And Raw materials
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Jinan Finer Chemical Co., Ltd | +86-531-88989536 +86-15508631887 | sales@finerchem.com | China | 2967 | 58 |
| Jinan Qinmu Fine Chemical Co.,Ltd. | +8618660799346 | sales@qinmuchem.com | China | 1009 | 58 |
| Shanghai Quedan biology science and technology co., ltd | +86-13004146052 | lnzc@quedan.com.cn | China | 1060 | 58 |
| Hebei Yanxi Chemical Co., Ltd. | +8617531190177 | peter@yan-xi.com | China | 5993 | 58 |
| Hebei Dangtong Import and export Co LTD | +8615632927689 | admin@hbdangtong.com | China | 991 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 7845 | 58 |
| Hebei Zhuanglai Chemical Trading Co.,Ltd | +8613343047651 | admin@zlchemi.com | China | 476 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21691 | 55 |
| Hangzhou FandaChem Co.,Ltd. | 008657128800458; +8615858145714 | fandachem@gmail.com | China | 9348 | 55 |
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View Lastest Price from Carbohydrazide manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-26 | Carbohydrazide
497-18-7
|
US $0.00 / Kg/Bag | 1KG | 99% | 500mt/year | Jinan Finer Chemical Co., Ltd | |
 |
2024-04-26 | Carbohydrazide
497-18-7
|
US $10.00-1.00 / kg | 1kg | 99% | 600tons | Hebei Dangtong Import and export Co LTD | |
 |
2024-04-26 | Carbohydrazide
497-18-7
|
US $5.00-1.00 / kg | 1kg | 99% | 300tons | Hebei Dangtong Import and export Co LTD |
-
- Carbohydrazide
497-18-7
- US $0.00 / Kg/Bag
- 99%
- Jinan Finer Chemical Co., Ltd
-
- Carbohydrazide
497-18-7
- US $10.00-1.00 / kg
- 99%
- Hebei Dangtong Import and export Co LTD
-
- Carbohydrazide
497-18-7
- US $5.00-1.00 / kg
- 99%
- Hebei Dangtong Import and export Co LTD