ChemicalBook >> CAS DataBase List >>4,5-DIMETHOXY-2-NITROBENZYL BROMIDE

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE

CAS No.
53413-67-5
Chemical Name:
4,5-DIMETHOXY-2-NITROBENZYL BROMIDE
Synonyms
6-NITROVERATRYL BROMIDE;1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene;-4,5-dimethoxy-2-nitrobenzene;-4,5-dimethoxy-2-nitrobenzene;4,5-dimenoxy-2-nitrobenzyl bromide;3,4-Dimethoxy-6-nitrobenzyl bromide;4,5-DIMETHOXY-2-NITROBENZYL BROMIDE;4,5-Dimethoxy-2-nitrobenzyl bromide 95%;4,5-Dimethoxy-2-nitro-1-bromomethylbenzene;1-(bromomethyl)-2-nitro-4,5-dimethoxybenzene
CBNumber:
CB4762285
Molecular Formula:
C9H10BrNO4
Molecular Weight:
276.08
MDL Number:
MFCD00192064
MOL File:
53413-67-5.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE Properties

Melting point 131-133 °C (lit.)
Boiling point 372.3±37.0 °C(Predicted)
Density 1.544
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
form Crystalline Powder or Needles
color Yellow to brown
Sensitive Lachrymatory

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
Hazard Codes  C
Risk Statements  34
Safety Statements  22-26-27-36/37/39-45
RIDADR  UN 3261 8/PG 2
WGK Germany  3
HazardClass  8
PackingGroup  III
HS Code  29093090

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE price More Price(21)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 392855 4,5-Dimethoxy-2-nitrobenzyl bromide 97% 53413-67-5 1g $124 2024-03-01 Buy
Sigma-Aldrich 392855 4,5-Dimethoxy-2-nitrobenzyl bromide 97% 53413-67-5 5g $196.8 2024-03-01 Buy
Biosynth Carbosynth FB139514 4,5-Dimethoxy-2-nitrobenzyl bromide 53413-67-5 5G $550 2021-12-16 Buy
AK Scientific 7598AB 1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene 53413-67-5 5g $271 2021-12-16 Buy
Biosynth Carbosynth FB139514 4,5-Dimethoxy-2-nitrobenzyl bromide 53413-67-5 2g $320 2021-12-16 Buy
Product number Packaging Price Buy
392855 1g $124 Buy
392855 5g $196.8 Buy
FB139514 5G $550 Buy
7598AB 5g $271 Buy
FB139514 2g $320 Buy

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE Chemical Properties,Uses,Production

Uses

1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene is a useful research chemical.

Uses

4,5-Dimethoxy-2-nitrobenzyl bromide (DMNB bromide, 6-nitroveratryl bromide) is suitable reagent used in the synthesis of N-(4,5-dimethoxy-2-nitrobenzyl)vanillylamine which forms caged vanilloid. It may be used in the synthesis of the following:

  • 4-(4′,5′-dimethoxy-2-nitrobenzyloxy)benzaldehyde, a DMNB-caged aldehyde
  • N-[4-[(4,5-dimethoxy-2-nitrobenzyl)oxy]-3-methoxybenzyl]acetamide
  • caged derivative of pyridostatin ([C]-PDS)
  • photosensitive polyimide (PI-DMNB)
  • caged β-ecdysone
  • 4-tert-butyldimethylsilyloxy-1-(2-deoxy-3,5-di-O-toluoyl-β-D-ribofuranosyl)-2-(6-nitroveratrylthio)-1H-benzimidazole, an intermediate in synthesis of phosphoramidite bearing 4-hydroxy-2-mercaptobenzimidazole (SBNV) nucleobase
  • alkylation of dihydrofluorescein
  • 4-(4′,5′-Dimethoxy-2′-nitrobenzyloxy)benzaldehyde

General Description

4,5-Dimethoxy-2-nitrobenzyl bromide (DMNBB, 1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene) is a 4,5-dimethoxy-2-nitrobenzyl derivative. 4,5-Dimethoxy-2-nitrobenzyl (DMNB) group of DMNBB is used as a photolabile protecting group in caging technology to develop pro-drugs. Synthesis of 1-(bromomethyl)-4,5-dimethoxy-2-nitrobenzene by using 6-nitroveratraldehyde as starting reagent has been reported.

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

4,5-DIMETHOXY-2-NITROBENZYL BROMIDE Suppliers

Global( 77)Suppliers
Supplier Tel Email Country ProdList Advantage
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63711 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 47465 58
Fuxin Pharmaceutical
+86-021-021-50872116 +8613122107989 contact@fuxinpharm.com China 10297 58
Zhengzhou Alfa Chemical Co.,Ltd
+8618530059196 sale04@alfachem.cn China 12477 58
Career Henan Chemica Co
+86-0371-86658258 15093356674; laboratory@coreychem.com China 30255 58
WinWin Chemical CO., Limited
+86-0086-577-64498589 +86-15355981851 sales@win-winchemical.com China 13854 58
Nanjing Fred Technology Co., Ltd
+86-25-84696168 +86-15380713688 Austin@fredbio.com China 2449 58
LEAPCHEM CO., LTD.
+86-852-30606658 market18@leapchem.com China 43348 58
Aladdin Scientific
+1-833-552-7181 sales@aladdinsci.com United States 57511 58
Amadis Chemical Company Limited
571-89925085 sales@amadischem.com China 131981 58
4,5-DIMETHOXY-2-NITROBENZYL BROMIDE 4,5-Dimethoxy-2-nitrobenzyl bromide 95% 1-(bromomethyl)-2-nitro-4,5-dimethoxybenzene 4,5-dimenoxy-2-nitrobenzyl bromide 3,4-Dimethoxy-6-nitrobenzyl bromide 4,5-Dimethoxy-2-nitro-1-bromomethylbenzene -4,5-dimethoxy-2-nitrobenzene JR-13611, 1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene, 97% Benzene, 1-(bromomethyl)-4,5-dimethoxy-2-nitro- -4,5-dimethoxy-2-nitrobenzene 6-NITROVERATRYL BROMIDE 1-(Bromomethyl)-4,5-dimethoxy-2-nitrobenzene 53413-67-5 O2NC6H2OCH32CH2Br Organic Building Blocks Nitrogen Compounds Nitro Compounds Building Blocks