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Ethyl 2-phenylacetoacetate

Ethyl 2-phenylacetoacetate structure

CAS No.: 5413-05-8

Chemical Name:: Ethyl 2-phenylacetoacetate

Synonyms: ETHYL 3-OXO-2-PHENYLBUTANOATE;2-Phenylacetoacetic acid ethyl ester;2-Phenylacetoacetate;ethyl 2-phenyl-3-oxobutanoate;Benzeneacetic acid, a-acetyl-, ethyl ester;a-acetyl-;99% Pure BMK;Bmk powder/oil;Ethyl 2-phenylacetoa;BMK Glycidate BMK Powder

CBNumber:: CB4772521

Molecular Formula:: C12H14O3

Molecular Weight:: 206.24

MDL Number:: MFCD00040490

MOL File:: 5413-05-8.mol

MSDS File:: SDS

Last updated:2024-04-17 18:50:11

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Ethyl 2-phenylacetoacetate Properties

Melting point	140-144°C/10mm
Boiling point	140-144°C 10mm
Density	1,085 g/cm³
refractive index	1.5130
Flash point	140-144°C/10mm
solubility	Chloroform (Slightly), Methanol (Slightly)
form	Oil
pka	10.69±0.46(Predicted)
color	Colourless to Pale Brown
BRN	1912655
InChI	InChI=1S/C12H14O3/c1-3-15-12(14)11(9(2)13)10-7-5-4-6-8-10/h4-8,11H,3H2,1-2H3
InChIKey	PWRUKIPYVGHRFL-UHFFFAOYSA-N
SMILES	C(C(=O)C)(C(=O)OCC)C1C=CC=CC=1

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS07

Signal word

Warning

Hazard statements

H302-H315-H319-H335

Precautionary statements

P261-P280-P301+P312-P302+P352-P305+P351+P338

Safety Statements

24/25

NFPA 704

	1
0		0

Ethyl 2-phenylacetoacetate price More Price(9)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Usbiological	E8609-67	Ethyl 2-Phenylacetoacetate	5413-05-8	5g	$389	2021-12-16	Buy
AK Scientific	6701CA	Ethyl3-oxo-2-phenylbutanoate	5413-05-8	5g	$417	2021-12-16	Buy
American Custom Chemicals Corporation	COR0003957	ETHYL 2-PHENYLACETOACETATE 95.00%	5413-05-8	1G	$1030.84	2021-12-16	Buy
American Custom Chemicals Corporation	COR0003957	ETHYL 2-PHENYLACETOACETATE 95.00%	5413-05-8	5G	$4244.63	2021-12-16	Buy
American Custom Chemicals Corporation	COR0003957	ETHYL 2-PHENYLACETOACETATE 95.00%	5413-05-8	10G	$7882.88	2021-12-16	Buy

Product number	Packaging	Price	Buy
E8609-67	5g	$389	Buy
6701CA	5g	$417	Buy
COR0003957	1G	$1030.84	Buy
COR0003957	5G	$4244.63	Buy
COR0003957	10G	$7882.88	Buy

Ethyl 2-phenylacetoacetate Chemical Properties,Uses,Production

Uses

Ethyl 2-Phenylacetoacetate is used in preparation of iridium polysubstituted quinoline diketonate complex and application as OLED.

Synthesis

A flame-dried flask was charged with 10 mmol (1 equiv) of sublimed potassium tert-butoxide in anhydrous DMF (50 mL) at room temperature under argon. Then, 10 mmol (1 equiv) of freshly distilled EAA was added to the reaction mixture and stirred for 30 min at 0 °C, followed by dropwise addition of diaryliodonium salt (4 mmol, 0.4 equiv to EAA) in 10 mL of DMF. Reaction was left stirring at room temperature for the time mentioned in the table. After confirming complete consumption of iodonium salt (by LCMS), to the reaction mixture was added 1 M HCl in one portion to bring the pH to around 5.0. The crude was extracted with diethyl ether until the aqueous layer was devoid of product. The organic layer was dried over sodium sulfate, and solvent was removed in vacuo. The product was purified by flash column chromatography (0.5-2% of hexane in ethyl acetate). Ethyl 2-phenylacetoacetate 1H NMR (500 MHz, CDCl3) δ 13.13 (s, 0.3H), 7.41-7.27 (m, 4H), 7.18-7.13 (m, 1H), 4.69 (s, 0.7H), 4.27-4.15 (m, 2H), 2.19 (s, 2H), 1.86 (s, 1H), 1.28 (t, J = 7.1 Hz, 2H), 1.18 (t, J = 7.1 Hz, 1H). 13C NMR (126 MHz, CDCl3) δ 201.7, 174.0, 172.7, 168.6, 135.4, 132.8, 131.4, 129.4, 129.0, 128.4, 128.1, 127.0, 104.5, 65.9, 61.8, 60.8, 28.9, 20.0, 14.3, 14.2. HRMS (ESI-TOF) m/z: [M + H]+ calcd for C12H14O3 207.1016; found 207.1018.
synthesis of Ethyl 2-phenylacetoacetate.jpg

Ethyl 2-phenylacetoacetate synthesis

Synthesis of Ethyl 2-phenylacetoacetate from Acetic anhydride and Ethyl phenylacetate

Ethyl 2-phenylacetoacetate Preparation Products And Raw materials

Raw materials

Preparation Products

Ethyl 2-phenylacetoacetate Suppliers

Global( 175)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Shanghai Longyu Biotechnology Co., Ltd.	+8615821988213	info@longyupharma.com	China	2531	58
Dorne Chemical Technology co. LTD	+86-13583358881 +86-18560316533	Ethan@dornechem.com	China	294	58
Wuhan wingroup Pharmaceutical Co., Ltd	+86-13296627870; +8613296627870	info@whwingroup.com	China	703	58
Firsky International Trade (Wuhan) Co., Ltd	+8615387054039	admin@firsky-cn.com	China	436	58
Shanghai Affida new material science and technology center	+undefined15081010295	2691956269@qq.com	China	359	58
Hebei Dangtong Import and export Co LTD	+8615632927689	admin@hbdangtong.com	China	991	58
Anhui Yiao New Material Technology Co., Ltd	+86-199-55145978 +8619955145978	sales8@anhuiyiao.com	China	253	58
Xiamen Wonderful Bio Technology Co., Ltd.	+8613043004613	Sara@xmwonderfulbio.com	China	305	58
Shaanxi Haibo Biotechnology Co., Ltd	+undefined18602966907	qinhe02@xaltbio.com	China	1000	58
Shandong Huisheng Import & Export Co., Ltd.	+86-13176845580 +86-13176845580	da@zhongda-biotech.com	China	248	58

Supplier	Advantage
Shanghai Longyu Biotechnology Co., Ltd.	58
Dorne Chemical Technology co. LTD	58
Wuhan wingroup Pharmaceutical Co., Ltd	58
Firsky International Trade (Wuhan) Co., Ltd	58
Shanghai Affida new material science and technology center	58
Hebei Dangtong Import and export Co LTD	58
Anhui Yiao New Material Technology Co., Ltd	58
Xiamen Wonderful Bio Technology Co., Ltd.	58
Shaanxi Haibo Biotechnology Co., Ltd	58
Shandong Huisheng Import & Export Co., Ltd.	58

View Lastest Price from Ethyl 2-phenylacetoacetate manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2024-04-25	Ethyl 2-phenylacetoacetate 5413-05-8	US $10.00-10.00 / ASSAYS	1ASSAYS	99%	10 tons	Dorne Chemical Technology co. LTD
2024-04-25	Ethyl 2-Phenylacetoacetate 5413-05-8	US $10.00-10.00 / ASSAYS	1ASSAYS	99%	10 tons	Dorne Chemical Technology co. LTD
2024-04-25	Ethyl 2-phenylacetoacetate 5413-05-8	US $0.00 / G	1G	99%	20	CONTIDE BIOTECH CO.,LTD

Ethyl 2-phenylacetoacetate
5413-05-8
US $10.00-10.00 / ASSAYS
99%
Dorne Chemical Technology co. LTD

Ethyl 2-Phenylacetoacetate
5413-05-8
US $10.00-10.00 / ASSAYS
99%
Dorne Chemical Technology co. LTD

Ethyl 2-phenylacetoacetate
5413-05-8
US $0.00 / G
99%
CONTIDE BIOTECH CO.,LTD

5413-05-8(Ethyl 2-phenylacetoacetate)Related Search:

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ETHYL 2-PHENYLACETOACETATE Benzeneacetic acid, .alpha.-acetyl-, ethyl ester 2-Phenyl-3-oxobutanoic acid ethyl ester 2-Phenyl-3-oxobutyric acid ethyl ester Ethyl a-acetylbenzeneacetate (2R)-3-oxo-2-phenylbutanoic acid ethyl ester high quality 2-PHENYLACETOACETATE CAS 5413-05-8 5413-05-8 2-Phenylacetoacetic acid ethyl ester BMK Glycidate BMK Powder BMK Powder ethyl 3-oxo-2-phenylbutanoate BMK Glycidate ethyl 3-oxo-2-phenylbutanoate Ethyl 2-phenylacetoacetate/New bmk ETHYL 2-PHENYLACETOACETATE CAS 5413-05-8 Benzeneacetic acid, α-acetyl-, ethyl ester Ethyl 2-phenylacetoacetate powder a-acetyl- ETHYL 2-PHENYLACETOACETATE bmk Ethyl 2-phenylacetoa NEW BMK Glycidates Powder ETHYL 2-PHENYLACETOACETATE Basic information BMK ETHYL 2-PHENYLACETOACETATE ETHYL 2-PHENYLACETOACETAT High purity Ethyl 2-phenylacetoacetate 99% Pure BMK Bmk powder/oil ETHYL 2-PHENYLACETOACETATE/BMK POWDER 2-Phenyl-3-oxobutyric acid ethyl High Quality New BMK Glycidate CAS 5413-05-8 BMK Oil Ethyl 3-oxo-4-phenylbutanoate The latest BMK16648 replacementThe latest PMK13605replacement New BMK Glycidate Powder Oil CAS 5413 05 8 cas5449 12 7 BMK CAS 5413-05-8,ruby@whkmbk.com 2-Phenylacetoacetic acid ethyl ester ETHYL 3-OXO-2-PHENYLBUTANOATE Benzeneacetic acid, a-acetyl-, ethyl ester ethyl 2-phenyl-3-oxobutanoate 2-Phenylacetoacetate Ethyl 2-Phenylacetoacetate(BMK Oil) bmk powder/Ethyl 2-phenylacetoacetate Ethyl 2-phenylacetoacetatee BMK Ethyl 3-oxo-4-phenylbutanoate 5413-05-8 5143-05-8 Aromatics Compounds 5413-05-8 1