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ISOPROPENYLMAGNESIUM BROMIDE

CAS No.
13291-18-4
Chemical Name:
ISOPROPENYLMAGNESIUM BROMIDE
Synonyms
IsopropenyL;Bromoisopropenylmagnesium;ISOPROPENYLMAGNESIUM BROMIDE;1-Methylvinylmagnesium bromide;1-Methylethenylmagnesium bromide;bromo(1-methylethenyl)-Magnesium;(1-Methylethenyl)magnesium bromide;IsopropenylMagnesiuM broMide soluti;Isopropenylmagnesium bromide(1M THF);isopropenylmagnesium bromide solution
CBNumber:
CB4783309
Molecular Formula:
C3H5BrMg
Molecular Weight:
145.28
MDL Number:
MFCD00192240
MOL File:
13291-18-4.mol
Last updated:2023-04-23 13:52:06

ISOPROPENYLMAGNESIUM BROMIDE Properties

Melting point 102-104 °C
Boiling point 67 °C
Density 0.94 g/mL at 20 °C
Flash point −36 °F
storage temp. 2-8°C
form Crystalline Powder
color White to yellow to orange
BRN 3587297
InChIKey LFTYALBVGVNGLI-UHFFFAOYSA-M

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS07,GHS08
Signal word  Danger
Hazard statements  H225-H260-H302-H314-H335-H351
Precautionary statements  P210-P231+P232-P280-P370+P378-P402+P404-P403+P235
Hazard Codes  F,C
Risk Statements  11-14/15-34-40-37-19-14
Safety Statements  26-30-36/37/39-43-45-7/8-16
RIDADR  UN 3399 4.3/PG 1
WGK Germany  1
1-3-10-34
HS Code  29319090

ISOPROPENYLMAGNESIUM BROMIDE price More Price(9)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 419567 Isopropenylmagnesium bromide solution 0.5 M in THF 13291-18-4 100ml $190 2024-03-01 Buy
Sigma-Aldrich 419567 Isopropenylmagnesium bromide solution 0.5 M in THF 13291-18-4 800ml $352 2024-03-01 Buy
Sigma-Aldrich 772836 Isopropenylmagnesium bromide solution 1.0 M in 2-methyltetrahydrofuran 13291-18-4 25ml $138 2024-03-01 Buy
Sigma-Aldrich 772836 Isopropenylmagnesium bromide solution 1.0 M in 2-methyltetrahydrofuran 13291-18-4 100ml $209 2024-03-01 Buy
GFS CHEMICALS 17523 ISOPROPENYLMAGNESIUMBROMIDE,0.5MinTETRAHYDROFURAN 13291-18-4 1L $180.6 2021-12-16 Buy
Product number Packaging Price Buy
419567 100ml $190 Buy
419567 800ml $352 Buy
772836 25ml $138 Buy
772836 100ml $209 Buy
17523 1L $180.6 Buy

ISOPROPENYLMAGNESIUM BROMIDE Chemical Properties,Uses,Production

Uses

Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)

2-Methyltetrahydrofuran (2-MeTHF): A Biomass-Derived Solvent with Broad Application in Organic Chemistry

Uses

Isopropenylmagnesium bromide (iPrMgBr) solution (0.5 M in THF) has been used in the Grignard reaction, a key step the in preparation of zofenoprilat and (S)-(?)-phosphonotrixin. It can also be used for the regioselective ring opening of an optically active epoxy alcohol in the total synthesis of (+)-desepoxyasperdiol.

General Description

This product, 1.0 M in 2-methyltetrahydrofuran aligns with Safer Solvents and Auxiliaries, Use of Renewable Feedstocks and Inherently Safer Chemistry for Accident Prevention.

557-93-7
13291-18-4
Synthesis of ISOPROPENYLMAGNESIUM BROMIDE from 2-BROMOPROPENE

ISOPROPENYLMAGNESIUM BROMIDE Preparation Products And Raw materials

Global( 171)Suppliers
Supplier Tel Email Country ProdList Advantage
Hangzhou FandaChem Co.,Ltd.
008657128800458; +8615858145714 fandachem@gmail.com China 9348 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Jinan Carbotang Biotech Co.,Ltd.
+8615866703830 figo.gao@foxmail.com China 6992 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22968 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63711 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49390 58
Fuxin Pharmaceutical
+86-021-021-50872116 +8613122107989 contact@fuxinpharm.com China 10297 58
Antai Fine Chemical Technology Co.,Limited
18503026267 info@antaichem.com CHINA 9641 58
Career Henan Chemica Co
+86-0371-86658258 15093356674; laboratory@coreychem.com China 30255 58

View Lastest Price from ISOPROPENYLMAGNESIUM BROMIDE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Bromo(isopropenyl)magnesium pictures 2023-07-19 Bromo(isopropenyl)magnesium
13291-18-4
US $30.00 / KG 1KG 99% 20 Tons Wuhan wingroup Pharmaceutical Co., Ltd
Isopropenylmagnesium bromide(1M THF) pictures 2023-01-30 Isopropenylmagnesium bromide(1M THF)
13291-18-4
US $43.00 / KG 1KG 99% 5000 tons Hebei Duling International Trade Co. LTD
isopropenylmagnesium bromide pictures 2019-07-06 isopropenylmagnesium bromide
13291-18-4
US $1.00 / kg 1kg 99% Customized Career Henan Chemical Co
Isopropenylmagnesium bromide, 0.5 M solution in THF, HySeal Isopropenylmagnesium bromide 1M solution in tetrahydrofuran ISOPROPENYLMAGNESIUM BROMIDE isopropenylmagnesium bromide solution ISOPROPENYLMAGNESIUM BROMIDE SOLUTION, ~ 0.5 M IN THF ISOPROPENYLMAGNESIUM BROMIDE, 0.5M SOLUT ION IN TETRAHYDROFURAN ISOPROPENYLMAGNESIUM BROMIDE in ETHYL ETHER ISOPROPENYLMAGNESIUM BROMIDE in TETRAHYDROFURAN (1-Methylethenyl)magnesium bromide 1-Methylethenylmagnesium bromide 1-Methylvinylmagnesium bromide Bromoisopropenylmagnesium Isopropenylmagnesium bromide,0.5M solution inTHF Isopropenylmagnesium bromide, 0.5M solution in THF, AcroSeal§3 Isopropenylmagnesium bromide solution 0.5 in THF Isopropenylmagnesium bromide, 0.5M solution in THF, AcroSeal Iso Propenyl MagnesiuM BroMide0.5M In Thf IsopropenylMagnesiuM broMide soluti IsopropenylMagnesiuM broMide, 0.5 M solution in THF, SpcSeal IsopropenylMagnesiuM broMide, 1.0 M solution in THF, SpcSeal Bromo(isopropenyl)magnesium Solution (0.5M in THF) Isopropenylmagnesium bromide(1M THF) Isopropenylmagnesium bromide, 0.5 M solution in THF, J&KSeal Isopropenylmagnesium bromide( 1.0 M solution in THF) ISOPROPENYLMAGNESIUM BROMIDE 0.5 M THF ISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, in TETRAHYDROFURAN ISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURANISOPROPENYLMAGNESIUM BROMIDE, 1.5 M, in METHYL TETRAHYDROFURAN IsopropenyL Isopropenylmagnesium bromide (0.5M in THF) FandaSeal Magnesium, bromo(1-methylethenyl)- (9CI) bromo(1-methylethenyl)-Magnesium Iso Propenyl Magnesium Bromide .5M in THF Iso Propenyl Magnesium Bromide 1.M in 2-Methyl THF ISOPROPENYL MAGNESIUM BROMIDE 0.5M THF/1.0M &2M THF ISOPROPENYLMAGNESIUM BROMIDE 0.5M IN THF/1.0M IN 2Me THF Iso Propenyl Magnesium Bromide 1.5M in 2-Methyl THF 13291-18-4 13219-18-4 CH2CCH3MgBr H2CCCH3MgCl Alkenyl Grignard Reagents Organometallic Reagents Grignard Reagent Alkenyl Grignard Reagents Organometallic Reagents