ChemicalBook >> CAS DataBase List >>4,4'-Diaminodicyclohexyl methane

4,4'-Diaminodicyclohexyl methane

CAS No.
1761-71-3
Chemical Name:
4,4'-Diaminodicyclohexyl methane
Synonyms
POLYLINK PACM;PACM20;DICYKAN;Wandamin hm;DIAMINODICYCLOHEXYLMETHANE;BIS(4-AMINOCYCLOHEXYL)METHANE;4,4'-METHYLENEBIS(CYCLOHEXYLAMINE);hlr4219;hlr4448;HLR 4219
CBNumber:
CB5109865
Molecular Formula:
C13H26N2
Molecular Weight:
210.36
MDL Number:
MFCD00001496
MOL File:
1761-71-3.mol
MSDS File:
SDS
Last updated:2024-04-15 15:30:59

4,4'-Diaminodicyclohexyl methane Properties

Melting point 60-65°C
Boiling point 330-331°C
Density 0.95 g/mL at 25 °C(lit.)
vapor pressure <0.1 mm Hg ( 38 °C)
refractive index 1.5032 (estimate)
Flash point >230 °F
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Chloroform (Slightly), Methanol (Slightly)
pka 10.87±0.70(Predicted)
form powder to lump to clear liquid
color White or Colorless to Almost white or Almost colorless
Water Solubility Insoluble (<0.1 g/100 mL)
BRN 2079179
LogP 2.03 at 25℃
CAS DataBase Reference 1761-71-3(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 0NW77H1O03
NIST Chemistry Reference Cyclohexanamine, 4,4'-methylenebis-(1761-71-3)
EPA Substance Registry System 4,4'-Methylenebis(cyclohexylamine) (1761-71-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS05,GHS07,GHS08,GHS09
Signal word  Danger
Hazard statements  H302-H314-H317-H373-H411
Precautionary statements  P273-P280-P305+P351+P338-P310
Hazard Codes  T+,N,C
Risk Statements  26-34-51/53-48/22-43-35-22
Safety Statements  26-28-36/37/39-45-61-50-14
RIDADR  UN 2928 6.1/PG 2
WGK Germany  2
RTECS  GX1530000
10-34
TSCA  Yes
HazardClass  8
PackingGroup  III
HS Code  29213000
Toxicity LC50 inhalation in mouse: 400mg/m3/4H
NFPA 704
1
3 0

4,4'-Diaminodicyclohexyl methane price More Price(18)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 368849 4,4′-Methylenebis(cyclohexylamine) technical grade, 95% 1761-71-3 250g $128 2024-03-01 Buy
TCI Chemical M0699 4,4'-Methylenebis(cyclohexylamine) (mixture of isomers) >97.0%(GC)(T) 1761-71-3 25g $31 2024-03-01 Buy
TCI Chemical M0699 4,4'-Methylenebis(cyclohexylamine) (mixture of isomers) >97.0%(GC)(T) 1761-71-3 500g $121 2024-03-01 Buy
Alfa Aesar L09598 4,4'-Diaminodicyclohexylmethane, mixture of stereoisomers, 98+% 1761-71-3 25g $35.65 2024-03-01 Buy
Alfa Aesar L09598 4,4'-Diaminodicyclohexylmethane, mixture of stereoisomers, 98+% 1761-71-3 100g $86.8 2024-03-01 Buy
Product number Packaging Price Buy
368849 250g $128 Buy
M0699 25g $31 Buy
M0699 500g $121 Buy
L09598 25g $35.65 Buy
L09598 100g $86.8 Buy

4,4'-Diaminodicyclohexyl methane Chemical Properties,Uses,Production

Uses

4,4'-Methylenebis(cyclohexylamine) is a potential high inhibitive and high temperature resistant shale inhibitor.

Chemical Properties

Beige solidified mass or fragments

Uses

4,4'-Diaminodicyclohexylmethane is used as epoxy curing agents. It is a versatile intermediate to produce leather, rubber products, plastics, dyes, and photo sensitive polymers. It is used in manufacturing diisocyanates and polyamides. It is also used as lubricant additive as and corrosion inhibitor.

Uses

4,4'-Diaminodicyclohexyl methane be used as organic intermediates and epoxy curing agents.

Synthesis Reference(s)

Journal of the American Chemical Society, 75, p. 1156, 1953 DOI: 10.1021/ja01101a044

General Description

Yellowish white liquid or brown solid paste.

Air & Water Reactions

Sensitive to decomposition in air and light . Insoluble in water.

Reactivity Profile

4,4'-Diaminodicyclohexyl methane neutralizes acids in weakly exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. May generate hydrogen, a flammable gas, in combination with strong reducing agents such as hydrides.

Health Hazard

ACUTE/CHRONIC HAZARDS: 4,4'-Diaminodicyclohexyl methane is corrosive.

Fire Hazard

4,4'-Diaminodicyclohexyl methane is probably combustible.

Flammability and Explosibility

Non flammable

Toxicology

On resorption, predominant clinical signs of intoxication were hyperexcitability, excessive salivation, and convulsions in animals; repeated oral dosing (50 – 100 mg kg -1 d -1 in rats and mice for 10 and 16 d, respectively, 50 mg/kg in dogs for up to 82 weeks) resulted in gastrointestinal hemorrhagic inflammations, nephritis, and fatty changes to the liver. No changes in methemoglobin or in other hematological parameters were induced in cats on repeated doses of 50 and 100 mg kg -1 d -1, given twice per week over 2 months. Several in vitro and in vivo mutagenicity studies gave no evidence of a mutagenic or clastogenic potential.

101-77-9
1761-71-3
Synthesis of 4,4'-Diaminodicyclohexyl methane from 4,4'-Methylenedianiline

4,4'-Diaminodicyclohexyl methane Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 267)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Daeyeon Chemicals Co., Ltd
021-64478606 +8615900664856 daeyeon001@vip.163.com China 2062 58
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+8613288715578 sales@hbmojin.com China 12453 58
Hebei Yanxi Chemical Co., Ltd.
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Henan Fengda Chemical Co., Ltd
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Hebei Saisier Technology Co., LTD
+86-18400010335 +86-13102810335 admin@hbsaisier.cn China 565 58
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+86-28792436-807 anna.lee66@139.com China 3 58
Capot Chemical Co.,Ltd.
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Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21695 55
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008657128800458; +8615858145714 fandachem@gmail.com China 9350 55
Jiangsu Qingquan Chemical Co., Ltd.
+86-571-86589381,86589382,86589383 sales1@qqpharm.com CHINA 154 55

View Lastest Price from 4,4'-Diaminodicyclohexyl methane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
PACM pictures 2024-04-18 PACM
1761-71-3
US $0.00-0.00 / KG 1KG 99% 100000 tons SHENZHEN XUHUA BIOTECHNOLOGY CO.,LTD.
4,4'-Diaminodicyclohexyl methane pictures 2024-04-15 4,4'-Diaminodicyclohexyl methane
1761-71-3
US $6.00 / KG 1KG More than 99% 2000KG/Month Hebei Saisier Technology Co., LTD
4,4'-Diaminodicyclohexyl methane pictures 2023-12-26 4,4'-Diaminodicyclohexyl methane
1761-71-3
US $0.00 / kg 1kg 99% 1000000 Hebei Jingbo New Material Technology Co., Ltd
  • PACM pictures
  • PACM
    1761-71-3
  • US $0.00-0.00 / KG
  • 99%
  • SHENZHEN XUHUA BIOTECHNOLOGY CO.,LTD.
4,4'-DIAMINODICYCLOHEXYLMETHANE 4,4-METHYLENEBIS(CYCLOHEXYLAMINE) 4,4'-METHYLENEBIS(AMINOCYCLOHEXANE) TIMTEC-BB SBB008433 1,4-bis(aminocyclohexyl)methane 4,4’-diaminodicyclohexylmethane,mixtureofisomers 4,4’-methylenebis(cyclohexanamine) 4,4’-methylenebis-cyclohexanamin Cyclohexylamine, 4,4'-methylenebis- Di(p-aminocyclohexyl)methane HLR 4219 HLR 4448 hlr4219 hlr4448 Methylenebis(4-aminocyclohexane) p,p’-diaminodicyclohexylmethane p,p'-Diaminodicyclohexylmethane wandaminhm BIS-(P-AMINOCYCLOHEXYL)METHANE 4,4'-METHYLENEBIS(CYCLOHEXYLAMINE), TECH ., 95%, MIXTURE OF ISOMERS 4,4'-METHYLENEBIS(CYCLOHEXYLAMINE), 97%, MIXTURE OF ISOMERS 4,4'-Methylenebis(4-aminocyclohexane) Methylenebis(cyclohexanamine) Cyclohexanamine, 4,4-methylenebis- METHYLENE-BIS-CYCLOHEXAMINE 4,4’-methylenebis-Cyclohexanamine 4,4’-methylenebis-cyclohexylamin 4,4’-methylenedicyclohexanamine 4,4’-methylenedicyclohexaneamine 4,4’-methylenedicyclohexylamine 4-[(4-azanylcyclohexyl)methyl]cyclohexan-1-amine 4,4'-Diaminodicycloh Bis(4-aminocyclohexyl)methane 4,4'-Diaminodicyclohexylmethane 4,4'-Methylenebis(aminocyclohexane) 4,4'-Diaminodicyclohexyl methane(PACM) 4,4'-Methylenebis(cyclohexylamine) technical grade, 95% 4,4'-Diaminodicyclohexylmethane, mixture of stereoisomers 4,4'-Bis(aminocyclohexyl)methane 4,4'-Methylenebis(cyclohexanamine) 4,4'-Methylenedicyclohexanamine 4,4'-Methylenedicyclohexaneamine 4,4'-Methylenedicyclohexylamine 4-[(4-Aminocyclohexyl)methyl]cyclohexylamine 4,4′-Methylenbis(cyclohexylamin) 4,4''-METHYLENEBIS(CYCLOHEXYLAMINE) (MIXED ISOMER) 98+% 4 4-DIAMINODICYCLOHEXYLMETHANE 97% 4,4'-Diaminodicyclohexylmethane mixture of stereoisomers, 98+% 4,4'-Methylenebis(cyclohexylamine) (mixture of isomers) 4,4'-Methylenedicyclohexalamine 4,4'-Diaminodicyclohexylmethane, 98+% Amicure PACM Wondamine HM 1,1'-Methylenebis(4-cyclohexanamine) 4,4'-Methylenebis(1-aminocyclohexane) 4,4'-diaminodicyclohexylmethane (fatty amine curing agent chain extender PACM, HMDA) 4,4'-diainodicyclonhexymethane 4,4'-Methylenebis(cyclohexylamine)(mixtureofisomers)> 4,4'-Diaminodicyclohexylmethane, 98%, for synthesis 4,4-Diaminodicyclohexylme