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Cyclobutanecarboxylic acid

CAS No.
3721-95-7
Chemical Name:
Cyclobutanecarboxylic acid
Synonyms
Cyclobutylcarboxylic acid;cyclobutanecarboxylate;Cyclobutane-1-carboxylic acid;obutanecarboxyL;Ring butyl forMate;RARECHEM AL BO 0291;Cyclo-butyl formic a;Cyclobutancarbonsure;CYCLO-BUTYL FORMIC ACID;Cyclobutanecarbonyl acid
CBNumber:
CB5113033
Molecular Formula:
C5H8O2
Molecular Weight:
100.12
MDL Number:
MFCD00001323
MOL File:
3721-95-7.mol
MSDS File:
SDS
Last updated:2023-11-28 12:12:34

Cyclobutanecarboxylic acid Properties

Melting point −7.5 °C(lit.)
Boiling point 195 °C(lit.)
Density 1.047 g/mL at 25 °C(lit.)
refractive index n20/D 1.444(lit.)
Flash point 183 °F
storage temp. Sealed in dry,Room Temperature
solubility soluble in Chloroform, Methanol
form Liquid
pka pK1:4.785 (25°C)
color Clear colorless to yellow
Specific Gravity 1.047
Water Solubility Slightly soluble in water.
BRN 1816777
CAS DataBase Reference 3721-95-7(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 0RDJ7C51O0
NIST Chemistry Reference Cyclobutane carboxylic acid(3721-95-7)
EPA Substance Registry System Cyclobutanecarboxylic acid (3721-95-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338
Hazard Codes  Xi,C
Risk Statements  36/37/38-34-20/21/22
Safety Statements  23-24/25-36-26-45-36/37/39
RIDADR  3265
WGK Germany  3
RTECS  GU1335000
13
TSCA  T
HazardClass  8
PackingGroup  III
HS Code  29162000
NFPA 704
2
2 0

Cyclobutanecarboxylic acid price More Price(31)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich C95609 Cyclobutanecarboxylic acid 98% 3721-95-7 5g $39.5 2024-03-01 Buy
Sigma-Aldrich C95609 Cyclobutanecarboxylic acid 98% 3721-95-7 25g $73.2 2024-03-01 Buy
TCI Chemical C0888 Cyclobutanecarboxylic Acid >97.0%(GC)(T) 3721-95-7 10g $32 2024-03-01 Buy
TCI Chemical C0888 Cyclobutanecarboxylic Acid >97.0%(GC)(T) 3721-95-7 25g $62 2024-03-01 Buy
Alfa Aesar A14480 Cyclobutanecarboxylic acid, 98+% 3721-95-7 25g $86.65 2024-03-01 Buy
Product number Packaging Price Buy
C95609 5g $39.5 Buy
C95609 25g $73.2 Buy
C0888 10g $32 Buy
C0888 25g $62 Buy
A14480 25g $86.65 Buy

Cyclobutanecarboxylic acid Chemical Properties,Uses,Production

Chemical Properties

CLEAR COLOURLESS TO SLIGHTLY AMBER LIQUID

Uses

Cyclobutanecarboxylic acid is used in water treatment, row materials for sodium fluosilicate potassium fluosilicateammonium fluosilicatecopper fluosilicatebarium fluosilicate and other fluosilicates and silicic tetrafluoride. It is also used in refining lead of electrolysis, as mordant and in the treatment of metal surface.

Preparation

Cyclobutanecarboxylic acid synthesis: Put 1,1-Cyclobutanedicarboxylic acid into a distillation device for heating, decarboxylate at about 160°C to release carbon dioxide, then heat for distillation, collect 189-195°C fractions as crude product, and re-distill to obtain the finished product cyclobutanecarboxylic acid. Yield 86%-91%.

Synthesis Reference(s)

The Journal of Organic Chemistry, 22, p. 1680, 1957 DOI: 10.1021/jo01363a041

Purification Methods

Dissolve the acid in aqueous HCO 3 then acidify with HCl and extract it into Et2O, wash with H2O, dry (Na2SO4), concentrate to a small volume, then distil it through a glass helices packed column. The S-benzylisothiuronium salt has m 176o (from EtOH), the anilide has m 112.5-113o, and the p-toluide has m 123o. [Payne & Smith J Org Chem 22 1680 1957, Kantaro & Gunning J Am Chem Soc 73 480 1951, Stodola & Heisig Org Synth Coll Vol III 213 1955, Beilstein 9 H 5.]

74-85-1
79-10-7
3721-95-7
Synthesis of Cyclobutanecarboxylic acid from ETHYLENE and Acrylic acid
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View Lastest Price from Cyclobutanecarboxylic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Cyclo-butyl formic acid pictures 2024-01-14 Cyclo-butyl formic acid
3721-95-7
US $5.00-0.50 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
Cyclobutanecarboxylic acid pictures 2023-11-28 Cyclobutanecarboxylic acid
3721-95-7
US $0.00 / kg 1kg 0.99 20 tons Hebei Yanxi Chemical Co., Ltd.
Cyclobutanecarboxylic acid pictures 2023-11-01 Cyclobutanecarboxylic acid
3721-95-7
US $0.00-0.00 / kg 0.10000000149011612kg 99.0%min 5MT Hangzhou ICH Biofarm Co., Ltd
RARECHEM AL BO 0291 CYCLO-BUTYL FORMIC ACID cyclobutylcarboxylicacid Cyclobutanecarbonyl acid cyclobutane carboyxlic acid CYCLOBUTANOIC ACID 98% (GC) CYCLOBUTANECARBOXYLIC AICD CyclobutanecarboxylicAcid98% cyclobutancecarboxylic acid Cyclobutyl carboxilic acid Cyclo-butyl formic a Cyclobutanecarboxylic acid, 98% 25GR Ring butyl forMate Cyclobutane carbonic acid Cyclobutanecarboxylic acid 98% obutanecarboxyL Cyclobutanecarboxylic Acid > Cyclobutanecarboxylic acid, 98%, for synthesis Cyclobutancarbonsure TIANFUCHEM-- 3721-95-7-- Cyclobutanecarboxylic acid in stock cyclobutanecarboxylate Cyclobutane-1-carboxylic acid Cyclobutylcarboxylic acid CYCLOBUTANECARBOXYLIC ACID Cyclobutanecarboxylic acid (6CI, 7CI, 8CI, 9CI, ACI) Adipic acid impurity5(Cyclobutanecarboxylic acid) Cyclobutanecaboxylic acid 3721-95-7 3271-95-7 C4H7COOH C4H7CO2H CARBOXYLIC ACID Organic Building Blocks C1 to C5 Carbonyl Compounds Carboxylic Acids Building Blocks Simple 4-Membered Ring Compounds Cyclobutanes & Cyclobutenes Aromatic Carboxylic Acids, Amides, Anilides, Anhydrides & Salts Acids and Derivatives Cyclobutanes & Cyclobutenes Simple 4-Membered Ring Compounds Cycloalkanes C1 to C5 Carbonyl Compounds Carboxylic Acids bc0001