ChemicalBook >> CAS DataBase List >>Hexafluoroethane

Hexafluoroethane

CAS No.
76-16-4
Chemical Name:
Hexafluoroethane
Synonyms
r116;C2F6;f116;R-116;R 116;F-116;PFC116;FC-116;FC1160;CFC-116
CBNumber:
CB5123920
Molecular Formula:
C2F6
Lewis structure
c2f6 lewis structure
Molecular Weight:
138.01
MDL Number:
MFCD00000428
MOL File:
76-16-4.mol
MSDS File:
SDS
Last updated:2024-03-14 15:18:26

Hexafluoroethane Properties

Melting point −100 °C(lit.)
Boiling point −78 °C(lit.)
Density 1,607 g/cm3
vapor density 4.7 (vs air)
vapor pressure 430 psi ( 21 °C)
refractive index 1.2060
InChIKey WMIYKQLTONQJES-UHFFFAOYSA-N
CAS DataBase Reference 76-16-4(CAS DataBase Reference)
FDA UNII 7VL5Z0IY3A
EPA Substance Registry System Hexafluoroethane (76-16-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS04
Signal word  Warning
Hazard statements  H280
Precautionary statements  P410+P403
Hazard Codes  Xi
Safety Statements  38
RIDADR  UN 2193 2.2
WGK Germany  3
RTECS  KI4110000
Hazard Note  Irritant
TSCA  T
HazardClass  2.2
HS Code  2903392820
NFPA 704
0
1 0

Hexafluoroethane price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 295361 Hexafluoroethane ≥98% 76-16-4 227g $856 2024-03-01 Buy
American Custom Chemicals Corporation HCH0026207 HEXAFLUOROETHANE 95.00% 76-16-4 100G $2571.95 2021-12-16 Buy
American Custom Chemicals Corporation HCH0026207 HEXAFLUOROETHANE 95.00% 76-16-4 250G $4493.64 2021-12-16 Buy
SynQuest Laboratories 1100-2-26 Hexafluoroethane 99.9% 76-16-4 25g $95 2021-12-16 Buy
SynQuest Laboratories 1100-2-02 Hexafluoroethane 99% 76-16-4 100g $145 2021-12-16 Buy
Product number Packaging Price Buy
295361 227g $856 Buy
HCH0026207 100G $2571.95 Buy
HCH0026207 250G $4493.64 Buy
1100-2-26 25g $95 Buy
1100-2-02 100g $145 Buy

Hexafluoroethane Chemical Properties,Uses,Production

Description

Hexafluoroethane is a colorless and oodorlessgas or liquid under pressure. Molecular weight = 138.02;Boiling point= 一78℃. Hazard Identification (based onNFPA-704 M Rating System): Health 1, Flammability 0,Reactivity 0. Insoluble in water.

Chemical Properties

Hexafluoroethane is a colorless and odorless gas, or liquid under pressure. asphyxiant in high concentrations. Gas density is heavier than air. Hexafluoroethane is chemically inert and has a very high global warming potential (GWP = 11,100; Greenhouse gas protocol, Fifth Assessment Report AR5). It is an etchant and chamber cleaning agent.

Uses

Hexafluoroethane is used as an important component in some refrigeration mixtures, and as a reactive ion etching gas in semiconductor materials processing applications. It can be used for selective etching of metal silicides and oxides versus their metal substrates and also for etching of silicon dioxide over silicon.
In semiconductor applications, for example in reactive ion etching, hexafluoroethane with a fluorine to carbon ratio of 3:1 offers a unique source of highly reactive trifluoromethyl radicals without accompanying hydrogen atoms.As a result, semiconductor material plasma etching processes employing hexafluoroethane are relatively aggressive with respect to fluorine radical formation.

Definition

ChEBI: Hexafluoroethane is a fluoroalkane and a fluorocarbon. It has a role as a refrigerant.

Synthesis Reference(s)

Journal of the American Chemical Society, 77, p. 3007, 1955 DOI: 10.1021/ja01616a025

General Description

HEXAFLUOROETHANE is a colorless, odorless gas. HEXAFLUOROETHANE is relatively inert. The mixture is nonflammable and nontoxic, though asphyxiation may occur because of displacement of oxygen. Under prolonged exposure to fire or intense heat the containers may rupture violently and rocket.

Reactivity Profile

HEXAFLUOROETHANE is chemically inert in many situations, but can react violently with strong reducing agents such as the very active metals and the active metals. Can react with strong oxidizing agents or weaker oxidizing agents under extremes of temperature.

Health Hazard

Vapors may cause dizziness or asphyxiation without warning. Vapors from liquefied gas are initially heavier than air and spread along ground. Contact with gas or liquefied gas may cause burns, severe injury and/or frostbite. Fire may produce irritating, corrosive and/or toxic gases.

Fire Hazard

Some may burn but none ignite readily. Containers may explode when heated. Ruptured cylinders may rocket.

Potential Exposure

It is used as a coolant, in dielectric fluids; as a propellant and refrigerant.

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irri gate immediately for at least15 min, occasionally lifting upper and lower lids. Seek med-ical attention immediately. If this chemical contacts theskin, remove contaminated clothingand wash immediatelywith soap and water. Seek medical attention immediately. Ifthis chemical has been inhaled, remove from exposure,begin rescue breathing (using universal precautions, includ-ing resuscitation mask) if breathing has stopped and CPR ifheart action has stopped. Transfer promptly to a medicalfacility. When this chemical has been swallowed, get medi-cal attention. Give large quantities of water and inducevomiting. Do not make an unconscious person vomit. Iffrostbite has occured, seek medical attention immediately;do NOT rub the affected areas or flush them with water. Inorder to prevent further tissue damage, do NOT attempt toremove frozen clothing from frostbitten areas. If frostbitehasNOT occurred, immediately and thoroughly washcontaminated skin with soap and water.

storage

Color Code- Green: General storage may be used.Prior to working with this chemical you should be trainedon its proper handling and storage. Store in tightly closedcontainers in a cool, well-venti lated area away from metals,including aluminum, zinc, and beryllium, and from openflames or temperatures above 52℃. Procedures for thehandling, use, and storage of cylinders should be in compli-ance with OSHA 1910.101 and 1910.169, as with therecommendations of the Compressed Gas Association.

Shipping

UN2193 Hexafluoroethane or Refrigerant gas R-116, Hazard Class: 2.2; Labels: 2.2-Nonflammable compressed gas.

Purification Methods

Purify it for pyrolysis studies by passing through a copper vessel containing CoF3 at ca 270o, and hold for 3hours in a bottle with a heated (1300o) platinum wire. It is then fractionally distilled. [Steunenberg & Cady J Am Chem Soc 74 4165 1962, Beilstein 1 IV 132.]

Incompatibilities

Active metals. Keep away from heat and sunlight.

Waste Disposal

Return refillable compressed gas cylinders to supplier.

354-33-6
76-16-4
Synthesis of Hexafluoroethane from Pentafluoroethane
Global( 75)Suppliers
Supplier Tel Email Country ProdList Advantage
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Hubei xin bonus chemical co. LTD
86-13657291602 linda@hubeijusheng.com CHINA 22968 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
SIMAGCHEM CORP
+86-13806087780 sale@simagchem.com China 17367 58
Allfluoro pharmaceutical co. ltd.
021-26137118 +8615821363818 sales@allfluoro.com China 5791 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671 sales@tnjchem.com China 34572 58
ANHUI WITOP BIOTECH CO., LTD
+8615255079626 eric@witopchemical.com China 23556 58
Shaanxi Dideu Medichem Co. Ltd
+86-029-89586680 +86-18192503167 1026@dideu.com China 9358 58
CD Chemical Group Limited
+8615986615575 info@codchem.com China 20356 58

View Lastest Price from Hexafluoroethane manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
HEXAFLUOROETHANE pictures 2019-07-06 HEXAFLUOROETHANE
76-16-4
US $1.00 / kg 1 g 99% 100KG Career Henan Chemical Co
freon116 Hexafluorethan hexafluoro-ethan Perfluorocarbon116 PFC116 R 116 r116 R-116 PERFLUOROETHANE CFC-116 HALOCARBON 116 HEXAFLUOROETHANE FC-116 FC-116~Perfluoroethane Hexafluoroethane (FC-116) Hexafluoroethane (FC-116) 99 Hexafluoroethene Hexafluoroethane (FC-116) 99.99% HEXAFLUORETHANE HEXAFLUOROETHANE: 99.9% CFC-116, Perfluoroethane Fron-116 Perfluroethane Perfluoroethane (FC-116) 99% Perfluoroethane (FC-116) 99.9% Perfluoroethane(FC-116)99% 1,1,1,2,2,2-Hexafluoroethane C2F6 ethane,hexafluoro- Ethylhexafluoride f116 F-116 FC1160 Fluorocarbon 116 Freon 116 Freon 1166SY Hexafluoroethane(R116) Ethane, 1,1,1,2,2,2-hexafluoro- Perfluorethan HEXAFLUOROETHANE ISO 9001:2015 REACH Six fluorine ethane 76-16-4 76164 CF3CF3 Synthetic Reagents Compressed and Liquefied Gases refrigerants Organics