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N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE

CAS No.
82113-66-4
Chemical Name:
N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE
Synonyms
TMS Triflimide;[Bis(trifluoromethanesulfonyl)amino]trimethylsilane;N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE;N-(Trimethylsilyl)bis(trifluoromethanesulfonyl)amine;N-(Trimethylsilyl)bis(trifluoromethanesulfonyl)imide;[Bis(trifluoromethanesulfonyl)amino]trimethylsilane TMS Triflimide;1,1,1-trifluoro-N-(trifluoroMethylsulfonyl)-N-(triMethylsilyl)MethanesulfonaMide;Methanesulfonamide,1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]-N-(trimethylsilyl)-
CBNumber:
CB51479303
Molecular Formula:
C5H9F6NO4S2Si
Molecular Weight:
353.34
MDL Number:
MOL File:
82113-66-4.mol
MSDS File:
SDS
Last updated:2023-06-08 17:06:37

N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE Properties

Boiling point 115 °C / 2mmHg
Density 1.543±0.06 g/cm3(Predicted)
storage temp. Freezer
solubility soluble in most common organic solvents, commonly used in dichloromethane, toluene, diethyl ether.
form clear liquid
pka -26.49±0.70(Predicted)
color Colorless to Red to Green

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319-H315
Precautionary statements  P264-P280-P305+P351+P338-P337+P313P-P264-P280-P302+P352-P321-P332+P313-P362
HS Code  2931.90.9010
NFPA 704
0
1 0

N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE price More Price(6)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical T2392 N-(Trimethylsilyl)bis(trifluoromethanesulfonyl)imide >97.0%(T) 82113-66-4 1g $97 2024-03-01 Buy
TCI Chemical T2392 N-(Trimethylsilyl)bis(trifluoromethanesulfonyl)imide >97.0%(T) 82113-66-4 5g $297 2024-03-01 Buy
AK Scientific 8368AL N-(Trimethylsilyl)bis(trifluoromethanesulfonyl)imide 82113-66-4 1g $183 2021-12-16 Buy
American Custom Chemicals Corporation ORS0001405 N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE 95.00% 82113-66-4 1G $185.85 2021-12-16 Buy
Ambeed A752811 N-(TRimethylsilyl)bis(trifluoromethanesulfonyl)imide 95% 82113-66-4 250mg $37 2021-12-16 Buy
Product number Packaging Price Buy
T2392 1g $97 Buy
T2392 5g $297 Buy
8368AL 1g $183 Buy
ORS0001405 1G $185.85 Buy
A752811 250mg $37 Buy

N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE Chemical Properties,Uses,Production

Physical properties

colorless liquid, bp: 115°C(2 Torr).

Uses

Methanesulfonamide, 1,1,1-Trifluoro- N[(trifluoromethyl)sulfonyl]- N(trimethylsilyl)-? can be used as Lewis acid catalyst for a variety of organic transformations.

Preparation

It is easily prepared in situ through protodesilation by mixing commercially available allyltrimethylsilane (or any TMS enol ether) and Tf2NH. Originally prepared by mixing Tf2NH with trimethylsilane at low temperature or mixing AgNTf2 with TMSCl.

N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE Preparation Products And Raw materials

Raw materials

Preparation Products

N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE Suppliers

Global( 33)Suppliers
Supplier Tel Email Country ProdList Advantage
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739 info@dycnchem.com CHINA 52867 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503259 +86-19930503259 cherry@crovellbio.com China 18456 58
LEAPCHEM CO., LTD.
+86-852-30606658 market18@leapchem.com China 43348 58
Shanghai Acmec Biochemical Technology Co., Ltd.
+undefined18621343501 product@acmec-e.com China 33349 58
Aladdin Scientific
+1-833-552-7181 sales@aladdinsci.com United States 52927 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 94838 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006608290; 18621169109 market03@meryer.com China 40241 62
TCI (Shanghai) Development Co., Ltd. 021-67121386 Sales-CN@TCIchemicals.com China 24539 81
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44751 61
Shanghai Longsheng chemical Co.,Ltd. 021-58099652-8005 13585536065 bin.wu@shlschem.com China 9816 59
N-(TRIMETHYLSILYL)BIS(TRIFLUOROMETHANESULFONYL)IMIDE [Bis(trifluoromethanesulfonyl)amino]trimethylsilane TMS Triflimide [Bis(trifluoromethanesulfonyl)amino]trimethylsilane TMS Triflimide 1,1,1-trifluoro-N-(trifluoroMethylsulfonyl)-N-(triMethylsilyl)MethanesulfonaMide Methanesulfonamide,1,1,1-trifluoro-N-[(trifluoromethyl)sulfonyl]-N-(trimethylsilyl)- N-(Trimethylsilyl)bis(trifluoromethanesulfonyl)imide N-(Trimethylsilyl)bis(trifluoromethanesulfonyl)amine 82113-66-4 C5H9F6NO4S2Si Si (Classes of Silicon Compounds) Si-N Compounds Trimethylsilylazide, etc.