Chinese Japanese Germany Korea
ChemicalBook >> CAS DataBase List >>(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Structure
(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) structure
CAS No.
380230-02-4
Chemical Name:
(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR)
Synonyms
3,4-a']dinapht...;(S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE;]dinaphthalen-4-yl)bis(1-phenylethyl)amine;1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR);(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D;(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D;]dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine.;3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine;3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine.;(S,S,S)-(3,5-Dioxa-4-phosphacyclohepa[2,1-a:3,4-a&rsquo
CBNumber:
CB5190531
Molecular Formula:
C36H30NO2P
Molecular Weight:
539.6
MDL Number:
MFCD04117688
MOL File:
380230-02-4.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06
Request For Quotation

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Properties

Melting point 88-89 °C
Boiling point 710.7±63.0 °C(Predicted)
alpha +13.1° (c 1.01, CHCl3)
storage temp. under inert gas (nitrogen or Argon) at 2-8°C
pka -0.57±0.20(Predicted)
form Powder
color off-white
Sensitive moisture sensitive
InChIKey LKZPDRCMCSBQFN-UIOOFZCWSA-N

SAFETY

Risk and Safety Statements

Risk Statements  36/37/38
Safety Statements  26-36/37/39
WGK Germany  3

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) price More Price(26)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 665290 (S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a’]dinaphthalen-4-yl)bis(1-phenylethyl)amine 97% 380230-02-4 100mg $84.3 2024-03-01 Buy
Sigma-Aldrich 665290 (S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a’]dinaphthalen-4-yl)bis(1-phenylethyl)amine 97% 380230-02-4 2g $636 2024-03-01 Buy
Strem Chemicals 15-1521 (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine, min. 95% 380230-02-4 100mg $94 2024-03-01 Buy
Strem Chemicals 15-1521 (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine, min. 95% 380230-02-4 500mg $367 2024-03-01 Buy
Sigma-Aldrich 665290 (S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a’]dinaphthalen-4-yl)bis(1-phenylethyl)amine 97% 380230-02-4 500mg $240.6 2024-03-01 Buy
Product number Packaging Price Buy
665290 100mg $84.3 Buy
665290 2g $636 Buy
15-1521 100mg $94 Buy
15-1521 500mg $367 Buy
665290 500mg $240.6 Buy

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Chemical Properties,Uses,Production

Reaction

  1. A ligand for asymmetric conjugate addition of dialkyl zinc reagents to activated olefins.
  2. Iridium-catalyzed regioselective and enantioselective allylation of enamines.
  3. Iridium-catalyzed asymmetric allylation of KSAc. 
Reactions of 380230-02-4

Uses

The product may be used as a ligand in:

  • Iridium-catalyzed allylic etherification of acyclic, achiral allylic carbonates with potassium silanolates to form chiral allylic alcohols.
  • Palladium-catalyzed asymmetric allylic cyclisation of N-tosyl and N-benzyl carbonates to form the corresponding pyrrolidine and piperidine derivatives, respectively.
  • Intramolecular iridium-catalyzed allylic cyclizationof (E)-allylic methyl carbonates to form 2,5-trans/cis pyrrolidine derivatives.

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Preparation Products And Raw materials

Raw materials

Preparation Products

(+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Suppliers

Global( 51)Suppliers
Supplier Tel Email Country ProdList Advantage
Dayang Chem (Hangzhou) Co.,Ltd. 		571-88938639 +8617705817739 info@dycnchem.com CHINA 52867 58
Hefei TNJ Chemical Industry Co.,Ltd. 		0551-65418684 +8618949823763 sales@tnjchem.com China 25363 58
PT CHEM GROUP LIMITED 		+86-85511178 +86-85511178 peter68@ptchemgroup.com China 35453 58
GIHI CHEMICALS CO.,LIMITED 		+8618058761490 info@gihichemicals.com China 49999 58
Shaoxin Catsyn Co., Ltd. 		+undefined-0575-82040869 +86-0575-82040869; sales@catsyn.com China 6116 58
Aladdin Scientific 		+1-833-552-7181 sales@aladdinsci.com United States 57511 58
Amadis Chemical Company Limited 		571-89925085 sales@amadischem.com China 131981 58
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2654 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44751 61
Supplier Advantage
Dayang Chem (Hangzhou) Co.,Ltd. 		58
Hefei TNJ Chemical Industry Co.,Ltd. 		58
PT CHEM GROUP LIMITED 		58
GIHI CHEMICALS CO.,LIMITED 		58
Shaoxin Catsyn Co., Ltd. 		58
Aladdin Scientific 		58
Amadis Chemical Company Limited 		58
LaaJoo 58
J & K SCIENTIFIC LTD. 76
Energy Chemical 61

380230-02-4((+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR))Related Search:

(+)-N,N-BIS[(1R)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) (R)-MONOPHOS (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a N N-BIS-[(S)-1-PHENYLETHYL]DIBENZO[D F][
(+)-N-BENZYL-N-METHYL-DINAPHTHO[2,1-D:1',2']DIOXAPHOSPHEPIN-4-AMINE, (11BS)

1of2

(S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS(1-PHENYLETHYL)AMINE (S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHEPTA[2,1-A:3,4-A']DINAPHTHALEN-4-YL)BIS[(1S)-1-PHENYLETHYL]AMINE (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) (S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine, min. 95% S)-(+)-(3,5-Dioxa-4-phospha-cyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine,min.95% 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine, min. 95% 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine (S,S,S)-(+)-(3,5-DIOXA-4-PHOSPHA-CYCLOHE 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine,min.95% N,N-Bis((S)-1-phenylethyl)dinaphtho-[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine N,N-Bis[(1S)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine (S,S,S)-(+)-(3,5-Dioxa-4-phosphacyclohepta[2,1-a:3,4-a']dinaphthalen-4-yl)bis(1-phenylethyl)aMine 97% 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine,95% ]dinaphthalen-4-yl)bis(1-phenylethyl)amine ]dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine. (S,S,S)-(3,5-Dioxa-4-phosphacyclohepa[2,1-a:3,4-a&rsquo (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D 1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) Dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, N,N-bis[(1S)-1-phenylethyl]- 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine,97% (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D:1',2'-F][1,3,2]DIOXAPHOSPHEPIN-4-AMINE, (11BR) 3,4-a']dinapht... (+)-N,N-BIS[(1S)-1-PHENYLETHYL]-DINAPHTHO[2,1-D 3,4-a']dinaphthalen-4-yl)bis[(1S)-1-phenylethyl]amine. 380230-02-4 C36H30NO2P Privileged Ligands DSM MonoPhos Phosphoramidites Asymmetric Synthesis Chiral Catalysts, Ligands, and Reagents Chiral Phosphine CPN