ChemicalBook >> CAS DataBase List >>(R)-(+)-Glycidol

(R)-(+)-Glycidol

CAS No.
57044-25-4
Chemical Name:
(R)-(+)-Glycidol
Synonyms
(R)-Oxiran-2-ylMethanol;(R)-GLYCIDOL;(R)-Oxiranemethanol;EOS-60676;R-Glycidoe;(R)-(+)-GL;(+)-Glycidol;(R)-(+)-GLYCIDOL;(R)-GLYCIDOL,99%;(r)-oxiranemethano
CBNumber:
CB5205831
Molecular Formula:
C3H6O2
Molecular Weight:
74.08
MDL Number:
MFCD00074873
MOL File:
57044-25-4.mol
MSDS File:
SDS
Last updated:2023-06-08 17:06:39

(R)-(+)-Glycidol Properties

Boiling point 56-57 °C11 mm Hg(lit.)
Density 1.116 g/mL at 20 °C(lit.)
refractive index n20/D 1.43(lit.)
Flash point 178 °F
storage temp. -20°C
Water Solubility Completely miscible in water
solubility Chloroform (Slightly), DMSO (Slightly)
pka 14.62±0.10(Predicted)
color Colorless to Light yellow
optical activity [α]23/D +15°, neat
BRN 79782
Stability Moisture Sensitive
InChIKey CTKINSOISVBQLD-GSVOUGTGSA-N
CAS DataBase Reference 57044-25-4(CAS DataBase Reference)
NIST Chemistry Reference Oxiranemethanol, (R)-(57044-25-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS02,GHS05,GHS06,GHS07,GHS08
Signal word  Danger
Hazard statements  H227-H315-H319-H335-H361-H370-H373-H242-H302-H312-H314-H331-H341-H350-H360F-H302+H312-H330
Precautionary statements  P201-P280-P305+P351+P338-P310-P260-P284-P202-P210-P264-P270-P271-P301+P312+P330-P302+P352+P312+P362+P364-P304+P340+P311-P305+P351+P338+P337+P313-P307+P311-P403+P233-P405-P501
Hazard Codes  T,E
Risk Statements  45-60-2-21/22-23-34-68-41-37/38
Safety Statements  53-45-36/37/39-26
RIDADR  UN 2922 8/PG 2
WGK Germany  3
RTECS  RR0508000
10-21
HazardClass  6.1
PackingGroup 
HS Code  29109000
NFPA 704
2
2 0

(R)-(+)-Glycidol price More Price(27)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 480819 (R)-(+)-Glycidol 97%, optical purity ee: 98% (GLC) 57044-25-4 1g $50.1 2023-06-20 Buy
TCI Chemical G0363 (R)-(+)-Glycidol >98.0%(GC) 57044-25-4 5g $86 2024-03-01 Buy
TCI Chemical G0363 (R)-(+)-Glycidol >98.0%(GC) 57044-25-4 25g $291 2024-03-01 Buy
TRC G615695 (R)-(+)-Glycidol 57044-25-4 10g $215 2021-12-16 Buy
TRC G615695 (R)-(+)-Glycidol 57044-25-4 5g $135 2021-12-16 Buy
Product number Packaging Price Buy
480819 1g $50.1 Buy
G0363 5g $86 Buy
G0363 25g $291 Buy
G615695 10g $215 Buy
G615695 5g $135 Buy

(R)-(+)-Glycidol Chemical Properties,Uses,Production

Chemical Properties

Colorless to light yellow liqui

Uses

(R)-(+)-Glycidol may be used in the following synthesis:

  • heteroarylpropane-2,3-diols, useful for combinatorial oligomer synthesis
  • enantiomerically pure (2S,3S)- and (2S,3R)-threoninol and -hydroxyphenylalaninol
  • 2-amino-1,4-anhydro-pentitol and 3-amino-1,5-anhydro-4-deoxy-hexitol with the arabino configuration
  • (S)-4-tosyloxymethyl-2-oxazolidinone, required for the synthesis of protected amino alcohol derivatives
  • 1-(S)-[3-hydroxy-2-(phosphonomethoxy)propyl]cytosine [(S)-HPMPC]
  • chiral building block used to construct an epoxyvinyl iodide intermediate in a synthesis of a furanocembrane, a marine natural product

Uses

(R)-(+)-Glycidol can be used to construct chiral building blocks of epoxyvinyl iodide intermediates in the synthesis of furanocembrane, a marine natural product.

Definition

ChEBI: (R)-glycidol is a glycidol. It is functionally related to a (R)-1,2-epoxypropane. It is an enantiomer of a (S)-glycidol.

General Description

Enantioselective esterification of (R)-(+)-glycidol with n-butyric acid in organic media using hybrid gel-entrapped lipase on Celite has been reported.

Purification Methods

[S(-)-isomer, § also available on polymer support, has b 49-50o/7mm, 66-67o/19mm, [ ] D -1 5o(neat)], [R(+)-isomer has b 56 -5 6 . 5o/11mm, d 4 1.117, n D 1.429, [ ] D +15o (neat)]. Purify glycidol by fractional distillation.

(R)-(+)-Glycidol Preparation Products And Raw materials

Global( 299)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Nanjing ChemLin Chemical Industry Co., Ltd.
025-83697070 product@chemlin.com.cn CHINA 3012 60
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
Shanghai Arbor Chemical Co., Ltd.
021-60451682 act@arborchemical.com CHINA 906 58
Jinan Carbotang Biotech Co.,Ltd.
+8615866703830 figo.gao@foxmail.com China 6992 58
Accela ChemBio Inc.
(+1)-858-699-3322 info@accelachem.com United States 19965 58
Changzhou Ditong Chemical Co.,Ltd
+86-0519-88299272 info@edengenechem.com China 2169 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49390 58

View Lastest Price from (R)-(+)-Glycidol manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
(R)-(+)-Glycidol pictures 2021-07-02 (R)-(+)-Glycidol
57044-25-4
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
(R)-(+)-Glycidol pictures 2019-08-06 (R)-(+)-Glycidol
57044-25-4
US $1.00 / KG 1KG 95%-99% 2000kg Career Henan Chemical Co
  • (R)-(+)-Glycidol pictures
  • (R)-(+)-Glycidol
    57044-25-4
  • US $15.00-10.00 / KG
  • 99%+ HPLC
  • Zhuozhou Wenxi import and Export Co., Ltd
(R)-(+)-1-Hydroxy-2,3-epoxypropane (R)-(+)-2-(Hydroxymethyl)oxirane (R)-(+)-Glycidol 97%, optical purity ee: 98% (GLC) 2-Oxiranemethanol, (2R)- (R)-(+)-1-Hydroxy-2,3-epoxypropane (R)-(+)-Glycidol≥ 99% (GC) (R)-(+)-Oxirane-2-methanol (R)-(+)-1-Hydroxy-2,3-epoxypropane (R)-(+)-2-(Hydroxymethyl)oxirane (r)-oxiranemethano (R)-(+)-2,3-EPOXY-1-PROPANOL (R)-(+)-GLYCIDOL R(+)-OXIRANE-2-METHANOL OXIRANEMETHANOL, (2R)- (R)-GLYCIDOL,99% (R)-3-Hydroxy-1,2-epoxypropane (R)-(+)-GLYCIDOL, 97% (98% EE/GLC) R-Glycidoe (R)-(+)-GLYCIDOL ((R)-(+)-2,3-EPOXY-1-PROPANOL) (2R)-Oxirane-2-methanol (R)-2-Hydroxymethyloxirane (R)-(+)-Glycidol,(R)-(+)-Oxirane-2-methanol (R)-(+)-Glycidol> (R)-(+)-GL 97%, optical purity ee: 98% (GLC) EOS-60676 (R)-Oxiran-2-ylMethanol (R)-GLYCIDOL (R)-Oxiranemethanol (+)-Glycidol 57044-25-4 C3H6O2 Asymmetric Synthesis Chiral Building Blocks Organic Building Blocks Epoxides Chiral Compound CHIRAL COMPOUNDS chiral API intermediates