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Methyl cinnamate

Chemical Properties Preparative Methods
Methyl cinnamate
Methyl cinnamate
CAS No.
103-26-4
Chemical Name:
Methyl cinnamate
Synonyms
FEMA 2698;Methyl cinmate;METHYL CINNAMATE;methyl cinanmate;METHYL CINNAMYLATE;Methyl cinnamate,98%;METHYL CINNAMATE 99%;METHYL TRANS-CINNAMATE;methl β-phenylacrylate;METHYL 3-PHENYLACRYLATE
CBNumber:
CB5206328
Molecular Formula:
C10H10O2
Formula Weight:
162.19
MOL File:
103-26-4.mol

Methyl cinnamate Properties

Melting point:
34-38 °C(lit.)
Boiling point:
260-262 °C(lit.)
Density 
1.092
refractive index 
1.5771
FEMA 
2698 | METHYL CINNAMATE
Flash point:
>230 °F
form 
Fused Crystalline Mass
color 
White to light yellow
Water Solubility 
insoluble
Merck 
14,2299
BRN 
386468
CAS DataBase Reference
103-26-4(CAS DataBase Reference)
NIST Chemistry Reference
2-Propenoic acid, 3-phenyl-, methyl ester(103-26-4)
EPA Substance Registry System
2-Propenoic acid, 3-phenyl-, methyl ester(103-26-4)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Safety Statements  22-24/25
WGK Germany  1
RTECS  GE0190000
TSCA  Yes
HS Code  29163990
Symbol(GHS):
Signal word:
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H303 May be harmfulif swallowed Acute toxicity,oral Category 5 P312
Precautionary statements:

Methyl cinnamate price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 96410 Methyl cinnamate ≥99.0% (GC) 103-26-4 100g $31.5 2017-11-08 Buy
Sigma-Aldrich 80835 Methyl cinnamate analytical reference material 103-26-4 250mg $64.3 2017-11-08 Buy
TCI Chemical C0360 Methyl Cinnamate >99.0%(GC) 103-26-4 25g $14 2017-11-08 Buy
TCI Chemical C0360 Methyl Cinnamate >99.0%(GC) 103-26-4 500g $74 2017-11-08 Buy
Alfa Aesar A15975 Methyl cinnamate, predominantly trans, 99% 103-26-4 100g $16 2017-11-08 Buy

Methyl cinnamate Chemical Properties,Uses,Production

Chemical Properties

It appears as white to slightly yellow crystal with cherry and fragrant ester fragrant {gas. It has a melting point of 34 ° C, a boiling point of 260 ° C, a refractive index (nD20) of 1.5670 and relative density (d435) of 1.0700. It is soluble in ethanol, ether, glycerol, propylene glycol. It mostly exists in non-volatile oil and mineral oil, insoluble in water.
Natural products are contained in basil oil (up to 52%), galangal oil and cinnamon oil.

Preparative Methods

It is obtained by esterification of cinnamic acid with methanol. The mixture of cinnamic acid, methanol and sulfuric acid (or hydrochloric acid) was heated to reflux for 5 h, and the excess amount of methanol was added. Cool and spate the acid layer, washed with water and 10% sodium carbonate solution, and then washed with water to neutral. The crude product was subjected to recrystallization or vacuum distillation [collection of 132-134 ° C (2.0 kPa) fraction] to give methyl cinnamate with a yield of about 70%.

Chemical Properties

White to light yellow fused crystalline mas

Methyl cinnamate Preparation Products And Raw materials

Raw materials

Preparation Products


Methyl cinnamate Suppliers

Global( 239)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Shenzhen Sendi Biotechnology Co.Ltd.
0755-23311925 18102838259
0755-23311925 Abel@chembj.com CHINA 3218 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32764 55
Hefei TNJ Chemical Industry Co.,Ltd.
86-0551-65418684 18949823763
86-0551-65418684 info@tnjchem.com China 1428 55
Shanghai Zheyan Biotech Co., Ltd.
18017610038
zheyansh@163.com CHINA 3625 58
Wuhan lenmaike Industrial Co., Ltd. 13396062449
027-83916065 279115899@qq.com China 278 58
Taizhou DongBang Fine Chemical Co. Ltd. +86-0523-86235448 15996000437
+86-0523-86235448 2535251509@qq.com China 54 55
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40399 62
INTATRADE GmbH +49 3493/605464
+49 3493/605470 sales@intatrade.de Germany 3587 66
Alfa Aesar 400-610-6006; 021-67582000
021-67582001/03/05 saleschina@alfa-asia.com China 30308 84

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