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METHYL 3-HYDROXY-4-METHYLBENZOATE

CAS No.
3556-86-3
Chemical Name:
METHYL 3-HYDROXY-4-METHYLBENZOATE
Synonyms
3,4-Cresotic acid methyl ester;METHYL 3-HYDROXY-4-METHYLBENZOATE;Methyl 4-Methyl-3-hydroxybenzoate;3-HYDROXY-P-TOLUIC ACID METHYL ESTER;Methyl 3-hydroxy-4-methylbenzoate 98%;3-HYDROXY-4-METHYLBENZOIC ACID METHYL ESTER;benzoic acid, 3-hydroxy-4-methyl-, methyl ester
CBNumber:
CB5209910
Molecular Formula:
C9H10O3
Molecular Weight:
166.17
MDL Number:
MFCD00213808
MOL File:
3556-86-3.mol
Last updated:2023-05-15 10:43:30

METHYL 3-HYDROXY-4-METHYLBENZOATE Properties

Melting point 119.0-120.5 °C
Boiling point 294.6±20.0 °C(Predicted)
Density 1.169±0.06 g/cm3(Predicted)
storage temp. Hygroscopic, Refrigerator, under inert atmosphere
solubility Acetone (Slightly), Chloroform (Slightly)
pka 9.50±0.10(Predicted)
form Solid
color Tan
Stability Hygroscopic
CAS DataBase Reference 3556-86-3(CAS DataBase Reference)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H319-H315-H302-H335
Precautionary statements  P264-P270-P301+P312-P330-P501-P264-P280-P302+P352-P321-P332+P313-P362-P264-P280-P305+P351+P338-P337+P313P
HazardClass  IRRITANT

METHYL 3-HYDROXY-4-METHYLBENZOATE price More Price(31)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC M322970 Methyl4-Methyl-3-hydroxybenzoate 3556-86-3 2.5g $45 2021-12-16 Buy
Usbiological 283450 Methyl 3-hydroxy-4-methylbenzoate 3556-86-3 2g $399 2021-12-16 Buy
Usbiological 164917 Methyl 4-Methyl-3-hydroxybenzoate 3556-86-3 1g $403 2021-12-16 Buy
Apolloscientific OR311176 Methyl3-hydroxy-4-methylbenzoate 98% 3556-86-3 25g $435 2021-12-16 Buy
SynQuest Laboratories 2729-1-71 Methyl 3-hydroxy-4-methylbenzoate 98% 3556-86-3 25g $480 2021-12-16 Buy
Product number Packaging Price Buy
M322970 2.5g $45 Buy
283450 2g $399 Buy
164917 1g $403 Buy
OR311176 25g $435 Buy
2729-1-71 25g $480 Buy

METHYL 3-HYDROXY-4-METHYLBENZOATE Chemical Properties,Uses,Production

Synthesis

Methyl 3-hydroxy-4-methylbenzoate is synthesized by the following steps:The amino ester 35 (60 g, 0.364 mol) was added to dil. H2SO4 (125 ml  conc. H2SO4 diluted with 1 L water) and warmed on a water bath until all  the compound was dissolved. Cold water (800 ml) was added and the  mixture was cooled to 0 °C. NaNO2 (62.6 g, 0.907 mol) was added to this  mixture with constant stirring. It was then stirred at room temperature for 15 minutes.  Then, urea (65.4 g, 1.09 mol) was added in portions. The mixture was warmed at 50 ºC for  15 minutes (temperature was not allowed to rise above 55 ºC). EtOAc was added to the reaction mixture and washed with brine, dried (anhydrous Na2SO4), filtered and  concentrated under reduced pressure to afford a colourless solid (26.56 g).

Uses

Methyl 4-Methyl-3-hydroxybenzoate is used in the preparation of potent antimalarial agents. Also used in the preparation of aromatic inhibtors of anthranilate synthase.

METHYL 3-HYDROXY-4-METHYLBENZOATE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 103)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15928 58
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32480 60
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63711 58
career henan chemical co
+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
Jinan Qinmu Fine Chemical Co.,Ltd.
+8618660799346 sales@qinmuchem.com China 1009 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671 sales@tnjchem.com China 34572 58
WinWin Chemical CO., Limited
+86-0086-577-64498589 +86-15355981851 sales@win-winchemical.com China 13854 58
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739 info@dycnchem.com CHINA 52867 58
Changzhou Anxuan Chemical Co., Ltd
+86-0519-89882563 +86-18961279162 andy@anxuanchem.com China 4226 58

View Lastest Price from METHYL 3-HYDROXY-4-METHYLBENZOATE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
METHYL 3-HYDROXY-4-METHYLBENZOATE pictures 2020-01-10 METHYL 3-HYDROXY-4-METHYLBENZOATE
3556-86-3
US $1.00 / KG 1KG 98% 200kgs Career Henan Chemical Co
benzoic acid, 3-hydroxy-4-methyl-, methyl ester Methyl 4-Methyl-3-hydroxybenzoate METHYL 3-HYDROXY-4-METHYLBENZOATE 3-HYDROXY-4-METHYLBENZOIC ACID METHYL ESTER 3-HYDROXY-P-TOLUIC ACID METHYL ESTER 3,4-Cresotic acid methyl ester Methyl 3-hydroxy-4-methylbenzoate 98% 3556-86-3 Esters Phenyls & Phenyl-Het