CERIUM(IV) TRIFLUOROMETHANESULFONATE
- CAS No.
- 107792-63-2
- Chemical Name:
- CERIUM(IV) TRIFLUOROMETHANESULFONATE
- Synonyms
- CERIUM(IV) TRIFLATE;ceric triflate;CERIUM(IV) TRIFLATE698999-65-4;CERIUM(IV) TRIFLUOROMETHANESULFONATE;CERIUM(IV) TRIFLUOROMETHANESULPHONATE;Cerium(IV) trifluoromethanesulfonate,99%;CeriuM(IV) trifluoroMethanesulfonate, Ce(CF3SO3)4
- CBNumber:
- CB5219973
- Molecular Formula:
- C4CeF12O12S4
- Molecular Weight:
- 736.39
- MDL Number:
- MFCD03844746
- MOL File:
- 107792-63-2.mol
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
| Hazard Codes | C | |||||||||
| Risk Statements | 34 | |||||||||
| Safety Statements | 45-36/37/39-26 | |||||||||
| TSCA | No | |||||||||
| HS Code | 29310099 | |||||||||
| NFPA 704 |
|
CERIUM(IV) TRIFLUOROMETHANESULFONATE price More Price(4)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Alfa Aesar | L20056 | Cerium(IV) trifluoromethanesulfonate, 98% | 107792-63-2 | 5g | $52.5 | 2024-03-01 | Buy |
| Alfa Aesar | L20056 | Cerium(IV) trifluoromethanesulfonate, 98% | 107792-63-2 | 25g | $159.65 | 2024-03-01 | Buy |
| TRC | C278580 | Cerium(IV)trifluoromethanesulfonate | 107792-63-2 | 1g | $110 | 2021-12-16 | Buy |
| American Custom Chemicals Corporation | ING0026060 | CERIUM(IV)TRIFLUOROMETHANESULFONATE 95.00% | 107792-63-2 | 5MG | $454.46 | 2021-12-16 | Buy |
CERIUM(IV) TRIFLUOROMETHANESULFONATE Chemical Properties,Uses,Production
Chemical Properties
Cerium(IV) Trifluoromethanesulfonate (ceric triflate) is a oxidizing agent for benzyl alcohols and toluenes; yellow powder or solid; sol water, THF, DME, dioxane; insol dichloromethane, hexane, benzene.
Uses
Cerium(IV) trifluoromethanesulfonate, is used as a strong oxidizing agent, in the oxidation of benzyl alcohols and alkylbenzenes to aryl aldehydes and aryl ketones respectively. It can also be used as a catalyst for high-yield deprotection of tert-butyldimethylsilyl ethers
Preparation
By the reaction of trifluoromethanesulfonic acid with freshly prepared cerium(IV) carbonate[1]. Cerium(IV) Trifluoromethanesulfonate can be prepared in situ by the electrochemical oxidation of Ce(OTf)3 in aqueous trifluoromethanesulfonic acid[2].
storage
Cerium(IV) trifluoromethanesulfonate is extremely hygroscopic and should be stored under strict absence of moisture. This reagent should be handled in a fume hood.
References
1. Imamoto, T.; Koide, Y.; Hiyama, S. CL 1990, 1445.
2. Kreh, R. P.; Spotnitz, R. M.; Lundquist, J. T. TL 1987, 28, 1067.
CERIUM(IV) TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials
Raw materials
Preparation Products
CERIUM(IV) TRIFLUOROMETHANESULFONATE Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Dayang Chem (Hangzhou) Co.,Ltd. | 571-88938639 +8617705817739 | info@dycnchem.com | China | 52849 | 58 |
| Alfa Chemistry | Info@alfa-chemistry.com | United States | 24072 | 58 | |
| PT CHEM GROUP LIMITED | +86-85511178; +86-85511178; | peter68@ptchemgroup.com | China | 35425 | 58 |
| GIHI CHEMICALS CO.,LIMITED | +8618058761490 | info@gihichemicals.com | China | 49984 | 58 |
| Shaoxin Catsyn Co., Ltd. | +undefined-0575-82040869 +86-0575-82040869; | sales@catsyn.com | China | 6114 | 58 |
| Aladdin Scientific | tp@aladdinsci.com | United States | 52924 | 58 | |
| XIAMEN AMITY INDUSTRY AND TRADE CO., LTD. | +8618950047208 | ellena@amitychem.com | China | 43416 | 58 |
| J & K SCIENTIFIC LTD. | 010-82848833 400-666-7788 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30123 | 84 |
| Energy Chemical | 021-021-58432009 400-005-6266 | sales8178@energy-chemical.com | China | 44733 | 61 |
| Supplier | Advantage |
|---|---|
| Dayang Chem (Hangzhou) Co.,Ltd. | 58 |
| Alfa Chemistry | 58 |
| PT CHEM GROUP LIMITED | 58 |
| GIHI CHEMICALS CO.,LIMITED | 58 |
| Shaoxin Catsyn Co., Ltd. | 58 |
| Aladdin Scientific | 58 |
| XIAMEN AMITY INDUSTRY AND TRADE CO., LTD. | 58 |
| J & K SCIENTIFIC LTD. | 76 |
| Alfa Aesar | 84 |
| Energy Chemical | 61 |
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