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CERIUM(IV) TRIFLUOROMETHANESULFONATE

CAS No.
107792-63-2
Chemical Name:
CERIUM(IV) TRIFLUOROMETHANESULFONATE
Synonyms
CERIUM(IV) TRIFLATE;ceric triflate;CERIUM(IV) TRIFLUOROMETHANESULFONATE;CERIUM(IV) TRIFLUOROMETHANESULPHONATE;Cerium(IV) trifluoromethanesulfonate,99%;CeriuM(IV) trifluoroMethanesulfonate, Ce(CF3SO3)4
CBNumber:
CB5219973
Molecular Formula:
C4CeF12O12S4
Molecular Weight:
736.39
MDL Number:
MFCD03844746
MOL File:
107792-63-2.mol
Last updated:2025-01-02 11:08:53
Product description Number Pack Size Price
Cerium(IV)trifluoromethanesulfonate C278580 1g $110
CERIUM(IV)TRIFLUOROMETHANESULFONATE 95.00% ING0026060 5MG $454.46

CERIUM(IV) TRIFLUOROMETHANESULFONATE Properties

solubility soluble in DMSO
form Solid
color Yellow
Water Solubility Soluble in water.
Sensitive Hygroscopic

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Danger
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  C
Risk Statements  34
Safety Statements  45-36/37/39-26
TSCA  No
HS Code  29310099
NFPA 704
1
3 1

CERIUM(IV) TRIFLUOROMETHANESULFONATE price More Price(4)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TRC C278580 Cerium(IV)trifluoromethanesulfonate 107792-63-2 1g $110 2021-12-16 Buy
American Custom Chemicals Corporation ING0026060 CERIUM(IV)TRIFLUOROMETHANESULFONATE 95.00% 107792-63-2 5MG $454.46 2021-12-16 Buy
Product number Packaging Price Buy
C278580 1g $110 Buy
ING0026060 5MG $454.46 Buy

CERIUM(IV) TRIFLUOROMETHANESULFONATE Chemical Properties,Uses,Production

Chemical Properties

Cerium(IV) Trifluoromethanesulfonate (ceric triflate) is a oxidizing agent for benzyl alcohols and toluenes; yellow powder or solid; sol water, THF, DME, dioxane; insol dichloromethane, hexane, benzene.

Uses

Cerium(IV) trifluoromethanesulfonate, is used as a strong oxidizing agent, in the oxidation of benzyl alcohols and alkylbenzenes to aryl aldehydes and aryl ketones respectively. It can also be used as a catalyst for high-yield deprotection of tert-butyldimethylsilyl ethers

Preparation

By the reaction of trifluoromethanesulfonic acid with freshly prepared cerium(IV) carbonate[1]. Cerium(IV) Trifluoromethanesulfonate can be prepared in situ by the electrochemical oxidation of Ce(OTf)3 in aqueous trifluoromethanesulfonic acid[2].

storage

Cerium(IV) trifluoromethanesulfonate is extremely hygroscopic and should be stored under strict absence of moisture. This reagent should be handled in a fume hood.

References

1. Imamoto, T.; Koide, Y.; Hiyama, S. CL 1990, 1445.
2. Kreh, R. P.; Spotnitz, R. M.; Lundquist, J. T. TL 1987, 28, 1067.

CERIUM(IV) TRIFLUOROMETHANESULFONATE Preparation Products And Raw materials

Raw materials

Preparation Products

CERIUM(IV) TRIFLUOROMETHANESULFONATE Suppliers

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CERIUM(IV) TRIFLUOROMETHANESULFONATE CERIUM(IV) TRIFLUOROMETHANESULPHONATE ceric triflate Cerium(IV) trifluoromethanesulfonate,99% CeriuM(IV) trifluoroMethanesulfonate, Ce(CF3SO3)4 CERIUM(IV) TRIFLATE 107792-63-2 21951-90-9 C4F12O12S4Ce25H2O C4CeF12O12S4 CF3SO34Ce