ETHYL 3-PHENYLGLYCIDATE
- CAS No.
- 121-39-1
- Chemical Name:
- ETHYL 3-PHENYLGLYCIDATE
- Synonyms
- FEMA 2454;ethyl3-phenyloxirane;ETHYL PHENYLGLYCIDATE;strawberry glycidate 2;ethyl3-phenyloxirane-2-;ETHYL 3-PHENYLGLYCIDATE;ETHYL PHENYLGLYCIDATE FCC;Ethyl 3-Phenylglycidate ETHYL A B-EPOXYHYDROCINNAMATE;ethyl2,3-epoxy-3-phenylpropion
- CBNumber:
- CB5292099
- Molecular Formula:
- C11H12O3
- Molecular Weight:
- 192.21
- MDL Number:
- MFCD00005123
- MOL File:
- 121-39-1.mol
- MSDS File:
- SDS
| Melting point | 17-18 °C |
|---|---|
| Boiling point | 96 °C/0.5 mmHg (lit.) |
| Density | 1.102 g/mL at 25 °C (lit.) |
| vapor pressure | 0.12Pa at 24℃ |
| FEMA | 2454 | ETHYL 3-PHENYLGLYCIDATE |
| refractive index |
n |
| Flash point | >230 °F |
| storage temp. | 2-8°C |
| solubility | Insoluble in water |
| form | Liquid |
| color | Clear colorless to yellow |
| Odor | at 100.00 %. sweet strawberry berry floral tropical |
| Odor Type | fruity |
| Water Solubility | 748.4mg/L at 24℃ |
| Sensitive | Moisture Sensitive |
| JECFA Number | 1576 |
| Stability | Stable. Combustible. Incompatible with strong oxidizing agents. |
| LogP | 2.4 at 20℃ |
| CAS DataBase Reference | 121-39-1(CAS DataBase Reference) |
| Substances Added to Food (formerly EAFUS) | ETHYL 3-PHENYLGLYCIDATE |
| FDA 21 CFR | 172.515 |
| EWG's Food Scores | 1 |
| FDA UNII | 2VVS520ZWM |
| EPA Substance Registry System | Ethyl 3-phenylglycidate (121-39-1) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H303-H335-H315-H319 | |||||||||
| Precautionary statements | P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
| Hazard Codes | Xi | |||||||||
| Risk Statements | 36/37/38 | |||||||||
| Safety Statements | 23-24/25 | |||||||||
| WGK Germany | 2 | |||||||||
| RTECS | MB4970000 | |||||||||
| TSCA | Yes | |||||||||
| HS Code | 29189990 | |||||||||
| Toxicity | The acute oral LD50 value in rats was reported as 2.3 ml/kg (2.0-2.6 ml/ kg) (Shelanski, 1973b). The acute dermal LD50 value in rabbits was reported as > 5 g/kg (Shelanski, 1973a). | |||||||||
| NFPA 704 |
|
ETHYL 3-PHENYLGLYCIDATE price More Price(21)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | W245402 | Ethyl 3-phenylglycidate mixture of | 121-39-1 | sample | $54.6 | 2024-03-01 | Buy |
| Sigma-Aldrich | 291404 | Ethyl 3-phenylglycidate technical grade, 92%, mixture of | 121-39-1 | 100ml | $49 | 2023-06-20 | Buy |
| TCI Chemical | E0798 | Ethyl 3-Phenylglycidate (cis- and trans- mixture) >90.0%(GC) | 121-39-1 | 25g | $21 | 2024-03-01 | Buy |
| Alfa Aesar | B22990 | Ethyl 3-phenylglycidate, cis + trans, 90+% | 121-39-1 | 50ml | $28.65 | 2024-03-01 | Buy |
| Alfa Aesar | B22990 | Ethyl 3-phenylglycidate, cis + trans, 90+% | 121-39-1 | 250ml | $70.65 | 2024-03-01 | Buy |
ETHYL 3-PHENYLGLYCIDATE Chemical Properties,Uses,Production
Chemical Properties
pale yellow liquid
Chemical Properties
Ethyl 3-phenylglycidate has a strong, fruity odor suggestive of strawberry with a corresponding sweet flavor.
Chemical Properties
Ethyl 3-Phenylglycidate is a colorless liquid
with a strawberry-like odor.
It is prepared by treating ethyl cinnamatewith peracetic acid or by condensation
of benzaldehyde with ethyl chloroacetate (in the aforementioned Darzens
reaction, R == H).Theglycidate is used as a long-lasting fragrancematerial for creating
harmonic, fruity notes in household and fine fragrances.
Occurrence
Apparently has not been reported to occur in nature.
Uses
Ethyl 3-Phenyloxirane-2-carboxylate is used in preparation method of early-strength viscosity-breaking Polycarboxylate water reducer containing three viscosity-breaking group and used as concrete additive.
Preparation
Usually prepared by the reaction of benzaldehyde and the ethyl ester of monochloracetic acid in the presence of an alkaline condensing agent; by reacting the silver salt of phenyl glycidic acid with ethyl iodide.
Definition
ChEBI: Ethyl phenylglycidate is an epoxide and a carboxylic acid.
Aroma threshold values
Detection: 8.5 ppm
Taste threshold values
Taste characteristics at 30 ppm: sweet, fruity and berry with dried fruit and floral nuance.
Synthesis Reference(s)
Synthetic Communications, 12, p. 355, 1982 DOI: 10.1080/00397918209408010
General Description
Clear pale yellow or yellow liquid.
Air & Water Reactions
Slightly water soluble.
Reactivity Profile
Epoxides are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.
Fire Hazard
ETHYL 3-PHENYLGLYCIDATE is probably combustible.
Flammability and Explosibility
Non flammable
Safety Profile
Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.
ETHYL 3-PHENYLGLYCIDATE Preparation Products And Raw materials
Raw materials
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Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12453 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
| Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 | alice@crovellbio.com | China | 8822 | 58 |
| career henan chemical co | +86-0371-86658258 15093356674; | factory@coreychem.com | China | 29826 | 58 |
| Shaanxi Dideu Medichem Co. Ltd | 18192627656 | 1012@dideu.com | China | 3657 | 58 |
| Hefei TNJ Chemical Industry Co.,Ltd. | 0551-65418671 | sales@tnjchem.com | China | 34572 | 58 |
| HANGZHOU CLAP TECHNOLOGY CO.,LTD | 86-571-88216897,88216896 13588875226 | sales@hzclap.com | CHINA | 6313 | 58 |
| ANHUI WITOP BIOTECH CO., LTD | +8615255079626 | eric@witopchemical.com | China | 23556 | 58 |
| Dideu Industries Group Limited | +86-29-89586680 +86-15129568250 | 1026@dideu.com | China | 29474 | 58 |
| Henan Alfa Chemical Co., Ltd | +8618339805032 | alfa4@alfachem.cn | China | 12755 | 58 |
View Lastest Price from ETHYL 3-PHENYLGLYCIDATE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-06-28 | ETHYL 3-PHENYLGLYCIDATE
121-39-1
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd | |
 |
2021-08-03 | ETHYL 3-PHENYLGLYCIDATE
121-39-1
|
US $10.00 / KG | 1KG | 99% | 10 mt | Hebei Guanlang Biotechnology Co., Ltd. | |
 |
2020-03-16 | Ethyl 3-Phenylglycidate (cis- and trans- Mixture)
121-39-1
|
US $1.00-0.00 / KG | 1KG | 99% | 50 tons | Shaanxi Dideu Medichem Co. Ltd |
-
- ETHYL 3-PHENYLGLYCIDATE
121-39-1
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd
-
- ETHYL 3-PHENYLGLYCIDATE
121-39-1
- US $10.00 / KG
- 99%
- Hebei Guanlang Biotechnology Co., Ltd.
-
- Ethyl 3-Phenylglycidate (cis- and trans- Mixture)
121-39-1
- US $1.00-0.00 / KG
- 99%
- Shaanxi Dideu Medichem Co. Ltd
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