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ETHYL 3-PHENYLGLYCIDATE

ETHYL 3-PHENYLGLYCIDATE
ETHYL 3-PHENYLGLYCIDATE structure
CAS No.
121-39-1
Chemical Name:
ETHYL 3-PHENYLGLYCIDATE
Synonyms
FEMA 2454;ethyl3-phenyloxirane;ETHYL PHENYLGLYCIDATE;strawberry glycidate 2;ethyl3-phenyloxirane-2-;ETHYL 3-PHENYLGLYCIDATE;ETHYL PHENYLGLYCIDATE FCC;Ethyl 3-Phenylglycidate ETHYL A B-EPOXYHYDROCINNAMATE;ethyl2,3-epoxy-3-phenylpropion
CBNumber:
CB5292099
Molecular Formula:
C11H12O3
Formula Weight:
192.21
MOL File:
121-39-1.mol

ETHYL 3-PHENYLGLYCIDATE Properties

Melting point:
17-18 °C
Boiling point:
96 °C/0.5 mmHg (lit.)
Density 
1.102 g/mL at 25 °C (lit.)
refractive index 
n20/D 1.518(lit.)
FEMA 
2454 | ETHYL 3-PHENYLGLYCIDATE
Flash point:
>230 °F
storage temp. 
2-8°C
form 
Liquid
color 
Clear colorless to yellow
Sensitive 
Moisture Sensitive
JECFA Number
1576
Stability:
Stable. Combustible. Incompatible with strong oxidizing agents.
CAS DataBase Reference
121-39-1(CAS DataBase Reference)
Substances Added to Food (formerly EAFUS)
ETHYL 3-PHENYLGLYCIDATE
FDA 21 CFR
172.515
EWG's Food Scores
1
FDA UNII
2VVS520ZWM
EPA Substance Registry System
Ethyl 3-phenylglycidate (121-39-1)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS07
Signal word  Warning
Hazard statements  H303-H335-H315-H319
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P280a-P304+P340-P305+P351+P338-P405-P501a
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  23-24/25
WGK Germany  2
RTECS  MB4970000
TSCA  Yes
HS Code  29189990
Toxicity The acute oral LD50 value in rats was reported as 2.3 ml/kg (2.0-2.6 ml/ kg) (Shelanski, 1973b). The acute dermal LD50 value in rabbits was reported as > 5 g/kg (Shelanski, 1973a).
NFPA 704
1
2 0

ETHYL 3-PHENYLGLYCIDATE price More Price(22)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich W245402 Ethyl 3-phenylglycidate mixtureofcisandtrans,92% 121-39-1 1 SAMPLE $50 2021-12-16 Buy
Sigma-Aldrich 291404 Ethyl 3-phenylglycidate technical grade, 92%, mixture of 121-39-1 100ml $42 2021-12-16 Buy
Sigma-Aldrich W245402 Ethyl 3-phenylglycidate mixture of 121-39-1 sample $50 2021-12-16 Buy
TCI Chemical E0798 Ethyl 3-Phenylglycidate (cis- and trans- mixture) >90.0%(GC) 121-39-1 25g $20 2021-12-16 Buy
Alfa Aesar B22990 Ethyl 3-phenylglycidate, cis + trans, 90+% 121-39-1 50ml $26.5 2021-12-16 Buy

ETHYL 3-PHENYLGLYCIDATE Chemical Properties,Uses,Production

Chemical Properties

pale yellow liquid

Chemical Properties

Ethyl 3-Phenylglycidate is a colorless liquid with a strawberry-like odor.
It is prepared by treating ethyl cinnamatewith peracetic acid or by condensation of benzaldehyde with ethyl chloroacetate (in the aforementioned Darzens reaction, R == H).Theglycidate is used as a long-lasting fragrancematerial for creating harmonic, fruity notes in household and fine fragrances.

Chemical Properties

Ethyl 3-phenylglycidate has a strong, fruity odor suggestive of strawberry with a corresponding sweet flavor.

Occurrence

Apparently has not been reported to occur in nature.

Uses

Ethyl 3-Phenyloxirane-2-carboxylate is used in preparation method of early-strength viscosity-breaking Polycarboxylate water reducer containing three viscosity-breaking group and used as concrete additive.

Preparation

Usually prepared by the reaction of benzaldehyde and the ethyl ester of monochloracetic acid in the presence of an alkaline condensing agent; by reacting the silver salt of phenyl glycidic acid with ethyl iodide.

Aroma threshold values

Detection: 8.5 ppm

Taste threshold values

Taste characteristics at 30 ppm: sweet, fruity and berry with dried fruit and floral nuance.

Synthesis Reference(s)

Synthetic Communications, 12, p. 355, 1982 DOI: 10.1080/00397918209408010

General Description

Clear pale yellow or yellow liquid.

Air & Water Reactions

Slightly water soluble.

Reactivity Profile

Epoxides are highly reactive. They polymerize in the presence of catalysts or when heated. These polymerization reactions can be violent. Compounds in this group react with acids, bases, and oxidizing and reducing agents. They react, possibly violently with water in the presence of acid and other catalysts.

Fire Hazard

ETHYL 3-PHENYLGLYCIDATE is probably combustible.

Safety Profile

Moderately toxic by ingestion. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also ESTERS.

ETHYL 3-PHENYLGLYCIDATE Preparation Products And Raw materials

Raw materials

Preparation Products


ETHYL 3-PHENYLGLYCIDATE Suppliers

Global( 116)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Hubei Jusheng Technology Co.,Ltd.
86-18871470254
027-59599243 linda@hubeijusheng.com CHINA 28229 58
Hebei Guanlang Biotechnology Co., Ltd.
+8619930503282
sales3@crovellbio.com China 5942 58
career henan chemical co
15093356674 0371-55982848
0086-371-86658258 factory@coreychem.com CHINA 29863 58
Shaanxi Dideu Medichem Co. Ltd
18192627656
+86-29-88380327 1012@dideu.com CHINA 3949 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671
0551-65418697 sales@tnjchem.com CHINA 37441 58
HANGZHOU CLAP TECHNOLOGY CO.,LTD
13588875226 86-571-88216897、88216896
86-571-88216895 sales@hzclap.com CHINA 6469 58
Dideu Industries Group Limited
029-88380327
Service@dideu.com CHINA 30014 58
Henan Alfa Chemical Co., Ltd
+8619139973225
adam@alfa-chemical.com;sales4@alfachem.cn;alfa8@alfachem.cn China 12043 58
Guangzhou TongYi biochemistry technology Co.,LTD
+8613073028829
mack@tongyon.com China 3000 58
Mainchem Co., Ltd. +86-0592-6210733
+86-0592-6210733 sale@mainchem.com CHINA 32439 55

View Lastest Price from ETHYL 3-PHENYLGLYCIDATE manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2021-08-03 ETHYL 3-PHENYLGLYCIDATE
121-39-1
US $10.00 / KG 1KG 99% 10 mt Hebei Guanlang Biotechnology Co., Ltd.
2020-03-16 Ethyl 3-Phenylglycidate (cis- and trans- Mixture)
121-39-1
US $1.00-0.00 / KG 1KG 99% 50 tons Shaanxi Dideu Medichem Co. Ltd
2020-01-13 ETHYL 3-PHENYLGLYCIDATE
121-39-1
US $1.00 / KG 1g 99.0% 100kg Career Henan Chemical Co

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