ChemicalBook >> CAS DataBase List >>D-(+)-Camphoric acid

D-(+)-Camphoric acid

CAS No.
124-83-4
Chemical Name:
D-(+)-Camphoric acid
Synonyms
(1R,3S)-CAMPHORIC ACID;(1R)-1,2,2-trimethylcyclopentane-1,3-dicarboxylic acid;(1R,3S)-1,2,2-triMethylcyclopentane-1,3-dicarboxylic acid;1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, (1R-cis)-;D-caMphor acid;D-(+)-Camphoric;(+)-CAMPHORIC ACID;D-(+)-Camphoricaci;D-(+)-Camphoric acid;Dextro-camphoric acid
CBNumber:
CB5296789
Molecular Formula:
C10H16O4
Molecular Weight:
200.23
MDL Number:
MFCD00001375
MOL File:
124-83-4.mol
MSDS File:
SDS
Last updated:2023-06-30 15:45:59

D-(+)-Camphoric acid Properties

Melting point 186-189 °C
alpha 46.5 º (c=10, C2H5OH)
Boiling point 297.96°C (rough estimate)
Density 1.1860
refractive index 1.4459 (estimate)
storage temp. Sealed in dry,Room Temperature
solubility DMSO (Slightly), Ethanol (Slightly), Methanol (Slightly)
form Crystalline Powder
pka pK1: 4.57;pK2: 5.10 (25°C)
color White
optical activity [α]20/D 46°, c = 1 in ethanol
Water Solubility 0.8 g/100 mL
Merck 14,1733
BRN 2050204
CAS DataBase Reference 124-83-4(CAS DataBase Reference)
FDA UNII W77RM1CSD5
NIST Chemistry Reference D-camphoric acid(124-83-4)
EPA Substance Registry System 1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, (1R,3S)- (124-83-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313
Hazard Codes  Xn
Risk Statements  22
Safety Statements  24/25
WGK Germany  2
TSCA  Yes
HS Code  29172090
NFPA 704
0
0 0

D-(+)-Camphoric acid price More Price(23)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich C409 (1R,3S)-(+)-Camphoric acid 99% 124-83-4 5g $49.6 2024-03-01 Buy
Sigma-Aldrich C409 (1R,3S)-(+)-Camphoric acid 99% 124-83-4 100g $101 2024-03-01 Buy
TCI Chemical C0012 (+)-Camphoric Acid >98.0%(GC)(T) 124-83-4 25g $85 2024-03-01 Buy
TCI Chemical C0012 (+)-Camphoric Acid >98.0%(GC)(T) 124-83-4 100g $233 2024-03-01 Buy
Alfa Aesar B23106 (1R,3S)-(+)-Camphoric acid, 98+% 124-83-4 25g $30.65 2024-03-01 Buy
Product number Packaging Price Buy
C409 5g $49.6 Buy
C409 100g $101 Buy
C0012 25g $85 Buy
C0012 100g $233 Buy
B23106 25g $30.65 Buy

D-(+)-Camphoric acid Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powde

Uses

D-(+)-Camphoric acid is used primarily as a reagent in syntheses of crystalline structures. It is used in the preparation of polymeric transition metal dipyridylamine D-camphorate complexes.

Uses

(1R,3S)-(+)-Camphoric acid may be used in the preparation (1R,2S,3R,5S)-2,3-dibenzyl-1,8,8-trimethyl-3-thianiumbicyclo[3.2.1]octane perchlorate. It reacts with uranyl nitrate in pyridine(py) or py/methanol(MeOH) to form novel uranyl-organic assemblages.

Definition

ChEBI: (?)-Camphoric acid is a dicarboxylic acid.

General Description

Camphoric acid is a diacid, generally prepared by the oxidation of terpene (+)-camphor. It can be used as a chirality inducing agent in some organic reactions.

storage

+4°C

Purification Methods

Purify the acid by re-precipitation from an alkaline solution by HCl, filter it off, and recrystallise it from water several times, rejecting the first crop. It forms leaflets from EtOH and Me2CO and H2O and is insoluble in CHCl3. Its solubility in H2O is 0.8% at 25o and 10% at 100o, 50% in EtOH and 5% in ethylene glycol. The (±)-acid has m 202-203o. The (+)-1-methyl ester has m 86o (from pet ether) [] 20 +45o (c 4, EtOH), and the (+)-3-methyl ester has m 77o (from pet ether) []17.5 +53.9o (c 3, EtOH). [Rupe & Thommen Helv Chim Acta 30 933

10334-26-6
124-83-4
Synthesis of D-(+)-Camphoric acid from (1R)-(-)-CAMPHORQUINONE

D-(+)-Camphoric acid Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 323)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15928 58
Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Shanghai Time Chemicals CO., Ltd.
+86-021-57951555 +8617317452075 jack.li@time-chemicals.com China 1807 55
career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
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(+1)-858-699-3322 info@accelachem.com United States 19965 58
Xi'an Kono chem co., Ltd.,
029-86107037 13289246953 info@konochemical.com China 2995 58
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86-714-3992388 overseasales1@yongstandards.com United States 14336 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63711 58

View Lastest Price from D-(+)-Camphoric acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
D-(+)-Camphoric acid pictures 2023-09-06 D-(+)-Camphoric acid
124-83-4
US $0.00 / KG 1KG 99% 500000kg Hebei Guanlang Biotechnology Co., Ltd.
D-(+)-Camphoric acid pictures 2023-06-15 D-(+)-Camphoric acid
124-83-4
US $300.00 / KG 1KG 98% 10000KG Baoji Guokang Bio-Technology Co., Ltd.
D-(+)-Camphoric acid pictures 2022-09-20 D-(+)-Camphoric acid
124-83-4
US $0.00 / kg 1kg 99% 1000kg henan kanbei chemical co.,ltd
(1R,3S)-(+)-CAMPHORIC ACID (1R,3S)-1,2,2-TRIMETHYL-1,3-CYCLOPENTANEDICARBOXYLIC ACID (+)-CAMPHORIC ACID D-caMphor acid D(+)-CaMphoric acid, 99% 100GR (1RS,3SR)-1,2,2-triMethylcyclopentane-1,3-dicarboxylic acid(caMphoric acid) (1R,3S)-(+)-Camphoric acid 99% (1R,3S)-(+)-Camphoric acid, >=99% 1,3-Cyclopentanedicarboxylicacid, 1,2,2-trimethyl-, (1R,3S)- (1R,3S)-(+)-Camphoric acid D(+)-Camphoric acid (1R,3S)-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid 2,2-trimethyl-3-cyclopentanedicarboxylicaci(1theta-cis)-1 Cis-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylicacid Dextro-camphoric acid (+)-CAMPHORIC ACID, NATURAL 1,2,2-Trimethyl-1,3-cyclopentanedicarbonsaeure D-(+)-Camphoric (1R,3S)-(+)-Camphoric acid, 98+% (+)-Camphoric acid, (1R,3S)-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid (1R)-cis-Camphoric acid cis-1,2,2-Trimethyl-1,3-cyclopentanedicarboxylic acid, (1R) 1,2,2-Trimethyl-1β,3β-cyclopentanedicarboxylic acid D(+)-Camphoric acid,99% D-(+)-Camphoric acid Levocarnitine EP Impurity B Levocarnitine Impurity 2(Levocarnitine EP Impurity B) (+)-Camphoric Acid > Levocarnitine Impurity B (D-(+)-Camphoric Acid) D-(+)-Camphoric acid USP/EP/BP (1R,3S)-1,2,2-trimethylcyclopentane-1,3-dicarboxylate (1R,3S)-CAMPHORIC ACID 1,3-Cyclopentanedicarboxylic acid, 1,2,2-trimethyl-, (1R-cis)- (1R,3S)-1,2,2-triMethylcyclopentane-1,3-dicarboxylic acid (1R)-1,2,2-trimethylcyclopentane-1,3-dicarboxylic acid D-(+)-Camphoricaci 124-83-4 Chiral Resolving Reagents Chiral Resolution Reagents Asymmetric Synthesis Optical Resolution Bicyclic Monoterpenes for Resolution of Bases Terpenes Bicyclic Monoterpenes Biochemistry for Resolution of Bases Optical Resolution Synthetic Organic Chemistry Terpenes Chiral Compound Pharmaceutical Intermediates FINE Chemical & INTERMEDIATES Miscellaneous Natural Products chiral