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Naphthalene-2,7-disulfonic acid

CAS No.
92-41-1
Chemical Name:
Naphthalene-2,7-disulfonic acid
Synonyms
Ebert-Merz α-acid;naphthalene-2,7-disulfonicaci;3,6-Naphthalenedisulfonic acid;2,7-NAPHTHALENE DISULFONIC ACID;naphthalene-2,7-disulfonic acid;naphthalene-2,7-disulphonic acid
CBNumber:
CB5297140
Molecular Formula:
C10H8O6S2
Molecular Weight:
288.3
MDL Number:
MFCD00035734
MOL File:
92-41-1.mol
MSDS File:
SDS
Last updated:2023-10-30 16:55:24

Naphthalene-2,7-disulfonic acid Properties

Melting point 199°C
Boiling point 400.53°C (rough estimate)
Density 1.6867 (rough estimate)
refractive index 1.6950 (estimate)
storage temp. 2-8°C
pka -0.33±0.40(Predicted)
CAS DataBase Reference 92-41-1(CAS DataBase Reference)
FDA UNII 01HGS7J21J
EPA Substance Registry System 2,7-Naphthalenedisulfonic acid (92-41-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P310-P260-P280
RIDADR  1759
HazardClass  8
PackingGroup  III
HS Code  2904100090

Naphthalene-2,7-disulfonic acid price More Price(10)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Matrix Scientific 098990 Naphthalene-2,7-disulfonic acid 95+% 92-41-1 250mg $341 2021-12-16 Buy
AK Scientific 5613AC Naphthalene-2,7-disulfonicacid 92-41-1 250mg $510 2021-12-16 Buy
Matrix Scientific 098990 Naphthalene-2,7-disulfonic acid 95+% 92-41-1 1g $756 2021-12-16 Buy
American Custom Chemicals Corporation DYE0002087 2,7-NAPHTHALENE DISULFONIC ACID 98.00% 92-41-1 10G $1715.18 2021-12-16 Buy
American Custom Chemicals Corporation DYE0002087 2,7-NAPHTHALENE DISULFONIC ACID 98.00% 92-41-1 500G $4519.52 2021-12-16 Buy
Product number Packaging Price Buy
098990 250mg $341 Buy
5613AC 250mg $510 Buy
098990 1g $756 Buy
DYE0002087 10G $1715.18 Buy
DYE0002087 500G $4519.52 Buy

Naphthalene-2,7-disulfonic acid Chemical Properties,Uses,Production

Chemical Properties

White, crystalline solid.Soluble in water. Combustible. Naphthalene-2,7-disulfonic acid [92- 41-1]. C10H8O6S2, Mr 288.28; the sodium salt of Naphthalene-2,7-disulfonic acid is much more soluble than that of the 2,6- isomer but can be isolated and purified by precipitation of the calcium salt at lower temperature followed by recrystallization.

Uses

Intermediate for dyes. The disodium salt of 8 gives 2-hydroxynaphthalene-7-sulfonic acid or 2,7-dihydroxynaphthalene by fusion processes. Sulfonation by oleum gives the 1,3,6-trisulfonic acid, and nitration gives 1-nitronaphthalene-3,6- disulfonic acid. In sulfuric acid solution, the disodium salt of naphthalene-2,7-disulfonic acid undergoes an unusual reaction at the 4-position with 4,40 -bis- (dimethylamino)benzhydrol. The resulting condensation product is oxidized with lead dioxide to give the acid basic dye C.I. Acid Green 16.

Production Methods

The 2,7-disulfonic acid is always the main product of high-temperature sulfonation of naphthalene, but at 160 C it converts slowly to an equilibrium mixture containing ca. 30 % of the 2,6-isomer. Crystallization of the pure product from conventional sulfonation is difficult, and alternative processes, (for example, reaction of naphthalene vapor with sulfur trioxide in the gas phase at 220 C) are said to give a purer product.

Definition

ChEBI: A naphthalenesulfonic acid in which the sulfo groups are attached to positions 2 and 7 of the naphthalene ring.

Purification Methods

Crystallise the acid from conc HCl. The disulfonamide has m 273o (from EtOH). [Beilstein 11 II 119, 11 III 463.]

Naphthalene-2,7-disulfonic acid Preparation Products And Raw materials

Global( 65)Suppliers
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Hubei Jusheng Technology Co.,Ltd.
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Mainchem Co., Ltd. +86-0592-6210733 sale@mainchem.com China 32360 55
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SHANGHAI BANGCHENG CHEMICAL Co.,Ltd. 021-69106960 13701823733 13701823733@163.com China 4775 60

View Lastest Price from Naphthalene-2,7-disulfonic acid manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Naphthalene-2,7-disulfonic acid pictures 2020-01-08 Naphthalene-2,7-disulfonic acid
92-41-1
US $1.00 / ASSAYS 1ASSAYS 99% 100KG Career Henan Chemical Co
naphthalene-2,7-disulfonic acid 2,7-NAPHTHALENE DISULFONIC ACID naphthalene-2,7-disulphonic acid 3,6-Naphthalenedisulfonic acid Ebert-Merz α-acid naphthalene-2,7-disulfonicaci 92-41-1 91-41-1 C10H8S2O6 Intermediates of Dyes and Pigments bc0001