ChemicalBook >> CAS DataBase List >>Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate
Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate
- CAS No.
- 132705-51-2
- Chemical Name:
- Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate
- Synonyms
- PYBROP;BROMOTRIPYRROLIDINOPHOSPHONIUM HEXAFLUOROPHOSPHATE;PYBRBOP;PYBROP(R);PYBROP(TM);PyBroP\(rg;PyBrOP®PyBroP Novabiochem;Bromo-tris-pyrrolidi;Pyrrolidine phosphorus complex
- CBNumber:
- CB5318935
- Molecular Formula:
- C12H24BrF6N3P2
- Molecular Weight:
- 466.19
- MDL Number:
- MFCD00077412
- MOL File:
- 132705-51-2.mol
- MSDS File:
- SDS
Last updated:2023-04-23 13:52:06
| Melting point | 100 °C |
|---|---|
| storage temp. | -20°C |
| solubility | DMF: 0.4 g/mL, clear |
| form | Powder |
| color | White to off-white |
| Water Solubility | moderately soluble |
| Sensitive | Moisture Sensitive |
| BRN | 7845702 |
| Stability | Moisture Sensitive |
| InChIKey | CYKRMWNZYOIJCH-UHFFFAOYSA-N |
| CAS DataBase Reference | 132705-51-2(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS05 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H314 | |||||||||
| Precautionary statements | P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363 | |||||||||
| Hazard Codes | Xi,C | |||||||||
| Risk Statements | 36/37/38-34 | |||||||||
| Safety Statements | 26-36-45-36/37/39-27 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10-21 | |||||||||
| HS Code | 2933 99 80 | |||||||||
| NFPA 704 |
|
Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate price More Price(65)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 8.51010 | PyBroP Novabiochem? | 132705-51-2 | 25g | $380 | 2024-03-01 | Buy |
| Sigma-Aldrich | 8.51010 | PyBroP Novabiochem? | 132705-51-2 | 100g | $1130 | 2024-03-01 | Buy |
| Sigma-Aldrich | 18565 | Bromotripyrrolidinophosphonium hexafluorophosphate ≥95.0% (HPLC) | 132705-51-2 | 1g | $11.6 | 2024-03-01 | Buy |
| Sigma-Aldrich | 18565 | Bromotripyrrolidinophosphonium hexafluorophosphate ≥95.0% (HPLC) | 132705-51-2 | 5g | $138 | 2024-03-01 | Buy |
| TCI Chemical | B2680 | Bromotripyrrolidinophosphonium Hexafluorophosphate >98.0%(HPLC)(N) | 132705-51-2 | 5g | $77 | 2024-03-01 | Buy |
Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate Chemical Properties,Uses,Production
Chemical Properties
white to off-white powder
Uses
It can be used as a coupling reagent:
- For Suzuki–Miyaura cross-coupling of phenols and arylboronic acids to synthesize biaryls and heterobiaryls.
- To functionalize pyrimidines (synthesized from 3,4-dihydropyrimidin-2(1H)-ones (DHPMs) via the Kappe dehydrogenation) by using various nucleophiles.
- To synthesize formamidines by coupling with various primary amines and N,N-diisopropylethylamine.
It can also be used as an activating reagent:
- For the activation of C-OH bond in tautomerizable heterocycles to form the phosphonium salt which aids the Sonogashira coupling of heterocycles with various alkynes.
- For the one–pot activation of C-O bond in phenols and further coupling reaction with phosphine oxide or phosphite to form C-P bonds.
Uses
A stable reagent for the coupling of N-Methylamino acids in peptide synthesis.
Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 292)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Springchem New Material Technology Co.,Limited | +86-021-62885108 +8613917661608 | info@spring-chem.com | China | 2068 | 57 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15928 | 58 |
| AB PharmaTech,LLC | 323-480-4688 | United States | 989 | 55 | |
| Shanghai Zheyan Biotech Co., Ltd. | 18017610038 | zheyansh@163.com | CHINA | 3620 | 58 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 | sales@sdzschem.com | China | 2931 | 58 |
| Shenzhen Nexconn Pharmatechs Ltd | +86-755-89396905 +86-15013857715 | admin@nexconn.com | China | 10248 | 58 |
| Jinan Carbotang Biotech Co.,Ltd. | +8615866703830 | figo.gao@foxmail.com | China | 6992 | 58 |
| Accela ChemBio Inc. | (+1)-858-699-3322 | info@accelachem.com | United States | 19965 | 58 |
View Lastest Price from Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2023-02-07 | Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate
132705-51-2
|
US $0.00 / KG | 1KG | 98%min | 30tons/month | WUHAN FORTUNA CHEMICAL CO., LTD | |
 |
2022-09-27 | Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate
132705-51-2
|
US $0.00-0.00 / KG | 1KG | 98% | 1ton | Henan Aochuang Chemical Co.,Ltd. | |
 |
2021-10-20 | Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate
132705-51-2
|
US $350.00 / KG | 1KG | 99% | 9000kg/per week | Hebei Lingding Biotechnology Co., Ltd. |
-
- Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate
132705-51-2
- US $0.00 / KG
- 98%min
- WUHAN FORTUNA CHEMICAL CO., LTD
-
- Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate
132705-51-2
- US $0.00-0.00 / KG
- 98%
- Henan Aochuang Chemical Co.,Ltd.
-
- Bromo-tris-pyrrolidino-phosphonium hexafluorophosphate
132705-51-2
- US $350.00 / KG
- 99%
- Hebei Lingding Biotechnology Co., Ltd.
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132705-51-2
C12H24BrN3PPF6
C12H24N3P2BrF6
C12H24BrN3PF6P
C12H24BrF6N3P2
Coupling
Phosphonium/Uronium/Formamidinium
Synthetic Reagents
Peptide
Coupling Reagent
Peptide Coupling Reagents