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Tetraethylene glycol dimethyl ether

CAS No.
143-24-8
Chemical Name:
Tetraethylene glycol dimethyl ether
Synonyms
TETRAGLYME;DIMETHYLTETRAGLYCOL;DIMETHOXYTETRAGLYCOL;BIS[2-(2-METHOXYETHOXY)ETHYL] ETHER;glyme5;Glyme-5;etraglyme;Me-PEG4-Me;Ansol E-181;e181(ether)
CBNumber:
CB5350092
Molecular Formula:
C10H22O5
Molecular Weight:
222.28
MDL Number:
MFCD00008505
MOL File:
143-24-8.mol
MSDS File:
SDS
Last updated:2024-04-10 13:06:19

Tetraethylene glycol dimethyl ether Properties

Melting point -30 °C (lit.)
Boiling point 275-276 °C (lit.)
Density 1.009 g/mL at 25 °C (lit.)
vapor density 7.7 (vs air)
vapor pressure <0.01 mm Hg ( 20 °C)
refractive index n20/D 1.432(lit.)
Flash point 285 °F
storage temp. Store below +30°C.
solubility Chloroform (Sparingly), Methanol (Slightly)
form Liquid
Specific Gravity 1.01
color Clear
explosive limit 0.8%(V)
Water Solubility Soluble
Merck 14,9208
BRN 1760005
InChIKey ZUHZGEOKBKGPSW-UHFFFAOYSA-N
LogP -0.84 at 23℃
CAS DataBase Reference 143-24-8(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 78L136FLZ9
NIST Chemistry Reference CH3O[CH2CH2O]4CH3(143-24-8)
EPA Substance Registry System Tetraglyme (143-24-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS08
Signal word  Danger
Hazard statements  H360FD
Precautionary statements  P201-P308+P313
Hazard Codes  Xi
Risk Statements  19-43-62-61
Safety Statements  36-24-45-36/37-53-26
WGK Germany  1
RTECS  SB0400000
Autoignition Temperature 510 °F
TSCA  Yes
HS Code  2909 19 90
Toxicity LD50 orally in rats: 5.14 g/kg (Smyth)
NFPA 704
1
0

Tetraethylene glycol dimethyl ether price More Price(21)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 8.20959 Tetraethylene glycol dimethyl ether for synthesis 143-24-8 250ML $59.2 2024-03-01 Buy
Sigma-Aldrich 8.20959 Tetraethylene glycol dimethyl ether for synthesis 143-24-8 1L $168 2024-03-01 Buy
Sigma-Aldrich 172405 Tetraethylene glycol dimethyl ether ≥99% 143-24-8 1kg $176 2024-03-01 Buy
Sigma-Aldrich 02659 Tetraethylene glycol dimethyl ether analytical standard 143-24-8 5ml $135 2022-05-15 Buy
TCI Chemical B0497 Tetraethylene Glycol Dimethyl Ether >98.0%(GC) 143-24-8 25mL $22 2024-03-01 Buy
Product number Packaging Price Buy
8.20959 250ML $59.2 Buy
8.20959 1L $168 Buy
172405 1kg $176 Buy
02659 5ml $135 Buy
B0497 25mL $22 Buy

Tetraethylene glycol dimethyl ether Chemical Properties,Uses,Production

Chemical Properties

clear liquid

Uses

Tetraethylene glycol dimethyl ether is used as a solvent.

Uses

Tetraethylene glycol dimethyl ether is used in lithium-ion battery technology. It is associated with trifluoroethanol and used as a working pair for organic absorption heat pumps. It acts as a solvent for cleaning and degreasing due to its chemical and thermal stability. Moreover, it is suitable solvent for high temperature reactions due its high boiling point. Further, it is used in the selective adsorption of proteins during the promotion of cell adhesion.

Definition

ChEBI: Tetraglyme is a polyether.

General Description

Tetraethylene glycol dimethyl ether or tetraglyme is an organic aprotic colourless solvent with film forming ability.

Flammability and Explosibility

Non flammable

Safety Profile

Mildly toxic by ingestion. Experimental reproductive effects. An eye irritant. Many glycol ethers are suspected of having dangerous human reproductive effects. When heated to decomposition it emits acrid smoke and irritating fumes. See also GLYCOL ETHERS

Purification Methods

Stand the ether over CaH2, LiAlH4 or sodium, and distil it when required. [Beilstein 1 IV 2404.]

Advantages

Tetraethylene glycol dimethyl ether (TEGDME) could be used as a bifunctional solvent which serves as both the casting solvent and active component by controlling the residual amount of TEGDME from excessive to appropriate. This method could avoid the negative impact of the residual organic solvent (such as acetonitrile) in polymer electrolytes prepared by the solution-casting method on battery performance. The residual TEGDME serves as a plasticizer in HSE that is beneficial for improving the plasticity and decreasing the crystallinity of PEO so that it can increase the mobility of lithium ions and flexibility of solid electrolytes. TEGDME can also improve the plasticity and interfacial contact[1].

Environmental considerations

Tetraethylene glycol dimethyl ether is a polar, non-aromatic compound. It is nonionic but water-soluble due to its polarity. However, it has been detected in municipal effluents, runoff from fields irrigated with treated wastewater, and wastewaters of two different waste oil refineries Citation[2].

References

[1] Hao-Ran Wang, &nbsp;Ya-Nan Yang and &nbsp; Tao Zhang*. “Tape-Casting Method of Hybrid Solid Electrolytes with a Residual Active Solvent of Tetraethylene Glycol Dimethyl Ether.” ACS Applied Energy Materials 6 3 (2023): 2031–2038.
[2] Holger Gulyas. “Combining activated carbon adsorption with heterogeneous photocatalytic oxidation: lack of synergy for biologically treated greywater and tetraethylene glycol dimethyl ether.” Environmental Technology 34 9–12 (2013): 1393–403.

75-21-8
115-10-6
110-71-4
112-49-2
111-96-6
143-24-8
1191-87-3
Synthesis of Tetraethylene glycol dimethyl ether from ETHYLENE OXIDE and Dimethyl ether

Tetraethylene glycol dimethyl ether Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 387)Suppliers
Supplier Tel Email Country ProdList Advantage
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View Lastest Price from Tetraethylene glycol dimethyl ether manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
Tetraethylene glycol dimethyl ether pictures 2024-04-10 Tetraethylene glycol dimethyl ether
143-24-8
US $0.00-0.00 / Kg 1Kg 99.99% 20 tons airuikechemical co., ltd.
TETRAETHYLENE GLYCOL DIMETHYL ETHER pictures 2024-03-27 TETRAETHYLENE GLYCOL DIMETHYL ETHER
143-24-8
US $0.00 / kg 200kg 99.0%MIN 2000tons Anhui lixing chemical co.,ltd
Tetraethylene glycol dimethyl ether pictures 2023-12-21 Tetraethylene glycol dimethyl ether
143-24-8
US $0.00-0.00 / kg 1kg 0.99 50000kg Hebei Yibangte Import and Export Co. , Ltd.
TETRA(ETHYLENE GLYCOL) DIMETHYL ETHER, 9 9+% TETRAETHYLENE GLYCOL DIMETHYL ETHER,STAN DARD FOR GC Tetraethylene glycol dimethyl ether, 98+% 2,5,8,11,14-Pentaoxapentadecane, Bis[2-(2-methoxyethoxy)ethyl] ether, Dimethoxytetraethylene glycol, Dimethyltetraglycol, Tetraglyme Tetraethylene glycol dimethyl ether, 99%, extra pure Tetraethylene glycol dimethyl ether, extra pure 1-(2-methoxyethoxy)-2-[2-(2-methoxyethoxy)-ethoxy]-ethane 1,11-dimethoxy-3,6,9-trioxa-undecane Ansol E-181 Ansul Ether 181AT ansulether181at e181(ether) Ether, bis[2-(2-methoxyethoxy)ethyl] ether,bis(2-(2-methoxyethoxy)ethyl) glyme5 Glyme-5 dimethyltetragol Bis[2-(2-methoxyethoxy)ethyl] Ether Tetraglyme Tetraethylene glycol dimethyl ether,2,5,8,11,14-Pentaoxapentadecane, Bis[2-(2-methoxyethoxy)ethyl] ether, Dimethoxytetraethylene glycol, Dimethyltetraglycol, Tetraglyme Bis(2-Methoxy-ethoxyethyl)ether Tetraethylene glycol diMethyl ether, extra pure, 99% 1KG Tetraethylene glycol diMethyl ether, extra pure, 99% 250GR Methyl-PEG4-methyl Fourtwo glycolether Tetraethylene glycol diMethyl ether, standard for GC,>=99.5%(GC) DIMETHOXYTETRAETHYLENE GLYCOL 2,5,8,11,14-PENTAOXAPENTADECANE methyltetraglyme200 nissanunioxmm200 Tetraethyleneglycoldimethyle TETRAETHYLENE GLYCOL DIMETHYL ETHER CAS_143-24-8 Tetraethylene Glycol Dimethyl Ether > TETRAETHYLENE GLYCOL DIMETHYL ETHER FOR etraglyme Me-PEG4-Me Factory Supply CAS 143-24-8 Tetraethylene Glycol Dimethyl Ether etraethylene glycol dimethyl ether 1-methoxy-2-[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]ethane BIS[2-(2-METHOXYETHOXY)ETHYL] ETHER DIMETHYLTETRAGLYCOL DIMETHOXYTETRAGLYCOL TETRAGLYME 143-24-8 CH3OCH2CH2O4CH3 143248 CH3OCH2CH24OCH3 C10H16D6O5 Organic Building Blocks Ethers General Use Puriss p.a. Oxygen Compounds Analytical Chromatography Product Catalog Building Blocks Analytical Reagents Aliphatics Alkyl