1,1,3,3-Tetramethyldisiloxane
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1,1,3,3-Tetramethyldisiloxane Properties
- Melting point:
- <-78°C
- Boiling point:
- 70-71 °C(lit.)
- Density
- 0.76 g/mL at 25 °C(lit.)
- vapor pressure
- 250 hPa (20 °C)
- refractive index
- n
20/D 1.370(lit.)
- Flash point:
- 14 °F
- storage temp.
- 2-8°C
- form
- liquid
- color
- colorless
- Specific Gravity
- 0.757
- explosive limit
- 0.8-62.9%(V)
- Water Solubility
- DECOMPOSES
- Sensitive
- Moisture Sensitive
- Hydrolytic Sensitivity
- 3: reacts with aqueous base
- BRN
- 1733364
- InChIKey
- NVYQDQZEMGUESH-UHFFFAOYSA-N
- CAS DataBase Reference
- 3277-26-7(CAS DataBase Reference)
- EWG's Food Scores
- 1
- NIST Chemistry Reference
- ((CH3)2SiH)2O(3277-26-7)
- EPA Substance Registry System
- Disiloxane, 1,1,3,3-tetramethyl- (3277-26-7)
SAFETY
- Risk and Safety Statements
| Symbol(GHS) |  GHS02 |
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|---|---|---|---|
| Signal word | Danger | ||
| Hazard statements | H225 | ||
| Precautionary statements | P210-P370+P378-P403+P235-P243-P403+P233 | ||
| Hazard Codes | F | ||
| Risk Statements | 11-36/37/38-16 | ||
| Safety Statements | 16-26-36-9-33-29 | ||
| RIDADR | UN 2924 3/PG 2 |
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| WGK Germany | 3 |
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| RTECS | JN1000000 |
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| F | 10-21 | ||
| Autoignition Temperature | 240 °C | ||
| TSCA | Yes | ||
| HazardClass | 3 | ||
| PackingGroup | II | ||
| HS Code | 29310095 |
1,1,3,3-Tetramethyldisiloxane price More Price(10)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 235733 | 1,1,3,3-Tetramethyldisiloxane 97% | 3277-26-7 | 25g | $27.2 | 2020-08-18 | Buy |
| Sigma-Aldrich | 235733 | 1,1,3,3-Tetramethyldisiloxane 97% | 3277-26-7 | 100g | $82.6 | 2020-08-18 | Buy |
| TCI Chemical | T1437 | 1,1,3,3-Tetramethyldisiloxane >97.0%(GC) | 3277-26-7 | 25mL | $20 | 2020-06-24 | Buy |
| TCI Chemical | T1437 | 1,1,3,3-Tetramethyldisiloxane >97.0%(GC) | 3277-26-7 | 250mL | $117 | 2020-06-24 | Buy |
| Alfa Aesar | B23697 | 1,1,3,3-Tetramethyldisiloxane, 97% | 3277-26-7 | 100g | $105 | 2020-06-24 | Buy |
1,1,3,3-Tetramethyldisiloxane Chemical Properties,Uses,Production
Description
1,1,3,3-Tetramethyldisiloxane is soluble in many organic solvents, such as aromatic hydrocarbon and petroleum hydrocarbons, and so on. This product is a kind of widely used organic silicon intermediates, and usually be used as organic silicon blocking agent. Due to containing reactive Si-H groups in the molecular structure, it can be used in the synthesis of copolymer macromolecule by hydrosilylation. The synthesis of copolymer macromolecule can be made into a series of reactive silicone oil.Chemical Properties
Colorless or yellowish transparent liquidUses
1. Synthesis of polysiloxane containing faculties end groups.2. Can be used for the preparation of high performance organic silicone surfactants.
3. Applicable to the production of many products, such as addition silicon rubber, silica gel, Hydrogenpolysiloxane and plastic, resin modifier, dendrite polymer special additives, etc.
Uses
1, 1, 3, 3-Tetramethyldisiloxane is a kind of siloxane derivative, and can be used as a monomer for the preparation of silicone polymers or silicone resins. It is used as an intermediate for preparing other organosilicon compounds. It is also used in non-aqueous polymer preparation as well as a laboratory reagent. In organic synthesis, it finds an application as an effective reducing agent in platinum-catalyzed reduction of carboxamides to amines as well as in the Au/TiO2-catalyzed hydrosilylation of carbonyl compounds (e.g., reduction of aldehydes or ketones) relative to monohydrosilanes. It can also enable a direct bromination of carboxylic acids in the presence of indium bromide (InBr3) as catalyst.Purification Methods
1,Possible impurity is 1,1,5,5-tetramethyl-3-trimethylsiloxytrisiloxane b 154-155o/733mm. Fractionate it, collect fractions boiling below 80o and re-fractionate it. Its purity can be analysed by alkaline hydrolysis and measuring the volume of H2 liberated followed by gravimetric estimation of silica in the hydrolysate. It is unchanged when stored in glass containers in the absence of moisture for 2-3 weeks. Small amounts of H2 are liberated on long storage. Care should be taken when opening a container due to pressure developed. [Speier et al. J Am Chem Soc 79 974 1958, Emeléus & Smythe J Chem Soc 609 1958, IR: Kriegsmann Z Anorg Chem 299 78 1959, Beilstein 4 IV 3991.]References
https://www.alfa.com/en/catalog/B23697/http://www.organic-chemistry.org/chemicals/reductions/tetramethyldisiloxane-TMDSO.shtm
https://www.infona.pl/resource/bwmeta1.element.elsevier-722236cc-df38-37aa-bbed-029ec07d525f
1,1,3,3-Tetramethyldisiloxane Preparation Products And Raw materials
Raw materials
Preparation Products
1,1,3,3-Tetramethyldisiloxane Suppliers
Global( 246)Suppliers
| Supplier | Tel | Fax | Country | ProdList | Advantage | |
|---|---|---|---|---|---|---|
| Jiangxi New jiayi New Materials Co., Ltd. | 15988280056 |
0792-3170903 | info@xjysi.com; mina@xjysi.com | CHINA | 27 | 55 |
| Kingfirst chemical (nanjing) co.,ltd | 86-25-84522992 |
86-25-84774616 or 1617 | marketing@kingfirstchem.com | CHINA | 95 | 58 |
| Hubei Co-Formula Material Tech Co., Ltd. | +86-27-84459282 |
+86-27-84459282 | sales@cfmats.com | CHINA | 882 | 58 |
| SIMAGCHEM CORP | 13806087780 +86 13806087780 |
shaobowang@simagchem.com | CHINA | 17852 | 58 | |
| Capot Chemical Co.,Ltd. | +86（0）13336195806 +86-571-85586718 |
+86-571-85864795 | sales@capotchem.com | China | 19932 | 60 |
| Henan DaKen Chemical CO.,LTD. | +86-371-55531817 |
info@dakenchem.com | CHINA | 21734 | 58 | |
| Hangzhou Bayee Chemical Co., Ltd. | 0086-571-86990109 |
0086-571-85775919 | rachelhoo@bayeechem.com | China | 105 | 55 |
| Henan Tianfu Chemical Co.,Ltd. | 0371-55170693 |
0371-55170693 | info@tianfuchem.com | CHINA | 22622 | 55 |
| Shanghai Time Chemicals CO., Ltd. | +8618017249410 +86-021-57951555 |
+86-021-57951555 | jack.li@time-chemicals.com | CHINA | 1365 | 55 |
| Hangzhou FandaChem Co.,Ltd. | 0086 158 5814 5714 (Mobile |
+86-571-56059825 | fandachem@gmail.com | CHINA | 3479 | 55 |
Related articles
- Application of 1,1,3,3-Tetramethyldisiloxane
- 1,1,3,3-Tetramethyldisiloxane is soluble in many organic solvents, such as aromatic hydrocarbon and petroleum hydrocarbons, an....
- Oct 24，2019
View Lastest Price from 1,1,3,3-Tetramethyldisiloxane manufacturers
| Image | Release date | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
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2020-06-17 |
1,1,3,3-Tetramethyldisiloxane; TMDSO 3277-26-7 |
US $22.50 / KG | 1KG | min99% | 100MT/month | Hubei Co-Formula Material Tech Co., Ltd. | |
 |
2019-07-16 |
TMDSO 1,1,3,3-Tetramethyldisiloxane 3277-26-7 |
US $15.50 / KG | 1KG | 99.50% in stock CAS 3277-26-7 | 36 MT per month | Chemwill Asia Co.,Ltd. | |
 |
2019-07-16 |
1,1,3,3-Tetramethyldisiloxane 3277-26-7 |
US $22.50 / KG | 1KG | 99.50% in stock CAS 3277-26-7 | 36 MT per month | Chemwill Asia Co.,Ltd. |
3277-26-7(1,1,3,3-Tetramethyldisiloxane)Related Search:
3-(2-Aminoethylamino)propyl-dimethoxymethylsilane 3-Aminopropyltriethoxysilane SILANE COUPLING AGENT BIS (ACETOXYBUTYL) TETRAMETHYLDISILOXANE 1,3-BIS(IODOMETHYL)TETRAMETHYLDISILOXANE BIS(TRIFLUOROPROPYL)TETRAMETHYLDISILOXANE BIS(CARBOXYPROPYL)TETRAMETHYLDISILOXANE METHACRYLOXYPROPYL TERMINATED POLYDIMETHYLSILOXANE 1,3-BIS(CHLOROMETHYL)-1,1,3,3-TETRAMETHYLDISILOXANE,1,3-BIS(CHLOROMETHYL)TETRAMETHYLDISILOXANE,BIS(CHLOROMETHYL)TETRAMETHYLDISILOXANE,1,3-Di-(chloromethyl)-tetramethyldisiloxan BIS[(BICYCLOHEPTENYL)ETHYL]TETRAMETHYLDISILOXANE BIS(DICHLOROMETHYL)TETRAMETHYLDISILOXANE,1,3-BIS(DICHLOROMETHYL)TETRAMETHYLDISILOXANE,1,3-BIS(DICHLOROMETHYL)-1,1,3,3-TETRAMETHYLDISILOXANE 1,3-Bis(bromomethyl)-1,1,3,3-tetramethyldisiloxane,BIS(BROMOMETHYL)TETRAMETHYLDISILOXANE 1,3-BIS(HYDROXYBUTYL)TETRAMETHYLDISILOXANE 1,3-DIVINYLTETRAMETHYLDISILOXANE = 1,3-DIVINYL-1,1,3,3-TETRAMETHYLDISILOXANE 1,3-BIS(CARBOMETHOXY)TETRAMETHYLDISILOXANE BIS(3-CHLOROPROPYL)TETRAMETHYLDISILOXANE,1,3-BIS(CHLOROPROPYL)TETRAMETHYLDISILOXANE 1-ALLYL-1,1,3,3-TETRAMETHYLDISILOXANE BIS(M-ALLYLPHENYLDIMETHYLSILYLOCTYL)TETRAMETHYLDISILOXANE
- TETRAMETHYLDISILOXANE
- 1,3-Dihydrotetramethyldisiloxane
- Bis(dimethylsilyl) oxide
- bis(dimethylsilyl)oxide
- CT2030
- Dimethylsilyl ether
- dimethylsilylether
- Disiloxane, 1,1,3,3-tetramethyl-
- sym-Tetramethyldisiloxane
- (CH3)2HSiOSiH(CH3)2
- 1,1,3,3-tetramethyl-disiloxan
- 1,1-Dihydro-1,1,3,3-tetramethyldisiloxane
- TMDO
- TMDSO
- 1,1,3,3-Tetramethyldisiloxane 3277-26-7 TMDSO
- TMDSO 1,1,3,3-Tetramethyldisiloxane
- [(dimethylsilyl)oxy]dimethylsilane
- SILOXANE HSI2
- 1,1,3,3-TETRAMETHYLDISILOXANE
- BIS(DIMETHYLSILYL) ETHER
- 1,1,3,3-TETRAMETHYLDISILOXANE,WACKER QUALITY
- Tetramethyldisiloxan
- 1,1,3,3,-TETRAMETHYLDISLOXANE
- 1,1,3,3-TETRAMETHYLDISILOXANE 97+%
- 1,1,3,3-Tetramethyl-1,3-dihydrodisiloxane
- 1,1,3,3-Tetramethyl-1,3-disiloxane
- 5-(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)-2-(trifluoromethyl)pyridine
- 1,1,3,3-Tetramethyl dihydro disiloxane
- 1,1,3,3-Tetramethyld
- (Me2HSi)2O
- 1,1,3,3-TetraMethyldisiloxane, 97% 100ML
- Dimethylsilyl ethe
- 1,1,3,3-TETRAMETHYLDISILOXANE FOR SYNTHE
- Tetramethyldiydrodisiloxane
- 1,1,3,3-Tetramethyldisiloxane, 99+% TMDSO (99.9999%-Si) PURATREM
- 1,1,3,3-Tetramethyldisiloxane, 98.5%
- (dimethyl-λ3-silanyl)oxy-dimethylsilicon
- (dimethyl-λ3-silanyl)oxy-dimethylsilicon
- 3277-26-7
- CH32SiH2O
- C4H14OSi2
- Organometallic Reagents
- Organosilicon
- Si-H Compounds
- Si-O Compounds
- Si (Classes of Silicon Compounds)
- Reduction
- Siloxanes
- Tetramethyldisiloxane
- Silicone serier
- Reduction
- Si (Classes of Silicon Compounds)
- Si-H Compounds
- Siloxanes
- Si-O Compounds
- Synthetic Organic Chemistry
- Hydrogensilanes Hydrogensiloxanes
- Reducing Agents
