NICKEL(II) CHLORIDE
- CAS No.
- 69098-15-3
- Chemical Name:
- NICKEL(II) CHLORIDE
- Synonyms
- NICKEL(II) CHLORIDE HYDRATE;Puratronic99.995%(metalsbasis);NICKEL(II) CHLORIDE HYDRATE, 99.95%;nickel(ii) chloride hydrate, puratronic;Nickel(II) chloride hydrate 99.95% trace metals basis;Nickel(II) chloride hydrate, Puratronic, 99.995% (metals basis);Nickel(II) chloride hydrate, Puratronic(R), 99.995% (metals basis)
- CBNumber:
- CB5370083
- Molecular Formula:
- Cl2H2NiO
- Molecular Weight:
- 147.61
- MDL Number:
- MFCD00149808
- MOL File:
- 69098-15-3.mol
| Melting point | 1001 °C |
|---|---|
| vapor pressure | 1 mm Hg ( 671 °C) |
| form | Crystalline Aggregates |
| color | Green |
| Water Solubility | Freely soluble in water. Soluble in ethylene glycol, ethanol, and ammonium hydroxide. |
| Sensitive | Hygroscopic |
| Merck | 14,6505 |
| Exposure limits | NIOSH: IDLH 10 mg/m3; TWA 0.015 mg/m3 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |    GHS06,GHS08,GHS09 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H301+H331-H315-H317-H334-H350i-H360D-H372-H410 | |||||||||
| Precautionary statements | P202-P273-P280-P301+P310-P302+P352-P304+P340+P311 | |||||||||
| Hazard Codes | T,N | |||||||||
| Risk Statements | 45-23/24/25-36/37/38-42/43-68-50/53-48/23-38-23/25-61-49 | |||||||||
| Safety Statements | 53-26-27-28-36/37/39-45-61-60 | |||||||||
| RIDADR | UN 3288 6.1/PG 3 | |||||||||
| WGK Germany | 3 | |||||||||
| RTECS | QR6480000 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 6.1 | |||||||||
| PackingGroup | III | |||||||||
| NFPA 704 |
|
NICKEL(II) CHLORIDE price More Price(11)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 364304 | Nickel(II) chloride hydrate 99.95% trace metals basis | 69098-15-3 | 100g | $75.2 | 2024-03-01 | Buy |
| Sigma-Aldrich | 364304 | Nickel(II) chloride hydrate 99.95% trace metals basis | 69098-15-3 | 500g | $220 | 2024-03-01 | Buy |
| Alfa Aesar | 010815 | Nickel(II) chloride hydrate, Puratronic?, 99.995% (metals basis) | 69098-15-3 | 5g | $54.6 | 2024-03-01 | Buy |
| Alfa Aesar | 010815 | Nickel(II) chloride hydrate, Puratronic?, 99.995% (metals basis) | 69098-15-3 | 25g | $135.45 | 2023-01-06 | Buy |
| Alfa Aesar | 010815 | Nickel(II) chloride hydrate, Puratronic?, 99.995% (metals basis) | 69098-15-3 | 100g | $462 | 2023-01-06 | Buy |
NICKEL(II) CHLORIDE Chemical Properties,Uses,Production
Uses
It is used in electroplating and as a catalyst for organic conversions, for example in chemo-selective thioacetalization of aldehydes. In combination with lithium aluminum hydride, it serves as a reducing agent for alkenes, alkynes, and organic halides; it can cleave N-O bond and open epoxides. It is a precursor to several nickel-phosphine complexes, such as bis(triphenylphosphine)nickel(II) chloride, which are used in alkyne trimerizations, carbonylations, and as catalysts in organic reactions such as Suzuki-Miyaura cross coupling reactions as an alternative to palladium(0) catalysts. It is the precursor to acetylacetonate complex of Ni, used for producing 1,5-cyclooctadiene complex, an important reagent in organonickel chemistry. It can be used to prepare the sandwich compound nickelocene through dimethoxyethane complex of nickel chloride.
Purification Methods
It crystallises from dilute HCl to form the green hexahydrate. At 70o this dehydrates to the tetrahydrate, and at higher temperatures it forms the anhydrous salt. It sublimes in yellow hexagonal scales in a stream of HCl. Store it in a desiccator as it is deliquescent. [Hart & Partington J Chem Soc 104 1943.]
NICKEL(II) CHLORIDE Preparation Products And Raw materials
Raw materials
Preparation Products
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
| Alfa Chemistry | +1-5166625404 | Info@alfa-chemistry.com | United States | 21317 | 58 |
| Shanghai Acmec Biochemical Technology Co., Ltd. | +undefined18621343501 | product@acmec-e.com | China | 33349 | 58 |
| Aladdin Scientific | +1-833-552-7181 | sales@aladdinsci.com | United States | 52927 | 58 |
| Alfa Aesar | 400-6106006 | saleschina@alfa-asia.com | China | 30132 | 84 |
| Energy Chemical | 021-021-58432009 400-005-6266 | sales8178@energy-chemical.com | China | 44751 | 61 |
| Adamas Reagent, Ltd. | 400-6009262 16621234537 | zhangsn@titansci.com | China | 14113 | 59 |
| Shanghai Hanhong Scientific Co.,Ltd. | 021-54306202 13764082696; | info@hanhongsci.com | China | 42982 | 64 |
| Shanghai Sunway Pharmaceutical Technology Co., Ltd | +8618575662672 18575662672 | mzeng@3wpharm.com | China | 10053 | 57 |
| Shanghai Macklin Biochemical Co.,Ltd. | 15221275939 15221275939 | shenlinxing@macklin.cn | China | 15878 | 55 |