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Nickel(II) acetate tetrahydrate

Physical Properties Uses Preparation
Nickel(II) acetate tetrahydrate
Nickel(II) acetate tetrahydrate structure
CAS No.
6018-89-9
Chemical Name:
Nickel(II) acetate tetrahydrate
Synonyms
Nickle Acetate;NICKEL ACETATE;NICKEL ACETATE 4H2O;NICKEL ACETATE TETRA;NICKEL ACETATE HYDRATE;ACETIC ACID NICKEL SALT;NICKEL(II) ACETATE 4 H2O;Nickel(II) acetate hydrate;diacetatonickeltetrahydrate;nickeldiacetatetetrahydrate
CBNumber:
CB5378827
Molecular Formula:
C4H14NiO8
Formula Weight:
248.84
MOL File:
6018-89-9.mol

Nickel(II) acetate tetrahydrate Properties

Melting point:
°Cd ec.)
Boiling point:
16℃
Density 
1.798 g/mL at 25 °C(lit.)
form 
Solid
Specific Gravity
1.798
color 
White to off-white
Water Solubility 
182 g/L (20 ºC)
Sensitive 
Hygroscopic
Merck 
14,6499
BRN 
3730764
Stability:
Stable.
CAS DataBase Reference
6018-89-9(CAS DataBase Reference)
EPA Substance Registry System
Acetic acid, nickel(2+) salt, tetrahydrate(6018-89-9)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
Hazard Codes  T,Xn,N
Risk Statements  45-22-43-40-68-50/53-48/23-42/43-20/22-61-49
Safety Statements  53-36/37-45-24-22-61-60
RIDADR  UN 3077 9 / PGIII
WGK Germany  3
RTECS  QR6126000
TSCA  Yes
HazardClass  9
PackingGroup  III
HS Code  29152990
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H332 Harmful if inhaled Acute toxicity,inhalation Category 4 Warning P261, P271, P304+P340, P312
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled Sensitisation, respiratory Category 1 Danger P261, P285, P304+P341, P342+P311,P501
H341 Suspected of causing genetic defects Germ cell mutagenicity Category 2 Warning P201,P202, P281, P308+P313, P405,P501
H350 May cause cancer Carcinogenicity Category 1A, 1B Danger
H360 May damage fertility or the unborn child Reproductive toxicity Category 1A, 1B Danger
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger P260, P264, P270, P314, P501
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning P273, P391, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
Precautionary statements:
P201 Obtain special instructions before use.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P405 Store locked up.

Nickel(II) acetate tetrahydrate price More Price(18)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 244066 Nickel(II) acetate tetrahydrate 98% 6018-89-9 100g $28.3 2018-11-13 Buy
Sigma-Aldrich 244066 Nickel(II) acetate tetrahydrate 98% 6018-89-9 500g $70 2018-11-13 Buy
Alfa Aesar 010813 Nickel(II) acetate tetrahydrate, Puratronic?, 99.999% (metals basis) 6018-89-9 5g $89.5 2018-11-16 Buy
Alfa Aesar 010813 Nickel(II) acetate tetrahydrate, Puratronic?, 99.999% (metals basis) 6018-89-9 25g $354 2018-11-16 Buy
Strem Chemicals 28-1100 Nickel(II) acetate tetrahydrate (99.999%-Ni) PURATREM 6018-89-9 25g $213 2018-11-13 Buy

Nickel(II) acetate tetrahydrate Chemical Properties,Uses,Production

Physical Properties

The tetrahydrate is a green crystalline solid; sweet taste; odor of acetic acid; density 1.744 g/cm3; loses water on heating to form a yellow-green powder of anhydrous nickel acetate; decomposes above 250°C; soluble in water, 17g/100mL at 20°C; sparingly soluble in alcohol.

Uses

Nickel acetate is used as a catalyst. It also is used as a dye mordant in textiles. Other applications are in electroplating nickel and as a sealer for anodizing aluminum.

Preparation

Nickel acetate is prepared by reacting nickel hydroxide or nickel carbonate with dilute acetic acid. The tetrahydrate is crystallized from solution.
Ni(OH)2 + 2CH3COOH → (CH3COO)2Ni + 2H2O
NiCO3 + 2CH3COOH → (CH3COO)2Ni + CO2 + 2H2O
On heating, the solution hydrolyzes depositing nickel hydroxide.

Chemical Properties

green monoclinic crystal(s); hygroscopic; used in textiles as a mordant [HAW93]

Uses

Nickel(II) acetate tetrahydrate can be used in synthesis of polynuclear-nickel polyoxotungstate cluster compounds that are ideal for the design of molecular magnets.

Safety Profile

Confirmed human carcinogen. Poison by ingestion and intraperitoneal routes. Mutation data reported. When heated to decomposition it emits acrid smoke and irritating fumes. See also NICKEL(II) ACETATE and NICKEL COMPOUNDS.

Purification Methods

The acetate crystallises from aqueous AcOH as the green tetrahydrate salt. It is soluble in 6 parts of H2O. It forms lower hydrates and should be kept in a well-sealed container. [Hardt & Pohlmann Z Anorg Allgem Chem 343 92 1966, Beilstein 2 IV 120.]

Nickel(II) acetate tetrahydrate Preparation Products And Raw materials

Raw materials

Preparation Products


Nickel(II) acetate tetrahydrate Suppliers

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