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4-Bromo-1,2-(methylenedioxy)benzene

4-Bromo-1,2-(methylenedioxy)benzene Structure
4-Bromo-1,2-(methylenedioxy)benzene structure
CAS No.
2635-13-4
Chemical Name:
4-Bromo-1,2-(methylenedioxy)benzene
Synonyms
5-bromobenzo[d][1,3]dioxole;5-BROMO-1,3-BENZODIOXOLE;1,2-METHYLENEDIOXY-4-BROMOBENZENE;1-BROMO-3,4-(METHYLENEDIOXY)BENZENE;enedioxy)benzene;BROMOBENZODIOXOLE;TIMTEC-BB SBB006662;4-Bromo-1,2-(methyL;Paroxetine Impurity 89;2-Methylenedioxybenzene
CBNumber:
CB5398696
Molecular Formula:
C7H5BrO2
Molecular Weight:
201.02
MDL Number:
MFCD00005821
MOL File:
2635-13-4.mol
MSDS File:
SDS
Last updated:2023-11-29 15:56:16
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4-Bromo-1,2-(methylenedioxy)benzene Properties

Boiling point 85-86 °C1 mm Hg(lit.)
Density 1.669 g/mL at 25 °C(lit.)
refractive index n20/D 1.583(lit.)
Flash point >230 °F
storage temp. Inert atmosphere,Room Temperature
solubility Chloroform, Methanol (Sparingly)
form Liquid
Specific Gravity 1.669
color Clear yellow-orange
BRN 127407
Stability Light Sensitive
InChI InChI=1S/C7H5BrO2/c8-5-1-2-6-7(3-5)10-4-9-6/h1-3H,4H2
InChIKey FBOYMIDCHINJKC-UHFFFAOYSA-N
SMILES O1C2=CC=C(Br)C=C2OC1
CAS DataBase Reference 2635-13-4(CAS DataBase Reference)
NIST Chemistry Reference 4-Bromo-1,2-(methylenedioxy)benzene(2635-13-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36-37/39
WGK Germany  3
Hazard Note  Irritant
HS Code  29329990
NFPA 704
1
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4-Bromo-1,2-(methylenedioxy)benzene price More Price(43)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 288314 1-Bromo-3,4-(methylenedioxy)benzene 97% 2635-13-4 100g $67.6 2024-03-01 Buy
Sigma-Aldrich 288314 1-Bromo-3,4-(methylenedioxy)benzene 97% 2635-13-4 25g $111 2024-03-01 Buy
TCI Chemical B1230 4-Bromo-1,2-methylenedioxybenzene >98.0%(GC) 2635-13-4 5g $36 2024-03-01 Buy
TCI Chemical B1230 4-Bromo-1,2-methylenedioxybenzene >98.0%(GC) 2635-13-4 25g $94 2024-03-01 Buy
Alfa Aesar A17906 4-Bromo-1,2-(methylenedioxy)benzene, 98% 2635-13-4 5g $29.65 2024-03-01 Buy
Product number Packaging Price Buy
288314 100g $67.6 Buy
288314 25g $111 Buy
B1230 5g $36 Buy
B1230 25g $94 Buy
A17906 5g $29.65 Buy

4-Bromo-1,2-(methylenedioxy)benzene Chemical Properties,Uses,Production

Chemical Properties

clear yellow-orange liquid

Synthesis Reference(s)

Tetrahedron, 64, p. 4999, 2008 DOI: 10.1016/j.tet.2008.03.085

General Description

The coupling of 1-bromo-3,4-(methylenedioxy)benzene with β-methallyl alcohol was catalyzed by Pd(OAc)2 in combination with P(t-Bu)3.

Synthesis

NBS (1.87 g, 10.50 mmol, 1.05 equiv.), HPLC-grade acetonitrile and benzo[d][1,3]dioxole (10 mmol) were placed into a flask and stirred until completely homogeneous. The solution was pumped through the Corning G1 photoreactor at the desired flow rate. The reaction mixture was collected from the reactor and combined with the two separate streams of toluene and water into a 10-mL Vapourtec static mixer coil; then, the mixture was pumped into a Zaiput liquid-liquid membrane separator, the organic phase was collected and passed twice more through the Zaiput membrane separator. The organic phase was evaporated under reduced pressure, providing the corresponding brominated product 4-Bromo-1,2-(methylenedioxy)benzene.
4-Bromo-1,2-(methylenedioxy)benzene

4-Bromo-1,2-(methylenedioxy)benzene synthesis

128-08-5
274-09-9
2635-13-4
Synthesis of 4-Bromo-1,2-(methylenedioxy)benzene from N-Bromosuccinimide and 1,3-Benzodioxole

4-Bromo-1,2-(methylenedioxy)benzene Preparation Products And Raw materials

Raw materials

Preparation Products

3,4-METHYLENEDIOXYPHENYLBORONIC ACID PIPERONALDOXIME 1-IODO-3,4-METHYLENEDIOXYBENZENE 5-Bromo-4-iodo-1,3-benzodioxole 3,4-(METHYLENEDIOXY)THIOPHENOL
3,4-(Methylenedioxy)aniline

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4-Bromo-1,2-(methylenedioxy)benzene Suppliers

Global( 339)Suppliers
Supplier Tel Email Country ProdList Advantage
Shaoxing Fangxiao Chemical Co., LTD
+86-13456999252 +86-13868192239 kenny@fangxiaochem.com China 50 58
Hebei Mojin Biotechnology Co., Ltd 		+8613288715578 sales@hbmojin.com China 12456 58
Capot Chemical Co.,Ltd. 		571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Shanxi Naipu Import and Export Co.,Ltd 		+86-13734021967 +8613734021967 kaia@neputrading.com China 1011 58
career henan chemical co 		+86-0371-86658258 sales@coreychem.com China 29914 58
NINGBO INNO PHARMCHEM CO., LTD. 		13867897135 sales@nbinno.com CHINA 925 58
Changzhou Ansciep Chemical Co., Ltd. 		+86 519 86305871 sales@ansciepchem.com CHINA 4242 58
Accela ChemBio Inc. 		(+1)-858-699-3322 info@accelachem.com United States 19965 58
Hebei Guanlang Biotechnology Co., Ltd. 		+86-19930503282 alice@crovellbio.com China 8823 58
Supplier Advantage
Shaoxing Fangxiao Chemical Co., LTD
58
Hebei Mojin Biotechnology Co., Ltd 		58
Capot Chemical Co.,Ltd. 		60
Henan Tianfu Chemical Co.,Ltd. 		55
Shanxi Naipu Import and Export Co.,Ltd 		58
career henan chemical co 		58
NINGBO INNO PHARMCHEM CO., LTD. 		58
Changzhou Ansciep Chemical Co., Ltd. 		58
Accela ChemBio Inc. 		58
Hebei Guanlang Biotechnology Co., Ltd. 		58

View Lastest Price from 4-Bromo-1,2-(methylenedioxy)benzene manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-Bromo-1,2-(methylenedioxy)benzene pictures 2023-08-30 4-Bromo-1,2-(methylenedioxy)benzene
2635-13-4
 US $500.00 / g 100g 99% 200ton Hebei Mojin Biotechnology Co., Ltd
5-Bromo-1,3-benzodioxole pictures 2022-12-01 5-Bromo-1,3-benzodioxole
2635-13-4
 US $200.00 / g 10g 99% 1000t/month Hebei Best Biological Technology Co., Ltd
4-Bromo-1,2-(Methylenedioxy)Benzene pictures 2022-04-20 4-Bromo-1,2-(Methylenedioxy)Benzene
2635-13-4
 US $100.00 / bag 1bag 99 500 Shanxi Naipu Import and Export Co.,Ltd

4-Bromo-1,2-(methylenedioxy)benzene Spectrum

4-Bromo-1,2-(methylenedioxy)benzene(2635-13-4)MS4-Bromo-1,2-(methylenedioxy)benzene(2635-13-4)1HNMR4-Bromo-1,2-(methylenedioxy)benzene(2635-13-4)13CNMR4-Bromo-1,2-(methylenedioxy)benzene(2635-13-4)IR14-Bromo-1,2-(methylenedioxy)benzene(2635-13-4)Raman

2635-13-4(4-Bromo-1,2-(methylenedioxy)benzene)Related Search:

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4-BROMO-1,2-(METHYLENEDIOXY)ENZENE 4-Bromo-1,2-methylenedioxybenzene 99% 5-Bromo-1,3-benzodioxole 99% BROMOBENZODIOXOLE 4-Bromo-1,2-(methylenedioxy)benzene-5 1-Bromo-3,4-(methylenedioxy)benzene 97% 5-Bromo-1,3-benzodioxolane 3,4-Methylenedioxy bromobenzene 1,3-Benzodioxol-5-bromo 4-BROMO-1,2-METHYLENEDIOXYBENZENE 97+% 3,4-Methylenedioxybrombenzene 4-Bromo-1,2-(methylenedioxy)benzene, 5-Bromo-1,3-benzodioxole 1,3-Benzodioxole-5-yl bromide 2-Methylenedioxybenzene 4-BroMo-1,2-(Methylenedioxy)benzene, 97% 25GR 5-Bromo-1,3-benzodioxole 3,4-Methylenedioxybromobenzene 4-BroMo-1,2-(Methylenedixoy) benzene 1-BroMo-3,4-(Methylenedioxy)benzene, 98%+ TIMTEC-BB SBB006662 4-Bromomethylenedioxybenzene 1,3-BENZODIOXOLE, 5-BROMO- 4-broMo -1,2-(Ya Jiaji twooxygenradicals)benzene 3,4-METHYLENEDIOXYBROMOBENZENE 3,4-METHYLENDIOXYBROMOBENZENE 4-BROMO-1,2-METHYLENEDIOXYBENZENE 5-BROMOBENZO-1,3-DIOXOLE 4-Bromo-1,2-(Methylenedioxy)Be 4-Bromo-1,2-(methylenedioxy)benzene (Bromobenzodioxole) 4-Bromo-1,2-methylenedioxybenzene > 4-Bromo-1,2-(methyL enedioxy)benzene 5-bromo-2H-1,3-benzodioxole 5-bromobenzo[d][1,3]dioxole 1,2-METHYLENEDIOXY-4-BROMOBENZENE 1-BROMO-3,4-(METHYLENEDIOXY)BENZENE 5-BROMO-1,3-BENZODIOXOLE Paroxetine Impurity 89 2635-13-4 128577-477-9 Protected Alcohols/Phenols Oxygen Compounds Organic Building Blocks Building Blocks ARYL HALIDE Building Blocks Chemical Synthesis Organic Building Blocks Oxygen Compounds Protected Alcohols/Phenols Miscellaneous Bromine Compounds Miscellaneous Compounds Aromatic Hydrocarbons (substituted) & Derivatives 2635-13-4