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4-Ethynylanisole

CAS No.
768-60-5
Chemical Name:
4-Ethynylanisole
Synonyms
1-ETHYNYL-4-METHOXYBENZENE;4-METHOXYPHENYLACETYLENE;NSC 71091;Anisylacetylene;P-ETHYNYLANISOLE;4-ETHYNYLANISOLE;4-Ethynylanisode;4-Ethynylanisole>4-Ethynylanisole,97%;4-Ethynylanisole 97%
CBNumber:
CB5403244
Molecular Formula:
C9H8O
Molecular Weight:
132.16
MDL Number:
MFCD00168815
MOL File:
768-60-5.mol
MSDS File:
SDS
Last updated:2023-05-25 10:25:49

4-Ethynylanisole Properties

Melting point 28-29 °C (lit.)
Boiling point 87-91 °C/11 mmHg (lit.)
Density 1.019 g/mL at 25 °C (lit.)
refractive index n20/D 1.563(lit.)
Flash point 180 °F
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility Acetontrile (Slightly), Chloroform (Slightly)
form Liquid or Low Melting Solid
color Clear colorless to deep yellow or brown
Water Solubility Insoluble in water. Soluble in chloroform, acetone, dichloromethane, and methanol.
Sensitive Light Sensitive
Stability Light and Temperature Sensitive
InChIKey KBIAVTUACPKPFJ-UHFFFAOYSA-N
CAS DataBase Reference 768-60-5(CAS DataBase Reference)
NIST Chemistry Reference 4-CH3O-C6H4-CCH(768-60-5)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H302-H315-H319-H335
Precautionary statements  P261-P280-P301+P312-P302+P352-P305+P351+P338
Hazard Codes  Xn,F
Risk Statements  22
Safety Statements  24/25
RIDADR  UN 1325 4.1/PG 2
WGK Germany  3
PackingGroup  II
HS Code  29093090
NFPA 704
2
2 0

4-Ethynylanisole price More Price(47)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 206490 4-Ethynylanisole 97% 768-60-5 1g $113 2024-03-01 Buy
Sigma-Aldrich 206490 4-Ethynylanisole 97% 768-60-5 5g $341 2024-03-01 Buy
TCI Chemical E0603 4-Ethynylanisole >98.0%(GC) 768-60-5 1g $51 2024-03-01 Buy
TCI Chemical E0603 4-Ethynylanisole >98.0%(GC) 768-60-5 5g $137 2024-03-01 Buy
Alfa Aesar H26283 4-Methoxyphenylacetylene, 99% 768-60-5 1g $74 2024-03-01 Buy
Product number Packaging Price Buy
206490 1g $113 Buy
206490 5g $341 Buy
E0603 1g $51 Buy
E0603 5g $137 Buy
H26283 1g $74 Buy

4-Ethynylanisole Chemical Properties,Uses,Production

Chemical Properties

Pale Yellow Oil

Uses

1,3-dipolar cycloaddition of acceptor-cyclopropylmethylsilanes affords functionalized cyclopentenes in good yields.1

Uses

Intermediate in the synthesis of histamine H3-receptor antagonists. Also utilized to prepare its luminescent copper complex

Uses

4-Ethynylanisole was used in the synthesis of photo luminescent 1,2-dihydrophosphinines via a [4 + 2] cycloaddition. Along with an arylboronic acid and sodium azide in a copper-catalyzed, three-component synthesis of trisubstituted 1,2,4-triazoles. In a study of a gold (III)-catalyzed hydroamination of alkynes leading to N-vinylindoles3.

Uses

Intermediates of Liquid Crystals

Definition

ChEBI: 1-Eth-1-ynyl-4-methoxybenzene is a member of methoxybenzenes.

Synthesis Reference(s)

Organic Syntheses, Coll. Vol. 9, p. 230, 1998
Synthesis, p. 305, 1978
Tetrahedron, 62, p. 6673, 2006 DOI: 10.1016/j.tet.2005.12.077

General Description

4-Ethynylanisole forms the corresponding propargyl aldehyde in good yield directly from DMF-dimethyl acetal without the need for making an acetylide salt. 1,3-dipolar cycloaddition of acceptor-cyclopropylmethylsilanes affords functionalized cyclopentenes in good yields.

Global( 250)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15928 58
Henan Tianfu Chemical Co.,Ltd.
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Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63711 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 49390 58

View Lastest Price from 4-Ethynylanisole manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-Ethynylanisole pictures 2021-07-13 4-Ethynylanisole
768-60-5
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
4-Ethynylanisole pictures 2021-07-10 4-Ethynylanisole
768-60-5
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
4-Ethynylanisole pictures 2019-07-06 4-Ethynylanisole
768-60-5
US $7.00 / KG 1KG 99% 100KG Career Henan Chemical Co
  • 4-Ethynylanisole pictures
  • 4-Ethynylanisole
    768-60-5
  • US $15.00-10.00 / KG
  • 99%+ HPLC
  • Zhuozhou Wenxi import and Export Co., Ltd
  • 4-Ethynylanisole pictures
  • 4-Ethynylanisole
    768-60-5
  • US $15.00-10.00 / KG
  • 99%+ HPLC
  • Zhuozhou Wenxi import and Export Co., Ltd

4-Ethynylanisole Spectrum

Benzene, 1-ethynyl-4-methoxy- P-ETHYNYLANISOLE 1-ETH-1-YNYL-4-METHOXYBENZENE 4-ETHYNYLANISOLE 4'-METHOXYPHENYL ACETYLENE Benzene, 1-ethynyl-4-methoxy- (9CI) 4-Ethynylmethoxybenzene 4-METHOXY PHENYL ACETYLENE,98% 1-ETHYNYL-4-METHOXYBENZENE/4-METHOXYPHENYLACETYLENE (4-Methoxyphenyl)ethyne 1-(4-Methoxyphenyl)ethyne 4-Ethynylanisole,97% 4-Methoxyphenylethyne p-Methoxyphenylacetylene 4-Ethynylanisole,1-Ethynyl-4-methoxybenzene 1-Ethynyl-4-methoxybenzene, 4-Ethynylanisole 4-Methoxy-1-ethynylbenzene Anisylacetylene NSC 71091 p-Methoxyphenylethyne 4-Ethynylanisole 97% 4-Ethynylanisode 4-Methoxyphenylacetylene 98% 4-ETHYNYLANISOLE, 98%4-ETHYNYLANISOLE, 98%4-ETHYNYLANISOLE, 98%4-ETHYNYLANISOLE, 98% 4-Ethynylanisole> 4-Methoxyphenylacetalene 4-Ethynylanisole,99% CAS No.768-60-5 4-Ethynylanisole 1-ETHYNYL-4-METHOXYBENZENE 4-METHOXYPHENYLACETYLENE 768-60-5 768-60-7 CH3OC6H4CCH CH3OC6H4C8801CH Alkynes Building Blocks Organic Building Blocks Terminal Alkynes Building Blocks Chemical Synthesis Organic Building Blocks Terminal Liquid Crystal intermediates Aromatics Compounds Aromatics pharmacetical