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BARIUM PERCHLORATE

CAS No.
13465-95-7
Chemical Name:
BARIUM PERCHLORATE
Synonyms
CPS 55R;Barium perchlorat;BARIUM PERCHLORATE;bariumdiperchlorate;Perchloricacid,bariumsalt;BariumPerchlorateExtraPure;Barium perchlorate, GR 98%;BARIUM PERCHLORATE STANDARD;BARIUM PERCHLORATE, 99.999%;barium perchlorate solution
CBNumber:
CB5417755
Molecular Formula:
BaClH3O4
Molecular Weight:
239.8
MDL Number:
MFCD00003440
MOL File:
13465-95-7.mol
MSDS File:
SDS
Last updated:2024-03-14 15:18:26

BARIUM PERCHLORATE Properties

Melting point 505 °C(lit.)
Density 3.2 g/mL at 25 °C(lit.)
Flash point 21 °C
storage temp. Store at +5°C to +30°C.
solubility 1985g/l
form Powder
Specific Gravity 3.2
color White
PH 5.6 (100g/l, H2O, 20℃)
Odor Odorless
Oxidising Properties The substance or mixture is classified as oxidizing with the subcategory 1.
Water Solubility Soluble in water.
Sensitive Hygroscopic
Merck 14,987
Exposure limits ACGIH: TWA 0.5 mg/m3
NIOSH: IDLH 50 mg/m3; TWA 0.5 mg/m3
CAS DataBase Reference 13465-95-7(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII EY48PA0C98
EPA Substance Registry System Perchloric acid, barium salt (2:1) (13465-95-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS03,GHS07
Signal word  Danger
Hazard statements  H271-H302+H332
Precautionary statements  P210-P301+P312+P330-P304+P340+P312
Hazard Codes  O,Xn,Xi
Risk Statements  9-20/22-67-36-10
Safety Statements  27-26
RIDADR  UN 1447 5.1/PG 2
WGK Germany  1
RTECS  SC7550000
TSCA  Yes
HazardClass  5.1
PackingGroup  II
HS Code  28291990
NFPA 704
0
2 1
OX

BARIUM PERCHLORATE price More Price(18)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 241733 Barium perchlorate 97% 13465-95-7 100g $112 2024-03-01 Buy
Sigma-Aldrich 1.01738 Barium perchlorate anhydrous for analysis EMSURE? 13465-95-7 250g $290 2024-03-01 Buy
Sigma-Aldrich 1.09086 Barium perchlorate solution in 2-propanol/water (80/20) c(Ba(ClO?)?) = 0.005 mol/l Titripur? Reag. USP 13465-95-7 1L $96.1 2024-03-01 Buy
Sigma-Aldrich 1.01738 Barium perchlorate anhydrous for analysis EMSURE? 13465-95-7 1kg $636 2024-03-01 Buy
Alfa Aesar 011657 Barium perchlorate, anhydrous 13465-95-7 100g $48.7 2024-03-01 Buy
Product number Packaging Price Buy
241733 100g $112 Buy
1.01738 250g $290 Buy
1.09086 1L $96.1 Buy
1.01738 1kg $636 Buy
011657 100g $48.7 Buy

BARIUM PERCHLORATE Chemical Properties,Uses,Production

Description

Barium perchlorate is a white crystalline solid.Molecular weight=336.2; Freezing/Melting point=400℃(trihydrate); 505℃ (anhydrous). Hazard Identification(based on NFPA-704 M Rating System): Health 2,Flammability 0, Reactivity 0. Highly soluble in water;solubility=200 g/100 mL at 33℃

Chemical Properties

White Crystalline Powder

Uses

In the determination of ribonuclease; as absorbent for water in C and H analysis.

Uses

Ribonuclease determination and effective desiccant.

Uses

Barium perchlorate, anhydrous is used to make explosives. It is also used as desiccant, ribonuclease determination.

General Description

A white crystalline solid. Noncombustible, but accelerates burning of combustible materials. May explode if large quantities are involved in a fire or the combustible material is finely divided. Prolonged exposure to fire or heat may result in an explosion. Used to make explosives.

Air & Water Reactions

Water soluble.

Reactivity Profile

Reflux heating of BARIUM PERCHLORATE with alcohols yields perchlorate esters, which are highly explosive [Kirk-Othmer 2nd ed. 5:75 1963]. A strong oxidizing agent. May react violently with organic materials.

Health Hazard

Inhalation or contact with eyes or skin causes irritation. Ingestion causes excessive salivation, vomiting, colic, diarrhea, convulsive tremors, slow, hard pulse, and elevated blood pressure; hemorrhages may occur in the stomach, intestines, and kidneys; muscular paralysis may follow.

Fire Hazard

Behavior in Fire: Increases the intensity of fire. Containers may explode.

Safety Profile

A poison. An unstable material. An oxidizer. When refluxed with an alcohol highly explosive alkyl perchlorates are formed. When heated to decomposition it emits toxic fumes of Cl-. A desiccant. See also PERCHLORATES and BARIUM COMPOUNDS.

Potential Exposure

It is used to make explosives and inexperimental rocket fuels.

First aid

If this chemical gets into the eyes, remove anycontact lenses at once and irrigate immediately for at least15 min, occasionally lifting upper and lower lids. Seekmedical attention immediately. If this chemical contactsthe skin, remove contaminated clothing and wash immediately with soap and water. Seek medical attention immediately. If this chemical has been inhaled, remove fromexposure, begin rescue breathing (using universal precautions, including resuscitation mask) if breathing hasstopped and CPR if heart action has stopped. Transferpromptly to a medical facility. When this chemical hasbeen swallowed, get medical attention. Give large quantities of water and induce vomiting. Do not make an unconscious person vomit.

storage

Color Comables and combustibles. Store in tightly closed containersin a cool, well-ventilated area away from heat sources,sources of shock, or the incompatible materials cited above.Sources of ignition, such as smoking and open flames, areprohibited where Barium perchlorate is handled, used, orstored. See OSHA Standard 1910.104 and NFPA 43A Codefor the Storage of Liquid and Solid Oxidizers for detailedhandling and storage regulationsde—Yellow: Reactive Hazard; Store in alocation separate from other materials, especially flam

Shipping

Barium perchlorate requires a shipping labelof “OXIDIZER, POISONOUS/TOXIC MATERIALS.”This material falls in Hazard Class 5.1 and PackingGroup II.[19, 20]

Purification Methods

Recrystallise the perchlorate twice from water. [Schmeisser in Handbook of Preparative Inorganic Chemistry (Ed. Brauer) Academic Press Vol I p 320 1963.]

Incompatibilities

An oxidizing agent. Contact with organicand combustible materials (such as paper, wood, and oil),finely divided metals (specifically magnesium and aluminum), sulfur, calcium hydride, and strontium hydride sinceviolent reactions occur

BARIUM PERCHLORATE Preparation Products And Raw materials

Raw materials

Preparation Products

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BARIUM PERCHLORATE Spectrum

CPS 55R Perchloric acid, bariumsalt (2:1) Barium perchlorate anhydrousAnalytical Reagent Grade, ≥ 99% (Assay, Metals basis) Barium perchlorate Barium diperchlorate Perchloric acid barium salt Barium perchlorat BARIUM PERCHLORATE BARIUM PERCHLORATE STANDARD bariumdiperchlorate Perchloricacid,bariumsalt Barium perchlorat, 99%, anhydrous, extra pure Bishyperchloric acid barium salt Dihyperchloric acid barium salt Baroim Perchlorate Anhydrous BARIUM PERCHLORATE, 99.999% BARIUM PERCHLORAT 0,005 MOL/L IN 2-PROPA NOL/WATER BARIUM PERCHLORATE ANHYDROUS BARIUM PERCHLORATE ANHYDROUS 99% BariumPerchlorateGr(Anhydrous) BariumPerchlorateExtraPure BARIUM PERCHLORATE SOLUTION 0,005 MOL/L 2-PROPANOL/WATER Barium perchlorat, anhydrous, extra pure, 99% barium perchlorate solution Barium perchlorate,99%,extra pure,anhydrous Barium perchlorate, anhydrous, extra pure, 99% BariuM perchlorate, anhydrous, extra pure, 99% 100GR BARIUM PERCHLORATE ANHYDROUS FOR ANALYSI BARIUM PERCHLORATE SOLUTION 1 L BARIUM PERCHLORATE, ANHYDROUSBARIUM PERCHLORATE, ANHYDROUSBARIUM PERCHLORATE, ANHYDROUSBARIUM PERCHLORATE, ANHYDROUS Barium perchlorate, GR 98% BARIUM PERCHLORATE 0.005 MOL/L (0.005M) AQUEOUS SOLUTION Barium perchlorate Standard Solution 13465-95-7 BaClO42 BaClO4 Oxidation Perchlorates Synthetic Reagents Barium SaltsSynthetic Reagents Metal and Ceramic Science Oxidation Perchlorates Salts Synthetic Reagents A - F Salt Solutions Volumetric Solutions Inorganics