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2-Methylresorcinol

CAS No.
608-25-3
Chemical Name:
2-Methylresorcinol
Synonyms
1,3-Benzenediol, 2-methyl-;2,6-DIHYDROXYTOLUENE;2-methyl-3-benzenediol;2-METHYL-1,3-BENZENEDIOL;1,3-Dihydroxy-2-methylbenzene;2-methyl-1,3-dihydroxybenzene;2-MR;Rodol MRP;2,6-Dihydr;JAROCOL 2MR
CBNumber:
CB5431461
Molecular Formula:
C7H8O2
Molecular Weight:
124.14
MDL Number:
MFCD00002271
MOL File:
608-25-3.mol
MSDS File:
SDS
Last updated:2024-03-22 17:12:53

2-Methylresorcinol Properties

Melting point 114-120 °C(lit.)
Boiling point 264 °C(lit.)
Density 1.1006 (rough estimate)
vapor pressure 0.017Pa at 20℃
refractive index 1.4922 (estimate)
Flash point 135°C
storage temp. Keep in dark place,Sealed in dry,Room Temperature
solubility 263g/l
pka pK1:10.05;pK2:11.64 (25°C,μ=0.65)
form Glassy Irregular Shaped Granules
color White
Water Solubility Soluble in water and methanol.
BRN 2042177
InChIKey ZTMADXFOCUXMJE-UHFFFAOYSA-N
LogP 1.58 at 25℃
CAS DataBase Reference 608-25-3(CAS DataBase Reference)
EWG's Food Scores 2-4
FDA UNII 32W7044A3T
NIST Chemistry Reference 1,3-Benzenediol, 2-methyl-(608-25-3)
EPA Substance Registry System 1,3-Benzenediol, 2-methyl- (608-25-3)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS05,GHS06,GHS09
Signal word  Danger
Hazard statements  H301-H317-H318-H400
Precautionary statements  P261-P273-P280-P301+P310-P302+P352-P305+P351+P338
Hazard Codes  T,C
Risk Statements  25-36/37/38-34-20/21/22
Safety Statements  26-36-45-37/39-28A-36/37/39-27
RIDADR  UN 2811 6.1/PG 3
WGK Germany  3
RTECS  VH2009500
TSCA  Yes
HazardClass  6.1
PackingGroup  III
HS Code  29072900
NFPA 704
0
3 0

2-Methylresorcinol price More Price(29)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 302589 2-Methylresorcinol 98% 608-25-3 25g $78.1 2024-03-01 Buy
Sigma-Aldrich 302589 2-Methylresorcinol 98% 608-25-3 100g $199 2024-03-01 Buy
TCI Chemical M0425 2-Methylresorcinol >98.0%(GC) 608-25-3 25g $107 2024-03-01 Buy
TCI Chemical M0425 2-Methylresorcinol >98.0%(GC) 608-25-3 100g $266 2024-03-01 Buy
Alfa Aesar A11821 2-Methylresorcinol, 98% 608-25-3 50g $39.1 2024-03-01 Buy
Product number Packaging Price Buy
302589 25g $78.1 Buy
302589 100g $199 Buy
M0425 25g $107 Buy
M0425 100g $266 Buy
A11821 50g $39.1 Buy

2-Methylresorcinol Chemical Properties,Uses,Production

Chemical Properties

White to off-white crystal powder

Uses

2-Methylresorcinol is used in the preparation of aromatic benziporphyrins, tripyrrane analogs and C-5-bromo-2-hydroxyphenylcalix[4]-2-methylresorcinarene. Further, it is employed in oxidative and non-oxidative hair dye formulations.

Application

2-Methylresorcinol is used as medicine, pesticide, dye intermediate, hair auxiliaries, etc.

Preparation

Synthesis of 2-methylresorcinol: The synthetic routes to an alkylresorcinol that is partially alkylated at a position other than the 4th position on the aromatic ring are multistep and give low overall yields. For example, a 50% yield of a 2-methylresorcinol is obtained by hydrogenation of resorcinol and methylation of the resulting dihydroresorcinol to 2-methylcyclohexane-1,3-dione which on treatment with bromine is converted into 4,6-dibromo-2-methylresorcinol and finally hydrogenolysis of the dibromo derivative to produce the 2-methylresorcinol. Another example is that 5-methylresorcinol can be prepared by a five-step synthesis starting with p-toluidine or a four-step synthesis starting from ethyl crotonate. The five-step synthesis involves acetylation, two-step nitration, reductive hydrogenation, and hydrolysis.
Literature source US04086281

General Description

The reaction between 2-methylresorcinol and 2-alkenals was studied to investigate the scavenging ability of m-diphenols for the 2-alkenals formed during lipid oxidation.

Flammability and Explosibility

Non flammable

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View Lastest Price from 2-Methylresorcinol manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Methylresorcinol pictures 2024-04-19 2-Methylresorcinol
608-25-3
US $0.00 / Kg/Drum 1KG 99% 200MT Jinan Finer Chemical Co., Ltd
2-Methylresorcinol pictures 2024-04-12 2-Methylresorcinol
608-25-3
US $30.00 / kg 1kg 98% 2000kg hebei hongtan Biotechnology Co., Ltd
2-methyl-3-benzenediol pictures 2024-03-15 2-methyl-3-benzenediol
608-25-3
US $44.00-32.00 / kg 500kg 99.9 200tons Shandong Juchuang Chemical Co., LTD
2-Methylresorcinol,1,3-Dihydroxy-2-methylbenzene 2-Methylresorcinol technical grade, 90% 2,6-Dihydroxytoluene, 2-Methyresorcinol 2,6-Dihydroxy-1-methylbenzene 2,6-Dihydroxytoluene for synthesis 2-Methylresorcin 2-methyl-resorcino 2-MR 2-METHYLRESORCINOL 3-Benzenediol,2-methyl-1 Resorcinol, 2-methyl- Toluene-2,6-diol LABOTEST-BB LT00053049 JAROCOL 2MR gamma-orcinol Methylresorcinoltech 2,6-dihydrobluene 2-METHYLRESORCINOL, TECH., 90% Rodol MRP 2-Methylresocinol 2-Methylresorcinol99% 2-Methylresorcinol, tech., 90+% 2,6-Dihydroxy 2-METHYLRESORCINOL,TECHNICAL 2-METHYL-RESORCINOL:2-METHYL -1,3-DIHYDROXYBENZENE 2,6-DIHYDROXYTOLUENE(2-METHYLRESORCINOL) 2-METHYL-N-RESORCINOL 2-Methylresoricinol 2,6-DIHYDROXYTOLUENE pure 2,6-Toluenediol 2-Methylresorcinol,98% 2-Methylresorcinol,90%,tech. 2,6-Dihydr 2-Methylresorcinol> 2-Methylresorcinol(2MR) Atomoxetine Impurity 4 Resorcinol Impurity 2 2-Methylresorcinol ISO 9001:2015 REACH 2-Methylresorcinol pure, 98% 1,3-Dihydroxy-2-methylbenzene 2-methyl-1,3-dihydroxybenzene 2-METHYL-1,3-BENZENEDIOL 2,6-DIHYDROXYTOLUENE 1,3-Benzenediol, 2-methyl- 2-methyl-3-benzenediol 608-25-3 680-25-3 Building Blocks Organic Building Blocks Polyols Oxygen Compounds Dye Intermediate Aromatic Hydrocarbons (substituted) & Derivatives Benzene derivates Organic Chemicals Intermediates of Dyes and Pigments fine chemicals Building Blocks