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ChemicalBook >> CAS DataBase List >>2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL

2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL

2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL Structure
2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL structure
CAS No.
564483-19-8
Chemical Name:
2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL
Synonyms
tBuXPhos;t-Bu XPhos;t-butyl-Xphos;tBuXPhos 97%;2‘98% tBuXPhos;di-t-Bu-XPhos;2-Di-tert-butyL;TERT-BUTYL X-PHOS;2-Di-t-butylphosphino-2',4',6'
CBNumber:
CB5451245
Molecular Formula:
C29H45P
Molecular Weight:
424.64
MDL Number:
MFCD06411306
MOL File:
564483-19-8.mol
MSDS File:
SDS
Last updated:2024-01-05 16:34:11
Request For Quotation

2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL Properties

Melting point 148-151 °C(lit.)
Boiling point 493.5±45.0 °C(Predicted)
solubility soluble in Toluene
form Crystalline Powder
color White
InChIKey SACNIGZYDTUHKB-UHFFFAOYSA-N

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P280-P305+P351+P338-P304+P340-P405-P501A
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36/37/39
WGK Germany  3
TSCA  No
HS Code  29310099
NFPA 704
0
2 0

2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL price More Price(41)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 901904 tBuXPhos 95% 564483-19-8 1G $61.4 2024-03-01 Buy
Sigma-Aldrich 638080 tBuXPhos 97% 564483-19-8 1g $57.4 2024-03-01 Buy
Sigma-Aldrich 901904 tBuXPhos 95% 564483-19-8 5G $142.8 2024-03-01 Buy
Sigma-Aldrich 638080 tBuXPhos 97% 564483-19-8 5g $184 2024-03-01 Buy
Sigma-Aldrich 901904 tBuXPhos 95% 564483-19-8 25G $420 2024-03-01 Buy
Product number Packaging Price Buy
901904 1G $61.4 Buy
638080 1g $57.4 Buy
901904 5G $142.8 Buy
638080 5g $184 Buy
901904 25G $420 Buy

2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL Chemical Properties,Uses,Production

Uses

tBuXPhos [2-Di-tert-butylphosphino-2′,4′,6′-triisopropylbiphenyl] is an air-stable, electron-rich biaryl phosphine ligand developed by the Buchwald group to enhance the reactivity of palladium catalysis during cross-coupling reactions. tBuXPhos has been used in the preparation of [tBuXPhosAu(MeCN)]BAr4F, a gold catalyst for the intermolecular [2+2] cycloaddition of terminal arylalkynes with substituted alkenes to form functionalized cyclobutenes with high regioselectivity.
tBuXPhos is a ligand for Pd-catalyzed C-O and C-N bond formation.
It can be used in the following reactions:
• Palladium-catalyzed Tsuji-Trost substitution and cross-coupling of benzylic fluorides.
• Palladium-catalyzed C-N cross-coupling of sulfinamides and aryl halides.
• Palladium-catalyzed rapid methoxylation and deuteriomethoxylation of bromo-chalcones.

Reactions

  • Effective ligand for the Pd-catalyzed arylation of pyrazoles, indazoles and amino heterocycles.
  • Ligand used in the Pd-catalyzed synthesis of phenols from aryl halides and KOH.
  • Ligand used in the Pd-catalyzed of benzoic acids from aryl halides and CO2.
  • Ligand used in the Pd-catalyzed trifluoromethylation of vinyl sulfonates.
  • Ligand used in the Pd-catalyzed arylation of nitroacetates.
  • Ligand used in the Pd-catalyzed Suzuki−Miyaura cross-coupling of allylboronates and aryl halides.
  • Ligand used in the Pd-catalyzed cyanation of (hetero)arylchlorides and bromides.
  • Ligand used in the Pd-catalyzed C–N cross coupling of sulfinamides and aryl halides.
  • Ligand used in the Pd-catalyzed arylation of cyanamides. 
Reactions of 564483-19-8_1 Reactions of 564483-19-8_2  

Chemical Properties

White to pale yellow

Uses

suzuki reaction

Uses

tBuXPhos is a ligand for Pd-catalyzed C-O and C-N bond formation.
It can be used in the following reactions:

  • Palladium-catalyzed Tsuji-Trost substitution and cross-coupling of benzylic fluorides.
  • Palladium-catalyzed C-N cross-coupling of sulfinamides and aryl halides.
  • Palladium-catalyzed rapid methoxylation and deuteriomethoxylation of bromo-chalcones.

Uses

Effective ligand for the Pd-catalyzed arylation of pyrazoles, indazoles and amino heterocycles

General Description

tBuXPhos [2-Di-tert-butylphosphino-2′,4′,6′-triisopropylbiphenyl] is an air-stable, electron-rich biaryl phosphine ligand developed by the Buchwald group to enhance the reactivity of palladium catalysis during cross-coupling reactions.

2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL synthesis

13716-10-4
694-80-4
21524-34-5
564483-19-8
Synthesis of 2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL from Di-tert-butylchlorophosphane and 2-Bromochlorobenzene and 1-BROMO-2,4,6-TRIISOPROPYLBENZENE

2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL Preparation Products And Raw materials

Raw materials

2-Bromopropane 2-Chloro-2-methylpropane Carbon tetrachloride Aluminum chloride Phosphorus trichloride
1,2-Dibromoethane Tetrahydrofuran 1,2-Dibromobenzene Benzene Ethyl acetate
Copper(I) chloride Government regulation Dichloromethane Iron Magnesium

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Preparation Products

1-Butanone, 1-(4-fluorophenyl)-4-[(6bS,10aR)-2,3,6b,9,10,10a-hexahydro-3-methyl-1H-pyrido[3',4':4,5]pyrrolo[1,2,3-de]quinoxalin-8(7H)-yl]- tBuXPhos-Pd-G3

2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL Suppliers

Global( 295)Suppliers
Supplier Tel Email Country ProdList Advantage
Puyang Huicheng Electronic Materials Co., Ltd.
+86-0393-+86-0393-8910800 +8615839383373 info@huichengchem.com China 516 58
XINXIANG RUNYU MATERIAL CO., LTD.
+86-13592593621; +8613592593621 sales@runvmat.com China 407 58
Speranza Chemical Co., Ltd. 		+86-86-075521030354 +8618688942810 sophieliu@speranzachem.com China 723 55
Shanghai UCHEM Inc. 		+862156762820 +86-13564624040 sales@myuchem.com China 6710 58
Capot Chemical Co.,Ltd. 		571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Shanghai Daken Advanced Materials Co.,Ltd 		+86-371-66670886 info@dakenam.com China 15928 58
Henan Tianfu Chemical Co.,Ltd. 		+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21691 55
Shanghai Time Chemicals CO., Ltd. 		+86-021-57951555 +8617317452075 jack.li@time-chemicals.com China 1807 55
Hangzhou FandaChem Co.,Ltd. 		008657128800458; +8615858145714 fandachem@gmail.com China 9348 55
Nanjing ChemLin Chemical Industry Co., Ltd. 		025-83697070 product@chemlin.com.cn CHINA 3012 60
Supplier Advantage
Puyang Huicheng Electronic Materials Co., Ltd.
58
XINXIANG RUNYU MATERIAL CO., LTD.
58
Speranza Chemical Co., Ltd. 		55
Shanghai UCHEM Inc. 		58
Capot Chemical Co.,Ltd. 		60
Shanghai Daken Advanced Materials Co.,Ltd 		58
Henan Tianfu Chemical Co.,Ltd. 		55
Shanghai Time Chemicals CO., Ltd. 		55
Hangzhou FandaChem Co.,Ltd. 		55
Nanjing ChemLin Chemical Industry Co., Ltd. 		60

View Lastest Price from 2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Di-tert-butylphosphino-2',4',6'-triisopropylbiphenyl pictures 2024-04-26 2-Di-tert-butylphosphino-2',4',6'-triisopropylbiphenyl
564483-19-8
 US $12.00 / kg 1kg 99% 200mt Jinan Finer Chemical Co., Ltd
2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL pictures 2024-04-26 2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL
564483-19-8
 US $0.00-0.00 / KG 25KG 98% 25KG Speranza Chemical Co., Ltd.
2-Di-tert-butylphosphino-2',4',6'-triisopropylbiphenyl pictures 2024-02-23 2-Di-tert-butylphosphino-2',4',6'-triisopropylbiphenyl
564483-19-8
 US $11.20-184.00 / g 1g 0.98 20kg Shanghai UCHEM Inc.

2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL Spectrum

2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL(564483-19-8)1HNMR2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL(564483-19-8)31PNMR2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL(564483-19-8)FT-IR

564483-19-8(2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL)Related Search:

2-DICYCLOHEXYLPHOSPHINO-2',6'-DIISOPROPOXYBIPHENYL 2-(Dicyclohexylphosphino)-2'-methylbiphenyl 2-Dicyclohexylphosphino-2',6'-dimethoxybiphenyl 2-(Dicyclohexylphosphino)biphenyl 2'-(dicyclohexylphosphino)-6-methoxy-N,N-dimethylbiphenyl-2-amine
2-Dicyclohexylphosphino-2'-(N,N-dimethylamino)biphenyl 2-(Dicyclohexylphosphino)-2'-methoxybiphenyl 2-(Dicyclohexylphosphino)-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl, min. 98% BrettPhos X-PHOS 2-Dicyclohexylphosphino-2',6'-bis(diMethylaMino)-1,1'-biphenyl, Min. 98% Cphos
Tri-tert-butylphosphine tetrafluoroborate 2-(Di-tert-butylphosphino)biphenyl 2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL 2-(DI-T-BUTYLPHOSPHINO)-2'-METHYLBIPHENYL DI-TERT-BUTYLPHENYLPHOSPHINE
2-DI-TERT-BUTYLPHOSPHINO-3,4,5,6-TETRAM&

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2-DI-T-BUTYLPHOSPHINO-2',4',6'-TRI-I-PROPYL-1,1'-BIPHENYL 2-Di-tert-butylphosphino-2',4',6'-trisopropylbinphenyl phosphine, bis(1,1-diMethylethyl)[2',4',6'-tris(1-Methylethyl)[1,1'-biphenyl]-2-yl]- Bis(1,1-dimethylethyl)[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine 2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL TERT-BUTYL X-PHOS 2-DI-TERT-BUTYLPHOSPHINO-2',4', 6'-TRI-I-PROPYL-1,1'-BIPHENYL 2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl,min.98% 2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl,min.98%t-butylXPhos 2-Di-tert-butylphosphino-2',4',6'-triisopropylbiphenyl ,98% 2-Di-tert-butylphosphino-2′,4′,6′-triisopropylbiphenyl,tert-Butyl XPhos 2-DI-T-BUTYLPHOSPHINO-2'',4'',6''-TRI-I-PROPYL-1,1''-BIPHENYL, MIN. 98% 2-di-tert-butylphosphino-2',4',6'-triisopropylbiph 98% tBuXPhos Di-tert-butyl(2',4',6'-triisopropyl-[1,1'-biphenyl]-2-yl)phosphine di-t-Bu-XPhos Di-tert-butyl(2',4',6'-triisopropylbiphenyl-2-yl)phosphine 2-Di-t-butylphosphiNA-2',4',6'-tri-i-propyl-1,1'-biphenyl 2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl, t-butylXPhos 2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl, Min. 98% t-Bu-X-PHOS 2-Di-t-butylphosphino-2',4',6' 2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl,98% tBuXPhos 2&lsquo -DI-Tert-Butylphosphino-2,4,6-Triisopropylbiphenyl 2-Di-tert-butyL phosphino-2',4',6'-triisopropyL phosphine, bis(1,1-diMethylethyl)[2',4',6'-tris(1-Methylethyl)[1,1'-biphenyl] phosphine, bis(1,1-diMethylethyl)[2',4',6'-tris(1-Methylethyl)[1,1'-biphen 2-(Di-t-butylphosphino)-2',4',6'-tri- i-propyl-1,1'-biphenyl (tBu-Xphos) Di-tert-butyl(2',4',6'-triisopropyl-[1,1'-biphenyl]-2-yl)phosphine 98% tBuXPhos / 2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl 2-Di-t-butylphosphino-2',4',6'-tri-isopropyl-1,1'-biphenyl 2-Di-t-butylphosphino-2',4',6'-tri-i-propylbiphenyl 2-Di-tert-butyphosphino-2',4',6'-trisopropyl-1,1'-biphenyl phosphine, bis(1,1-dimethylethyl)[2',4',6'-tris(1-methylethy... 564483-19-8 2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL tBuXPhos 97% t-Bu XPhos tBuXPhos t-butyl-Xphos di-tert-butyl(2',4',6'-triisopropyl-[1,1'-biphenyl]-2-yl)phosphane 2-Di-t-butylphosphino-2’,4’,6’-triisopropyl-1,1’-biphenyl (tBuXPhos) 2-DI-TERT-BUTYLPHOSPHINO-2',4',6'-TRIISOPROPYLBIPHENYL Di-tert-butyl(2',4',6'-triisopropyl-[1,1'-biphenyl]-2-yl)phosphine Bis(1,1-dimethylethyl)[2',4',6'-tris(1-methylethyl)[1,1'-biphenyl]-2-yl]phosphine 2-Di-t-butylphosphino-2',4',6'-tri-i-propyl-1,1'-biphenyl di-tert-butyl(2',4',6'-triisopropyl-[1,1'-biphenyl]-2-yl)phosphane 564483-19-8 C29H45P Achiral Phosphine Aryl Phosphine Buchwald Ligands Series Buchwald Ligands&Precatalysts