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2-Methyl anthraquinone

CAS No.
84-54-8
Chemical Name:
2-Methyl anthraquinone
Synonyms
2-METHYLANTHRAQUINONE;TECTOQUINONE;2-Methyl-9,10-anthraquinone;Tectochinon;2-methylanthracene-9,10-dione;2-METHYL AQ;Techtoquinone;CH3C6H3COC6H4CO;Methylanthraquinone;9,10-Antracenedione
CBNumber:
CB5472864
Molecular Formula:
C15H10O2
Molecular Weight:
222.24
MDL Number:
MFCD00001235
MOL File:
84-54-8.mol
MSDS File:
SDS
Last updated:2024-04-09 16:57:55

2-Methyl anthraquinone Properties

Melting point 170-173 °C (lit.)
Boiling point 236-238 °C/10 mmHg (lit.)
Density 1.1404 (rough estimate)
vapor pressure 0Pa at 25℃
refractive index 1.6600 (estimate)
Flash point 209 °C
storage temp. 2-8°C
solubility Soluble in Chloroform,Dichloromethane,Ethyl Acetate,DMSO,Acetone,etc.
form powder to crystal
color Light orange to Yellow to Green
Water Solubility Soluble in water 1.234 mg/L @ 25°C.
Merck 14,6021
BRN 2050523
InChIKey NJWGQARXZDRHCD-UHFFFAOYSA-N
LogP 3.4 at 25℃
CAS DataBase Reference 84-54-8(CAS DataBase Reference)
FDA UNII Q9P233HWAJ
NIST Chemistry Reference 9,10-Anthracenedione, 2-methyl-(84-54-8)
EPA Substance Registry System 2-Methylanthraquinone (84-54-8)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P280-P302+P352-P305+P351+P338
Hazard Codes  Xi,N
Risk Statements  51/53
Safety Statements  22-24/25-61
RIDADR  UN 3077 9/PG 3
WGK Germany  3
Hazard Note  Irritant
TSCA  Yes
HS Code  29146990
NFPA 704
0
0 0

2-Methyl anthraquinone price More Price(31)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 65800 2-Methylanthraquinone technical, ≥95% (HPLC) 84-54-8 100g $68.1 2024-03-01 Buy
Sigma-Aldrich 65800 2-Methylanthraquinone technical, ≥95% (HPLC) 84-54-8 500g $260 2024-03-01 Buy
TCI Chemical M0156 2-Methylanthraquinone >99.0%(GC) 84-54-8 25g $42 2024-03-01 Buy
TCI Chemical M0156 2-Methylanthraquinone >99.0%(GC) 84-54-8 500g $427 2022-04-27 Buy
Alfa Aesar A14502 2-Methylanthraquinone, 97% 84-54-8 50g $28.65 2024-03-01 Buy
Product number Packaging Price Buy
65800 100g $68.1 Buy
65800 500g $260 Buy
M0156 25g $42 Buy
M0156 500g $427 Buy
A14502 50g $28.65 Buy

2-Methyl anthraquinone Chemical Properties,Uses,Production

Chemical Properties

YELLOW TO GREEN-YELLOW FINE POWDER

Uses

2-Methylanthraquinone is used as a pharmaceutical intermediate. It is used in smog dyes.
2-Methylanthraquinone may be used in the preparation of potential bioreducible anthraquinone derivatives.

Definition

ChEBI: 2-methylanthraquinone is an anthraquinone that is 9,10-anthraquinone in which the hydrogen at position 2 is substituted by a methyl group. It derives from a 9,10-anthraquinone.

Reactions

The compound is produced by the reaction of phthalic anhydride and toluene. It can be chlorinated to give 1-chloro-2-methylanthraquinone. Nitration gives 1-nitro-2-methylanthraquinone, which can be reduced to 1-amino-2-methyl derivative. Oxidation of the methyl group gives anthraquinone-2-carboxylic acid.

Synthesis Reference(s)

Organic Syntheses, Coll. Vol. 1, p. 353, 1941
Tetrahedron Letters, 24, p. 5499, 1983 DOI: 10.1016/S0040-4039(00)94122-4

Synthesis Reference(s)

Canadian Journal of Chemistry, 44, p. 2881, 1966 DOI: 10.1139/v66-428

Flammability and Explosibility

Not classified

Purification Methods

Crystallise the quinone from EtOH, then sublime it. It has max at 257, 275 and 330nm (EtOH). [Hersbery & Fieser J Am Chem Soc 63 2562 1941, Beilstein 7 H 809, 7 III 4104, 7 IV 2574.]

83790-93-6
107-15-3
936-49-2
84-54-8
Synthesis of 2-Methyl anthraquinone from 9,10-Anthracenedione, 2-(2-phenylethynyl)- and Ethylenediamine
Global( 334)Suppliers
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Kindchem(Nanjing)Co.,Ltd
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QINGDAO HONG JIN CHEMCIAL CO.,LTD.
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Shenzhen Nexconn Pharmatechs Ltd
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View Lastest Price from 2-Methyl anthraquinone manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2-Methyl anthraquinone pictures 2024-04-17 2-Methyl anthraquinone
84-54-8
US $0.00 / Kg/Drum 1KG 99% 500mt/year Jinan Finer Chemical Co., Ltd
2-Methyl anthraquinone pictures 2024-02-22 2-Methyl anthraquinone
84-54-8
US $1.00 / g 1g 99% 10tons/month Hubei Langyou International Trading Co., Ltd
2-Methyl anthraquinone pictures 2024-01-02 2-Methyl anthraquinone
84-54-8
US $0.00 / Kg 1Kg 98% 20 Kindchem(Nanjing)Co.,Ltd
9,10-Anthracenedione,2-methyl- 9,10-Antracenedione, 2-methyl- Anthraquinone, 2-methyl- anthraquinone,2-methyl- beta-Methylanthraquinone -Methylanthranpuinone Techtoquinone 2-METHYL AQ 2-Methyl-9,10-anthracenedione LABOTEST-BB LT00159669 Methylanthraquinone METHYLANTHRAQUINONE, 2- 2-Methylanthraquinone (Beta-) b-Methylanthraquinone Thiophene-3-carbonyl thiophene-3-carboperoxoate 2-Methylanthraquinone,94% CH3C6H3COC6H4CO 2-Methylanthraquinone, 94% 100GR 2-Methylanthraquinone,97% 2-methyl-10-anthracenedione 2-methyl-9,10(9H,10H)-anthracenedione 2-Methylanthra-9,10-quinone 2-Methylanthracenedione 2-Methylanthrapuinone 2-Methyl anthraquino 2-Methylanthraquinone technical, >=95% (HPLC) 2-Methylanthraquinone> RECH 2-Methyl anthraquinone 2-Mehtyl anthraquinone 9,10-Antracenedione 2-Methylanthracene-9,10(4aH,9aH)-dione TIANFU-CHEM_2-Methyl anthraquinone,84-54-8 Dicarbomethoxyzinc dihydrate 2-METHYL-ANTHRACHINON Tectochinon 2-METHYLANTHRAQUINONE TECTOQUINONE 2-Methyl-9,10-anthraquinone 2-methylanthracene-9,10-dione 4'-ethyl-2,3-difluoro-4-(4-propylcyclohexyl)-1,1'-biphenyl 84-54-8 85-54-8 C6H4CO2C6H4CH3 Anthraquinones Chloroanthraquine, etc. Building Blocks Carbonyl Compounds C15 to C38 Ketones Organic Building Blocks Anthraquinones, Hydroquinones and Quinones Anthraquinones Chloroanthraquine, etc. C15 to C38 Carbonyl Compounds Ketones Intermediates of Dyes and Pigments commercial