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(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE

CAS No.
138517-66-5
Chemical Name:
(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE
Synonyms
(S,S)-11,12-Diamino-9,10-dihydro-9,10-ethanoanthracene;(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE;(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine>9,10-Ethanoanthracene-11,12-diamine, 9,10-dihydro-, (11S,12S)-;(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine >=95.0% (HPLC);(11S,12S)-11,12-diamino-9,10-dihydro-9,10-ethanoanthracene (R)-mandelate monoammonium salt
CBNumber:
CB5500732
Molecular Formula:
C16H16N2
Molecular Weight:
236.31
MDL Number:
MFCD09038520
MOL File:
138517-66-5.mol
MSDS File:
SDS
Last updated:2023-06-08 17:06:38

(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE Properties

Melting point 158 °C
Boiling point 396.7±42.0 °C(Predicted)
Density 1.195±0.06 g/cm3(Predicted)
refractive index 20 ° (C=1, MeOH)
storage temp. under inert gas (nitrogen or Argon) at 2–8 °C
form powder to crystal
pka 9.38±0.40(Predicted)
color White to Orange to Green
BRN 8693351

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P264-P280-P302+P352+P332+P313+P362+P364-P305+P351+P338+P337+P313-P261-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26
WGK Germany  3
HS Code  2921.51.5000
NFPA 704
0
2 0

(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE price More Price(16)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
TCI Chemical D3445 (11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine >98.0%(HPLC)(T) 138517-66-5 1g $538 2024-03-01 Buy
TCI Chemical D3445 (11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine >98.0%(HPLC)(T) 138517-66-5 100mg $103 2024-03-01 Buy
TRC D450518 (11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine 138517-66-5 2mg $60 2021-12-16 Buy
TRC D450518 (11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine 138517-66-5 10mg $75 2021-12-16 Buy
Biosynth Carbosynth FD59982 (11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine 138517-66-5 50mg $65 2021-12-16 Buy
Product number Packaging Price Buy
D3445 1g $538 Buy
D3445 100mg $103 Buy
D450518 2mg $60 Buy
D450518 10mg $75 Buy
FD59982 50mg $65 Buy

(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE Chemical Properties,Uses,Production

Uses

(11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine is a chiral diamine, which can be used as a reactant:

  • To synthesize pyridine based C2-symmetrical chiral organocatalysts via palladium catalyzed coupling reaction with 2-bromo-4-(alkylamino)pyridine.
  • To prepare porous organic imine cages by cycloimination reaction with triformylbenzene.
  • To synthesize Ga/Yb-Schiff base complex, which is utilized as a catalyst for the asymmetric synthesis of 5-amino-2-(hydroxyalkyl)oxazoles by enantioselective α-addition of α-isocyano amides to aldehydes.

(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE Preparation Products And Raw materials

Raw materials

Preparation Products

(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE Suppliers

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(11S,12S)-9,10-DIHYDRO-9,10-ETHANOANTHRACENE-11,12-DIAMINE (S,S)-11,12-Diamino-9,10-dihydro-9,10-ethanoanthracene (11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine >=95.0% (HPLC) (11S,12S)-11,12-diamino-9,10-dihydro-9,10-ethanoanthracene (R)-mandelate monoammonium salt (11S,12S)-9,10-Dihydro-9,10-ethanoanthracene-11,12-diamine> 9,10-Ethanoanthracene-11,12-diamine, 9,10-dihydro-, (11S,12S)- 138517-66-5 Asymmetric Synthesis Synthetic Organic Chemistry