ChemicalBook >> CAS DataBase List >>1,3-Diphenylguanidine

1,3-Diphenylguanidine

CAS No.
102-06-7
Chemical Name:
1,3-Diphenylguanidine
Synonyms
DPG;Dynamine;DIPHENYLGUANIDINE;DFG;Accelerator D;N,N'-DIPHENYLGUANIDINE;Denax;1133293;denaxdpg;Vulkazit
CBNumber:
CB5671991
Molecular Formula:
C13H13N3
Molecular Weight:
211.26
MDL Number:
MFCD00001758
MOL File:
102-06-7.mol
MSDS File:
SDS
Last updated:2023-10-24 17:36:38

1,3-Diphenylguanidine Properties

Melting point 146-148 °C(lit.)
Boiling point 170°C
Density 1,13 g/cm3
vapor pressure 0Pa at 25℃
refractive index 1.6000 (estimate)
Flash point 170°C
storage temp. Sealed in dry,Store in freezer, under -20°C
solubility Soluble in alcohol, chloroform, hot benzene, hot toluene, and dilute mineral acids
pka pK1:10.12 (25°C)
form Powder
color Pale Cream
Odor wh. powd., bitter taste, sl. odor
PH 10.2 (10g/l, H2O)
Water Solubility slightly soluble
Merck 14,3324
BRN 1875653
Stability Stable. Combustible. Incompatible with strong oxidizing agents. Moisture sensitive.
InChIKey OWRCNXZUPFZXOS-UHFFFAOYSA-N
LogP 2.42 at 21.1℃
CAS DataBase Reference 102-06-7(CAS DataBase Reference)
Indirect Additives used in Food Contact Substances 1,3-DIPHENYLGUANIDINE
FDA 21 CFR 177.2600
EWG's Food Scores 3
FDA UNII 6MRZ85RNHQ
NIST Chemistry Reference Guanidine, n,n'-diphenyl-(102-06-7)
EPA Substance Registry System 1,3-Diphenylguanidine (102-06-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS06,GHS08,GHS09
Signal word  Danger
Hazard statements  H301-H315-H319-H335-H361f-H411
Precautionary statements  P202-P261-P273-P301+P310-P302+P352-P305+P351+P338
Hazard Codes  Xn,N,T
Risk Statements  22-36/37/38-51/53-62-25
Safety Statements  26-36/37/39-61-45
RIDADR  UN 3077 9/PG 3
WGK Germany  2
RTECS  MF0875000
TSCA  Yes
HazardClass  9
PackingGroup  III
HS Code  29252000
Toxicity LD50 oral in rabbit: 250mg/kg
NFPA 704
0
2 0

1,3-Diphenylguanidine price More Price(29)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich D207756 1,3-Diphenylguanidine 97% 102-06-7 500g $66.6 2024-03-01 Buy
Sigma-Aldrich 43029 1,3-Diphenylguanidine analytical standard (for titrimetry) 102-06-7 50g $404 2024-03-01 Buy
TCI Chemical D0723 1,3-Diphenylguanidine >98.0%(HPLC)(T) 102-06-7 25g $21 2024-03-01 Buy
TCI Chemical D0723 1,3-Diphenylguanidine >98.0%(HPLC)(T) 102-06-7 500g $40 2024-03-01 Buy
Alfa Aesar 031395 1,3-Diphenylguanidine, primary standard, 99+% 102-06-7 50g $73.3 2024-03-01 Buy
Product number Packaging Price Buy
D207756 500g $66.6 Buy
43029 50g $404 Buy
D0723 25g $21 Buy
D0723 500g $40 Buy
031395 50g $73.3 Buy

1,3-Diphenylguanidine Chemical Properties,Uses,Production

Chemical Properties

1,3-diphenylguanidine is a white or cream powder with a slight odour and bitter taste. slightly soluble in water, soluble in ethanol, chloroform, hot benzene, hot toluene, easily soluble in dilute inorganic acids. Used as medium speed accelerator for natural rubber and synthetic rubber, mainly used in the manufacture of tires, rubber plates, rubber shoes and other rubber industrial products.

Uses

N,N'-Diphenylguanidine is a primary standard for acids; aeeelerator for the vulcanization of rubber for use with thiazoles and sulfenamides; complexing agent in the deteetion of metals and organie bases.

Uses

1,3-Diphenylguanidine is used as pharmaceutical intermediate.

Definition

ChEBI: 1,3-diphenylguanidine is guanidine carrying a phenyl substituent on each of the two amino groups. It is used as an accelerator in the rubber industry. It has a role as an allergen.

General Description

White to cream-colored chalky powder. Bitter taste and slight odor.

Air & Water Reactions

Sensitive to moisture. Aqueous solutions are strongly alkaline. Insoluble in water.

Reactivity Profile

1,3-Diphenylguanidine behaves as an amine. Amines are chemical bases. They neutralize acids to form salts plus water. These acid-base reactions are exothermic. The amount of heat that is evolved per mole of amine in a neutralization is largely independent of the strength of the amine as a base. Amines may be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen is generated by amines in combination with strong reducing agents, such as hydrides. 1,3-Diphenylguanidine is incompatible with strong oxidizers.

Fire Hazard

1,3-Diphenylguanidine is combustible.

Flammability and Explosibility

Non flammable

Contact allergens

Diphenylguanidine is a rubber sensitizer that can induce immediate-type reactions and delayed-type contact allergy. It was formerly contained in “carba mix.” Occupational exposure concerns finished rubber items and the rubber manufacturing industry. The most frequent occupational categories are metal industry, homemakers, health services and laboratories, and the building industry.

Safety Profile

Poison by ingestion and intraperitoneal routes. Experimental teratogenic and reproductive effects. Mutation data reported. When heated to decomposition it emits toxic fumes of NOx,.

Purification Methods

1,3-Diphenylguanidine [102-06-7] M 211.3, m 148o, 10.12. Crystallise it from toluene,

102-08-9
102-06-7
Synthesis of 1,3-Diphenylguanidine from 1,3-Diphenyl-2-thiourea
Global( 436)Suppliers
Supplier Tel Email Country ProdList Advantage
Hebei Mojin Biotechnology Co., Ltd
+8613288715578 sales@hbmojin.com China 12456 58
Hebei Yanxi Chemical Co., Ltd.
+8617531190177 peter@yan-xi.com China 5993 58
Dalian Richfortune Chemicals Co., Ltd
0411-84820922 8613904096939 sales@richfortunechem.com China 303 57
Henan Tianfu Chemical Co.,Ltd.
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Hangzhou FandaChem Co.,Ltd.
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Chemson Industrial (Shanghai) Co., Ltd.
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career henan chemical co
+86-0371-86658258 sales@coreychem.com China 29914 58
NINGBO INNO PHARMCHEM CO., LTD.
13867897135 sales@nbinno.com CHINA 925 58
Jinan Finer Chemical Co., Ltd
+86-531-88989536 +86-15508631887 sales@finerchem.com China 2967 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8823 58

View Lastest Price from 1,3-Diphenylguanidine manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1,3-Diphenylguanidine pictures 2023-10-24 1,3-Diphenylguanidine
102-06-7
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
1,3-Diphenylguanidine pictures 2023-10-21 1,3-Diphenylguanidine
102-06-7
US $40.00-40.00 / kg 1kg 0.99 10 tons Hebei Yanxi Chemical Co., Ltd.
1,3-Diphenylguanidine pictures 2023-09-13 1,3-Diphenylguanidine
102-06-7
US $100.00 / bag 1bag 99 5000 Hebei Fengqiang Trading Co., LTD
NCI-C60924 AcceleratorD Akrochem DPG Denax denaxdpg DPG accelerator dpgaccelerator Dwufenyloguanidyna Guanidine, 1,3-diphenyl- N,N’-diphenyl-Guandine n,n’-diphenyl-guanidin MELANILINE 1,3-DIPHENYLGUANIDINE 1133293 Rubber accelerator D (DPG) (E)-1,2-diphenylguanidine Rubber vulcanization accelerator DPG-80 Diphenyl guanidin 1,3-Diphenylguanidine N,N'-Diphenylguanidine sym-Diphenylguanidine Melaniline DPG N,N'-DIPHENYLGUANIDINE (SYM.), STANDARD TITRIM. SUBSTANCE DiphenylGuanidine(Dpg) ACCELERACTOR D (DIPHENYL GUANIDINE) DIPHENYLGUANIDINE PRIMARY STANDARD vulcafordpg Vulcaid DPG Vulcogene ND Vulkacit D Vulkacit D/C vulkacitd vulkacitd/c Vulkacite D vulkacited Vulkazit DIPHENYLGUANIDINE REAGENT 1,3-Diphenylguanidine, Accelerator DPG(D) Guanidine, N,N-diphenyl- 1,3-diphenylguanidine, primary standard ACCELERATORD(DIPHENYLGUANIDINE) 1,3-DIPHENYLGUANIDINE, PRIMARY STANDARD, 99+% Aminodianilinemethane 1,2-Di(phenyl)guanidine Accerator D 1,3-Diphenylguanidine,97% SYM-DIPHENYLGUANIDINE VANAX DPG (vulcanization) accelrator D TIMTEC-BB SBB000514 Nocceler D noccelerd Perkacit DPG Phenaldine Sanceler D s-Diphenylguanidine Soxinol D USAF B-19 USAF ek-1270 usafb-19 usafek-1270