ChemicalBook >> CAS DataBase List >>4-Hydroxyphenylboronic acid
4-Hydroxyphenylboronic acid
- CAS No.
- 71597-85-8
- Chemical Name:
- 4-Hydroxyphenylboronic acid
- Synonyms
- ACF2;AKOS BRN-0188;4-BORONOPHENOL;RARECHEM AH PB 0222;4-Hydroxybenzeneboronic;4-DIHYDROXYBORANYL-PHENOL;4-Hydroxyphenylboronicaci;4-HYDROXYPHENYLBORONIC ACID;4-HYDROXYBENZENEBORONIC ACID;(P-HYDROXYPHENYL)BORONIC ACID
- CBNumber:
- CB5691083
- Molecular Formula:
- C6H7BO3
- Molecular Weight:
- 137.93
- MOL File:
- 71597-85-8.mol
| Melting point | >230 °C (lit.) |
|---|---|
| Boiling point | 351.4±44.0 °C(Predicted) |
| Density | 1.32±0.1 g/cm3(Predicted) |
| storage temp. | Inert atmosphere,Room Temperature |
| form | Powder |
| pka | 9.09±0.10(Predicted) |
| color | Off-white to light brown |
| Water Solubility | 25 g/L |
| BRN | 2963491 |
| InChIKey | COIQUVGFTILYGA-UHFFFAOYSA-N |
| CAS DataBase Reference | 71597-85-8(CAS DataBase Reference) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|---|---|
| Signal word | Warning |
| Hazard statements | H315-H319-H335 |
| Precautionary statements | P261-P280a-P304+P340-P405-P501a-P305+P351+P338 |
| Hazard Codes | Xi,C |
| Risk Statements | 36/37/38-34 |
| Safety Statements | 26-36-37/39-45-36/37/39-27 |
| WGK Germany | 3 |
| Hazard Note | Irritant |
| TSCA | No |
| HS Code | 2931 90 00 |
| HazardClass | IRRITANT |
4-Hydroxyphenylboronic acid price More Price(40)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 8.43854 | 4-Hydroxyphenylboronic acid ≥97% (acidimetric) | 71597-85-8 | 1g | $70.3 | 2022-05-15 | Buy |
| Sigma-Aldrich | 8.43854 | 4-Hydroxyphenylboronic acid ≥97% (acidimetric) | 71597-85-8 | 5G | $252 | 2022-05-15 | Buy |
| Sigma-Aldrich | 523976 | 4-Hydroxyphenylboronic acid ≥95.0% | 71597-85-8 | 1g | $54.4 | 2022-05-15 | Buy |
| Sigma-Aldrich | 523976 | 4-Hydroxyphenylboronic acid ≥95.0% | 71597-85-8 | 5g | $134 | 2022-05-15 | Buy |
| TCI Chemical | H1228 | 4-Hydroxyphenylboronic Acid (contains varying amounts of Anhydride) | 71597-85-8 | 1g | $42 | 2022-04-27 | Buy |
4-Hydroxyphenylboronic acid Chemical Properties,Uses,Production
Chemical Properties
off-white to light brown powder
Uses
4-Hydroxybenzeneboronic acid is used for Suzuki-Miyaura coupling and Stille coupling and potential for introducing different alkyl groups, palladium-catalyzed aminocarbonylation and cross-coupling reactions, bio-supported palladium nanoparticles as phosphine-free catalyst for Suzuki reaction in water and Cu2O-catalyzed aerobic oxidative cross-coupling of tetrazoles. It is also used in preparation of rod-like dendronized polymers.
Uses
suzuki reaction
Uses
4-Hydroxyphenylboronic acid can be used as a reactant in:
It can also be used to prepare/promote:
- Suzuki-Miyaura coupling and Stille coupling reactions.
- Palladium-catalyzed aminocarbonylation and cross-coupling reactions.
- Suzuki reaction for preparation of bio-supported palladium nanoparticles as phosphine-free catalysts.
- Cu2O-catalyzed aerobic oxidative cross-coupling of tetrazoles.
It can also be used to prepare/promote:
- PDK1 inhibitory activity (cancer cell growth, survival, and tumorigenesis inhibitor).
- Rod-like dendronized polymers containing G4 and G5 ester dendrons via macromonomer approach by living ROMP.
- Estrone-derived cyclopamine analogs as Sonic Hedgehog signaling inhibitors for anti-cancer chemotherapeutics.
- Enzymatic inhibitors for the treatment of Gram-negative bacterial infections.
- Oligoarenes by Suzuki-Miyaura palladium-catalyzed cross-coupling.
Synthesis Reference(s)
Tetrahedron Letters, 37, p. 6705, 1996 DOI: 10.1016/S0040-4039(96)01468-2
4-Hydroxyphenylboronic acid Preparation Products And Raw materials
Raw materials
Tetrahydrofuran
4-Bromophenol
Triisopropyl borate
n-Butyllithium
Boronic acid, B-[4-[[(4-methylphenyl)sulfonyl]oxy]phenyl]-
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Global( 384)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Henan DaKen Chemical CO.,LTD. | +86-371-66670886 | info@dakenchem.com | China | 16666 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | 0371-55170693 | info@tianfuchem.com | China | 22021 | 55 |
| Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3013 | 60 |
| ATK CHEMICAL COMPANY LIMITED | 21-51619050 | ivan@atkchemical.com | China | 26815 | 60 |
| Beijing Green Guardee Technology Co., Ltd | 86-010-69706062 | sales2@greenguardee.com | CHINA | 650 | 58 |
| Zjartschem | +86-571-8723 8903 jocelynpan@zjarts.com | jocelynpan@zjarts.com | CHINA | 997 | 58 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29959 | 58 |
| Shanghai Arbor Chemical Co., Ltd. | 021-60451682 | act@arborchemical.com | CHINA | 906 | 58 |
| Jinan Finer Chemical Co., Ltd | 531-88989536 +8615508631887 | sales@finerchem.com | CHINA | 2824 | 58 |
| Accela ChemBio Inc. | (+1)-858-699-3322 | info@accelachem.com | United States | 19969 | 58 |
View Lastest Price from 4-Hydroxyphenylboronic acid manufacturers
| Image | Release date | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2022-02-18 | (4-hydroxyphenyl)boronic acid
71597-85-8
|
US $0.00 / KG | 1KG | 98.00% | 1000KG/month | Henan DaKen Chemical CO.,LTD. | |
 |
2021-11-02 | 4-Hydroxyphenylboronic acid
71597-85-8
|
US $750.00 / ASSAYS | 10g | 99% | 10tons | Baoji Guokang Healthchem co.,ltd | |
 |
2021-08-13 | 4-Hydroxybenzeneboronic acid
71597-85-8
|
US $10.00 / KG | 10g | 99 | 50 Ton/Tons per Month | Shijiazhuang tongyang Import and Export Co., LTD |
-
- (4-hydroxyphenyl)boronic acid
71597-85-8
- US $0.00 / KG
- 98.00%
- Henan DaKen Chemical CO.,LTD.
-
- 4-Hydroxyphenylboronic acid
71597-85-8
- US $750.00 / ASSAYS
- 99%
- Baoji Guokang Healthchem co.,ltd
-
- 4-Hydroxybenzeneboronic acid
71597-85-8
- US $10.00 / KG
- 99
- Shijiazhuang tongyang Import and Export Co., LTD
71597-85-8(4-Hydroxyphenylboronic acid)Related Search:
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2,4-Dimethoxybenzeneboronic acid
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4-(N-OCTYLOXY)BENZENEBORONIC ACID
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RARECHEM AH PB 0222
(P-HYDROXYPHENYL)BORONIC ACID
BORONIC ACID, (4-HYDROXYPHENYL)-
4-Boronophenol~4-Hydroxyphenylboronic acid
4-Hydroxybenzeneboronic
4-BORONOPHENOL
4-HYDROXYPHENYLBORONIC ACID
4-HYDROXYBENZENEBORONIC ACID
AKOS BRN-0188
4-DIHYDROXYBORANYL-PHENOL
4-Hydroxyphenylboronic Acid (contains varying amounts of Anhydride)
4-Hydroxyphenylboronic acid,97%
4-Hydroxyphenylboronic acid ,98%
4-Hydroxyphenylboronic acid, 97% 1GR
4-Hydroxyphenylboronic acid, 97% 5GR
Boronic acid, B-(4-hydroxyphenyl)-
BORONIC ACID, B-(4-HYDROXYPHENYL)-;
4-Hydroxyphenylboronic acid (contains Anhydride)
p-hydroxy-benzeneboronic acid
4-Hydroxyphenylboronic acid >=95.0%
4-Hydroxybenzeneboronic acid 97%
4-Hydroxyphenylboronicaci
ACF2
71597-85-8
71579-85-8
C5H7BO2
C6H7BO3
C6H7O3B
BORONIC ACID
Boronic Acids and Derivatives
Boronic Acids
Aryl
Organometallic Reagents
OLED materials,pharm chemical,electronic
Boronate Ester
Potassium Trifluoroborate
Boronic Acids
Boronic Acid
Boronic Acids
Boronic Acids and Derivatives
Organic acids
B (Classes of Boron Compounds)
Alcohols and Derivatives
Boron, Nitrile, Thio,& TM-Cpds
Aryl
Organoborons
blocks
BoronicAcids