ChemicalBook >> CAS DataBase List >>4-Hydroxyphenylboronic acid
4-Hydroxyphenylboronic acid
- CAS No.
- 71597-85-8
- Chemical Name:
- 4-Hydroxyphenylboronic acid
- Synonyms
- ACF2;AKOS BRN-0188;4-BORONOPHENOL;RARECHEM AH PB 0222;4-Hydroxybenzeneboronic;4-DIHYDROXYBORANYL-PHENOL;4-Hydroxyphenylboronicaci;4-HYDROXYPHENYLBORONIC ACID;4-HYDROXYBENZENEBORONIC ACID;(P-HYDROXYPHENYL)BORONIC ACID
- CBNumber:
- CB5691083
- Molecular Formula:
- C6H7BO3
- Molecular Weight:
- 137.93
- MDL Number:
- MFCD01074628
- MOL File:
- 71597-85-8.mol
- MSDS File:
- SDS
Last updated:2025-01-27 09:38:02
| Melting point | >230 °C (lit.) |
|---|---|
| Boiling point | 351.4±44.0 °C(Predicted) |
| Density | 1.32±0.1 g/cm3(Predicted) |
| storage temp. | Inert atmosphere,Room Temperature |
| solubility | soluble in Acetonitrile, DMSO, Methanol |
| form | Powder |
| pka | 9.09±0.10(Predicted) |
| color | Off-white to light brown |
| Water Solubility | 25 g/L |
| BRN | 2963491 |
| InChIKey | COIQUVGFTILYGA-UHFFFAOYSA-N |
| CAS DataBase Reference | 71597-85-8(CAS DataBase Reference) |
| UNSPSC Code | 12352301 |
| NACRES | NA.22 |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319 | |||||||||
| Precautionary statements | P264-P280-P302+P352-P305+P351+P338-P332+P313-P337+P313 | |||||||||
| Hazard Codes | Xi,C | |||||||||
| Risk Statements | 36/37/38-34 | |||||||||
| Safety Statements | 26-36-37/39-45-36/37/39-27 | |||||||||
| WGK Germany | 3 | |||||||||
| TSCA | No | |||||||||
| HS Code | 2931 90 00 | |||||||||
| HazardClass | IRRITANT | |||||||||
| NFPA 704 |
|
4-Hydroxyphenylboronic acid price More Price(40)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 8.43854 | 4-Hydroxyphenylboronic acid ≥97% (acidimetric) | 71597-85-8 | 1g | $80.1 | 2024-03-01 | Buy |
| Sigma-Aldrich | 8.43854 | 4-Hydroxyphenylboronic acid ≥97% (acidimetric) | 71597-85-8 | 5G | $287 | 2024-03-01 | Buy |
| Sigma-Aldrich | 523976 | 4-Hydroxyphenylboronic acid ≥95.0% | 71597-85-8 | 1g | $62.2 | 2024-03-01 | Buy |
| Sigma-Aldrich | 523976 | 4-Hydroxyphenylboronic acid ≥95.0% | 71597-85-8 | 5g | $134 | 2024-03-01 | Buy |
| TCI Chemical | H1228 | 4-Hydroxyphenylboronic Acid (contains varying amounts of Anhydride) | 71597-85-8 | 1g | $44 | 2024-03-01 | Buy |
4-Hydroxyphenylboronic acid Chemical Properties,Uses,Production
Chemical Properties
off-white to light brown powder
Uses
4-Hydroxyphenylboronic acid can be used as a reactant in:
- Suzuki-Miyaura coupling and Stille coupling reactions.
- Palladium-catalyzed aminocarbonylation and cross-coupling reactions.
- Suzuki reaction for preparation of bio-supported palladium nanoparticles as phosphine-free catalysts.
- Cu2O-catalyzed aerobic oxidative cross-coupling of tetrazoles.
It can also be used to prepare/promote:
- PDK1 inhibitory activity (cancer cell growth, survival, and tumorigenesis inhibitor).
- Rod-like dendronized polymers containing G4 and G5 ester dendrons via macromonomer approach by living ROMP.
- Estrone-derived cyclopamine analogs as Sonic Hedgehog signaling inhibitors for anti-cancer chemotherapeutics.
- Enzymatic inhibitors for the treatment of Gram-negative bacterial infections.
- Oligoarenes by Suzuki-Miyaura palladium-catalyzed cross-coupling.
Uses
4-Hydroxybenzeneboronic acid is used for Suzuki-Miyaura coupling and Stille coupling and potential for introducing different alkyl groups, palladium-catalyzed aminocarbonylation and cross-coupling reactions, bio-supported palladium nanoparticles as phosphine-free catalyst for Suzuki reaction in water and Cu2O-catalyzed aerobic oxidative cross-coupling of tetrazoles. It is also used in preparation of rod-like dendronized polymers.
Synthesis Reference(s)
Tetrahedron Letters, 37, p. 6705, 1996 DOI: 10.1016/S0040-4039(96)01468-2
4-Hydroxyphenylboronic acid Preparation Products And Raw materials
Raw materials
Tetrahydrofuran
4-Bromophenol
Triisopropyl borate
n-Butyllithium
Boronic acid, B-[4-[[(4-methylphenyl)sulfonyl]oxy]phenyl]-
1of3
Preparation Products
1of2
Global( 423)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Xinsheng New Material Technology Co., LTD. | +86-16632316109 | xinshengkeji@xsmaterial.com | China | 1085 | 58 |
| Anhui Ruihan Technology Co., Ltd | +8617756083858 | daisy@anhuiruihan.com | China | 973 | 58 |
| Henan Fengda Chemical Co., Ltd | +86-371-86557731 +86-13613820652 | info@fdachem.com | China | 20262 | 58 |
| Capot Chemical Co.,Ltd. | +86-（0）57185586718 +86-13336195806 | sales@capot.com | China | 29792 | 60 |
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 18949 | 58 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21632 | 55 |
| Nanjing ChemLin Chemical Industry Co., Ltd. | 025-83697070 | product@chemlin.com.cn | CHINA | 3009 | 60 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32965 | 60 |
| Beijing Green Guardee Technology Co., Ltd | 86-010-69706062 | sales2@greenguardee.com | CHINA | 650 | 58 |
| Zjartschem | +86-571 87238903 | jocelynpan@zjarts.com | CHINA | 988 | 58 |
View Lastest Price from 4-Hydroxyphenylboronic acid manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2025-02-13 | (4-hydroxyphenyl)boronic acid
71597-85-8
|
US $0.00 / KG | 1KG | 98.00% | 1000KG/month | Shanghai Daken Advanced Materials Co.,Ltd | |
 |
2024-04-08 | 4-Hydroxyphenylboronic acid
71597-85-8
|
US $34.00-1.20 / kg | 1kg | 99% | g-kg-tons, free sample is available | Henan Fengda Chemical Co., Ltd | |
 |
2023-11-30 | 4-Hydroxyphenylboronic acid
71597-85-8
|
US $0.00-0.00 / kg | 1kg | 99.9% | 30000 Kg | Hebei Xinsheng New Material Technology Co., LTD. |
-
- (4-hydroxyphenyl)boronic acid
71597-85-8
- US $0.00 / KG
- 98.00%
- Shanghai Daken Advanced Materials Co.,Ltd
-
- 4-Hydroxyphenylboronic acid
71597-85-8
- US $34.00-1.20 / kg
- 99%
- Henan Fengda Chemical Co., Ltd
-
- 4-Hydroxyphenylboronic acid
71597-85-8
- US $0.00-0.00 / kg
- 99.9%
- Hebei Xinsheng New Material Technology Co., LTD.
71597-85-8(4-Hydroxyphenylboronic acid)Related Search:
RARECHEM AH PB 0222
(P-HYDROXYPHENYL)BORONIC ACID
BORONIC ACID, (4-HYDROXYPHENYL)-
4-Boronophenol~4-Hydroxyphenylboronic acid
4-Hydroxybenzeneboronic
4-BORONOPHENOL
4-HYDROXYPHENYLBORONIC ACID
4-HYDROXYBENZENEBORONIC ACID
AKOS BRN-0188
4-DIHYDROXYBORANYL-PHENOL
4-Hydroxyphenylboronic Acid (contains varying amounts of Anhydride)
4-Hydroxyphenylboronic acid,97%
4-Hydroxyphenylboronic acid ,98%
4-Hydroxyphenylboronic acid, 97% 1GR
4-Hydroxyphenylboronic acid, 97% 5GR
Boronic acid, B-(4-hydroxyphenyl)-
BORONIC ACID, B-(4-HYDROXYPHENYL)-;
4-Hydroxyphenylboronic acid (contains Anhydride)
p-hydroxy-benzeneboronic acid
4-Hydroxyphenylboronic acid >=95.0%
4-Hydroxybenzeneboronic acid 97%
4-Hydroxyphenylboronicaci
ACF2
B-(4-Hydroxyphenyl)boronic acid
71597-85-8
71579-85-8
C5H7BO2
C6H7BO3
C6H7O3B
BORONIC ACID
Boronic Acids and Derivatives
Boronic Acids
Aryl
Organometallic Reagents
OLED materials,pharm chemical,electronic
Boronate Ester
Potassium Trifluoroborate
Boronic Acids
Boronic Acid
Boronic Acids
Boronic Acids and Derivatives
Organic acids
B (Classes of Boron Compounds)
Alcohols and Derivatives
Boron, Nitrile, Thio,& TM-Cpds
Aryl
Organoborons
blocks
BoronicAcids
bc0001