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3,4-Dichloroaniline

3,4-Dichloroaniline
3,4-Dichloroaniline structure
CAS No.
95-76-1
Chemical Name:
3,4-Dichloroaniline
Synonyms
3,4-dca;3.4-Dichloroan;AKOS BBS-00003672;3,4-Dichloranilin;3,4-Dichloroanihne;3,4-Dichloraniline;m,p-dichloroaniline;3,4-DICHLOROANILINE;3,4-Dichloroanaline;3,4-dichloro-anilin
CBNumber:
CB5696598
Molecular Formula:
C6H5Cl2N
Formula Weight:
162.02
MOL File:
95-76-1.mol

3,4-Dichloroaniline Properties

Melting point:
69-71 °C(lit.)
Boiling point:
272 °C(lit.)
Density 
1,34 g/cm3
refractive index 
1.6140 (estimate)
Flash point:
166 °C
storage temp. 
0-6°C
solubility 
0.73g/l
form 
Crystalline Mass and/or Chunks
color 
Beige to brown
PH
7.1 (0.8g/l, H2O)
Water Solubility 
0.06 g/100 mL
Merck 
14,3054
BRN 
636837
Stability:
Stable, but darkens in storage. Combustible. Incompatible with strong oxidizing agents, acids, acid chlorides, acid anhydrides.
CAS DataBase Reference
95-76-1(CAS DataBase Reference)
NIST Chemistry Reference
Benzenamine, 3,4-dichloro-(95-76-1)
EPA Substance Registry System
Benzenamine, 3,4-dichloro-(95-76-1)
SAFETY
  • Risk and Safety Statements
  • Hazard and Precautionary Statements (GHS)
  • NFPA
Hazard Codes  T,N
Risk Statements  23/24/25-41-43-50/53-51/53-33
Safety Statements  26-36/37/39-45-60-61-36/37-28
RIDADR  UN 3442 6.1/PG 2
WGK Germany  3
RTECS  BX2625000
8
TSCA  Yes
HazardClass  6.1
PackingGroup  II
HS Code  29214210
Hazardous Substances Data 95-76-1(Hazardous Substances Data)
Symbol(GHS):
Signal word: Danger
Hazard statements:
Code Hazard statements Hazard class Category Signal word Pictogram P-Codes
H301 Toxic if swalloed Acute toxicity,oral Category 3 Danger P264, P270, P301+P310, P321, P330,P405, P501
H302 Harmful if swallowed Acute toxicity,oral Category 4 Warning P264, P270, P301+P312, P330, P501
H310 Fatal in contact with skin Acute toxicity,dermal Category 1, 2 Danger P262, P264, P270, P280, P302+P350,P310, P322, P361, P363, P405, P501
H311 Toxic in contact with skin Acute toxicity,dermal Category 3 Danger P280, P302+P352, P312, P322, P361,P363, P405, P501
H315 Causes skin irritation Skin corrosion/irritation Category 2 Warning P264, P280, P302+P352, P321,P332+P313, P362
H317 May cause an allergic skin reaction Sensitisation, Skin Category 1 Warning P261, P272, P280, P302+P352,P333+P313, P321, P363, P501
H318 Causes serious eye damage Serious eye damage/eye irritation Category 1 Danger P280, P305+P351+P338, P310
H330 Fatal if inhaled Acute toxicity,inhalation Category 1, 2 Danger P260, P271, P284, P304+P340, P310,P320, P403+P233, P405, P501
H331 Toxic if inhaled Acute toxicity,inhalation Category 3 Danger P261, P271, P304+P340, P311, P321,P403+P233, P405, P501
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled Sensitisation, respiratory Category 1 Danger P261, P285, P304+P341, P342+P311,P501
H371 May cause damage to organs Specific target organ toxicity, single exposure Category 2 Warning P260, P264, P270, P309+P311, P405,P501
H372 Causes damage to organs through prolonged or repeated exposure Specific target organ toxicity, repeated exposure Category 1 Danger P260, P264, P270, P314, P501
H400 Very toxic to aquatic life Hazardous to the aquatic environment, acute hazard Category 1 Warning P273, P391, P501
H410 Very toxic to aquatic life with long lasting effects Hazardous to the aquatic environment, long-term hazard Category 1 Warning P273, P391, P501
Precautionary statements:
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P261 Avoid breathing dust/fume/gas/mist/vapours/spray.
P264 Wash hands thoroughly after handling.
P264 Wash skin thouroughly after handling.
P270 Do not eat, drink or smoke when using this product.
P271 Use only outdoors or in a well-ventilated area.
P273 Avoid release to the environment.
P280 Wear protective gloves/protective clothing/eye protection/face protection.
P284 Wear respiratory protection.
P311 Call a POISON CENTER or doctor/physician.
P320 Specific treatment is urgent (see … on this label).
P330 Rinse mouth.
P391 Collect spillage. Hazardous to the aquatic environment
P301+P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician.
P304+P340 IF INHALED: Remove victim to fresh air and Keep at rest in a position comfortable for breathing.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continuerinsing.
P405 Store locked up.
P403+P233 Store in a well-ventilated place. Keep container tightly closed.
P501 Dispose of contents/container to..…

NFPA 704

Diamond Hazard Value Description
1
0
Health  
Flammability   1 Materials that require considerable preheating, under all ambient temperature conditions, before ignition and combustion can occur. Includes some finely divided suspended solids that do not require heating before ignition can occur. Flash point at or above 93.3 °C (200 °F). (e.g. mineral oil, ammonia)
Instability   0 Normally stable, even under fire exposure conditions, and is not reactive with water (e.g. helium,N2)
Special  

(NFPA, 2010)

3,4-Dichloroaniline price More Price(8)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 437778 3,4-Dichloroaniline 98% 95-76-1 5g $20.8 2018-11-13 Buy
Sigma-Aldrich 437778 3,4-Dichloroaniline 98% 95-76-1 250g $40.8 2018-11-13 Buy
TCI Chemical D0324 3,4-Dichloroaniline >98.0%(GC) 95-76-1 25g $27 2018-11-22 Buy
TCI Chemical D0324 3,4-Dichloroaniline >98.0%(GC) 95-76-1 500g $133 2018-11-22 Buy
Alfa Aesar A15199 3,4-Dichloroaniline, 98% 95-76-1 250g $36.9 2018-11-13 Buy

3,4-Dichloroaniline Chemical Properties,Uses,Production

Chemical Properties

brown solid

Uses

3,4-Dichloroaniline is used in the preparation of the herbicide propanil (P760840).

Definition

ChEBI: A dichloroaniline having the two chloro-substituents at the 3- and 4-positions.

General Description

Light tan to dark gray crystals or brown solid. Melting point 71-72°C.

Air & Water Reactions

Sensitive to prolonged exposure to heat, light and air. Darkens in storage. Insoluble in water.

Reactivity Profile

3,4-Dichloroaniline is incompatible with oxidizing agetns, acids, acid chlorides and acid anhydrides. 3,4-Dichloroaniline can decompose at low pH. Hydrochloric acid accelerates decomposition. Reacts at temperatures above 356°F in the presence of ferric chloride .

Fire Hazard

3,4-Dichloroaniline is combustible.

Metabolic pathway

The basidiomycete Filoboletus sp. TA9054 metabolizes 3,4-dichloroaniline and forms several condensation products on solid media and in liquid culture, and no oligomers are produced. Six metabolites are identified as 3,3'-4,4'- tetrachloroazobenzene, 4-(3,4-dichloroanilino)-3,3',4' - trichloroazobenzene, 4-[(3,4-dichloroanilino)-4-(3,4- dichloroanilino)]-3,3'4'-trichloroazobenzene, 2-(3,4- dichloroanilino)-N-(3,4-dichlorophenyl)-4- (chlorophenylene), 6-(3,4-dichloroanilino)-N-(3,4- dichlorophenyl)-4-(chlorophenylene), and 3,5-bis(3,4- dichloroanilino)-1,4-chlorobenzoquinone.

Purification Methods

Crystallise the aniline from MeOH. [Beilstein 12 IV 1257.]

3,4-Dichloroaniline Preparation Products And Raw materials

Raw materials

Preparation Products


3,4-Dichloroaniline Suppliers

Global( 271)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Henan DaKen Chemical CO.,LTD.
+86-371-55531817
info@dakenchem.com CHINA 21968 58
Henan Tianfu Chemical Co.,Ltd.
0371-55170693
0371-55170693 info@tianfuchem.com CHINA 20680 55
Mainchem Co., Ltd.
+86-0592-6210733
+86-0592-6210733 sales@mainchem.com CHINA 32457 55
Xiamen AmoyChem Co., Ltd
+86 (0)592-605 1114
sales@amoychem.com CHINA 6374 58
Chemwill Asia Co.,Ltd.
86-21-51086038
86-21-51861608 chemwill_asia@126.com;sales@chemwill.com;chemwill@hotmail.com;chemwill@gmail.com CHINA 24001 58
Hubei Jusheng Technology Co.,Ltd.
86-188-71490254
peter@hubeijusheng.com CHINA 20095 58
career henan chemical co
+86-371-86658258
sales@coreychem.com CHINA 19923 58
Shanghai Billion Chemical Chemical Co. Ltd. 021-58771921 13818686088(wechat)
QQ: 3440059551 958130795(qq group) info@chemofchina.com China 2961 58
J & K SCIENTIFIC LTD. 400-666-7788 +86-10-82848833
+86-10-82849933 jkinfo@jkchemical.com;market6@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. +86-(0)21-61259100(Shanghai) +86-(0)755-86170099(ShenZhen) +86-(0)10-62670440(Beijing)
+86-(0)21-61259102(Shanghai) +86-(0)755-86170066(ShenZhen) +86-(0)10-88580358(Beijing) sh@meryer.com China 40277 62

View Lastest Price from 3,4-Dichloroaniline manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2018-12-15 3,4-Dichloroaniline
95-76-1
US $1.00 / kg 1kg 99% Customized career henan chemical co

3,4-Dichloroaniline Spectrum


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