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3,4-Dichloroaniline

3,4-Dichloroaniline structure

CAS No.: 95-76-1

Chemical Name:: 3,4-Dichloroaniline

Synonyms: 3,4-dca;Gefitinib-1;3.4-Dichloroan;3,4-Dichloroanil;3,4-Dichloranilin;AKOS BBS-00003672;3,4-Dichloraniline;3，4-Dichloroanihne;3,4-DICHLOROANILINE;3,4-dichloro-anilin

CBNumber:: CB5696598

Molecular Formula:: C6H5Cl2N

Molecular Weight:: 162.02

MDL Number:: MFCD00007768

MOL File:: 95-76-1.mol

MSDS File:: SDS

Last updated:2024-03-19 15:37:50

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3,4-Dichloroaniline Properties

Melting point	69-71 °C(lit.)
Boiling point	272 °C(lit.)
Density	1,34 g/cm³
vapor pressure	97.5Pa at 78℃
refractive index	1.6140 (estimate)
Flash point	166 °C
storage temp.	0-6°C
solubility	0.73g/l
pka	2.90±0.10(Predicted)
form	Crystalline Mass and/or Chunks
color	Beige to brown
PH	7.1 (0.8g/l, H2O)
Water Solubility	0.06 g/100 mL
Merck	14,3054
BRN	636837
Stability	Stable, but darkens in storage. Combustible. Incompatible with strong oxidizing agents, acids, acid chlorides, acid anhydrides.
LogP	2.68 at 20℃
CAS DataBase Reference	95-76-1(CAS DataBase Reference)
EWG's Food Scores	3-4
FDA UNII	20KR9WJ4NS
NIST Chemistry Reference	Benzenamine, 3,4-dichloro-(95-76-1)
EPA Substance Registry System	3,4-Dichloroaniline (95-76-1)

SAFETY

Risk and Safety Statements

Symbol(GHS)

GHS05,GHS06,GHS09

Signal word

Danger

Hazard statements

H301+H311+H331-H317-H318-H410

Precautionary statements

P273-P280-P301+P310-P302+P352+P312-P304+P340+P311-P305+P351+P338

Hazard Codes

T,N

Risk Statements

23/24/25-41-43-50/53-51/53-33

Safety Statements

26-36/37/39-45-60-61-36/37-28

RIDADR

UN 3442 6.1/PG 2

WGK Germany

RTECS

BX2625000

TSCA

Yes

HazardClass

6.1

PackingGroup

HS Code

29214210

NFPA 704

	1
3		0

3,4-Dichloroaniline price More Price(29)

Manufacturer	Product number	Product description	CAS number	Packaging	Price	Updated	Buy
Sigma-Aldrich	437778	3,4-Dichloroaniline 98%	95-76-1	5g	$36.4	2024-03-01	Buy
Sigma-Aldrich	437778	3,4-Dichloroaniline 98%	95-76-1	250g	$95.3	2024-03-01	Buy
TCI Chemical	D0324	3,4-Dichloroaniline >98.0%(GC)	95-76-1	25g	$30	2024-03-01	Buy
TCI Chemical	D0324	3,4-Dichloroaniline >98.0%(GC)	95-76-1	500g	$149	2024-03-01	Buy
Alfa Aesar	A15199	3,4-Dichloroaniline, 98%	95-76-1	50g	$26.65	2024-03-01	Buy

Product number	Packaging	Price	Buy
437778	5g	$36.4	Buy
437778	250g	$95.3	Buy
D0324	25g	$30	Buy
D0324	500g	$149	Buy
A15199	50g	$26.65	Buy

3,4-Dichloroaniline Chemical Properties,Uses,Production

Description

3,4-Dichloroaniline, 1-amino3,4- dichlorobenzene, is a gray to dark-brown crystalline solid at room temperature. It is used as an intermediate for pesticides and dyes and is produced by catalytic hydrogenation of 3,4-dichloronitrobenzene with noble metal catalysts under pressure. Various types of additives prevent dehalogenation during production and reactors must be fabricated with special steel alloys to inhibit corrosion.

Description

3,4-Dichloroaniline, 1-amino- 3,4- dichlorobenzene, is a gray to dark-brown crystalline solid at room temperature. It is used as an intermediate for pesticides and dyes and is produced by catalytic hydrogenation of 3,4-dichloronitrobenzene with noble metal catalysts under pressure. Various types of additives prevent dehalogenation during production and reactors must be fabricated with special steel alloys to inhibit corrosion .

Chemical Properties

brown solid
3,4-Dichloroaniline

Uses

3,4-Dichloroaniline is used as an intermediate for pesticides and dyes.

Uses

3,4-Dichloroaniline is used in the preparation of the herbicide propanil (P760840).

Uses

3,4-Dichloroaniline may be employed as derivatization reagent for the HPLC analysis of perfluorooctanoic acid (PFOA).

Definition

ChEBI: A dichloroaniline having the two chloro-substituents at the 3- and 4-positions.

Preparation

3,4-Dichloroaniline is produced by catalytic hydrogenation of 3,4-dichloronitrobenzene with noble metal catalysts under pressure. Various types of additives prevent dehalogenation during production and reactors must be fabricated with special steel alloys to inhibit corrosion.

General Description

Light tan to dark gray crystals or brown solid. Melting point 71-72°C.

Air & Water Reactions

Sensitive to prolonged exposure to heat, light and air. Darkens in storage. Insoluble in water.

Reactivity Profile

3,4-Dichloroaniline is incompatible with oxidizing agetns, acids, acid chlorides and acid anhydrides. 3,4-Dichloroaniline can decompose at low pH. Hydrochloric acid accelerates decomposition. Reacts at temperatures above 356°F in the presence of ferric chloride .

Fire Hazard

3,4-Dichloroaniline is combustible.

Metabolic pathway

The basidiomycete Filoboletus sp. TA9054 metabolizes 3,4-dichloroaniline and forms several condensation products on solid media and in liquid culture, and no oligomers are produced. Six metabolites are identified as 3,3'-4,4'- tetrachloroazobenzene, 4-(3,4-dichloroanilino)-3,3',4' - trichloroazobenzene, 4-[(3,4-dichloroanilino)-4-(3,4- dichloroanilino)]-3,3'4'-trichloroazobenzene, 2-(3,4- dichloroanilino)-N-(3,4-dichlorophenyl)-4- (chlorophenylene), 6-(3,4-dichloroanilino)-N-(3,4- dichlorophenyl)-4-(chlorophenylene), and 3,5-bis(3,4- dichloroanilino)-1,4-chlorobenzoquinone.

Purification Methods

Crystallise the aniline from MeOH. [Beilstein 12 IV 1257.]

3,4-Dichloroaniline synthesis

Synthesis of 3,4-Dichloroaniline from 3,4-Dichloronitrobenzene

3,4-Dichloroaniline Preparation Products And Raw materials

Raw materials

4-Chloronitrobenzene Chlorine Ferric chloride Hydrogen Industrial ethanol

3,4-Dichloronitrobenzene 1,2-Dichlorobenzene

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Preparation Products

Propanil 5-[(3,4-dichlorophenyl)azo]-1,2-dihydro-6-hydroxy-1,4-dimethyl-2-oxonicotinonitrile Diuron CHLORANOCRYL 3,4-DICHLORO-N-METHYLANILINE

SWEP 1-(3,4-Dichlorophenyl)piperazine Isocyanic acid 3,4-dichlorophenyl ester 2-AMINO-5,6-DICHLOROBENZOIC ACID 1-(3,4-DICHLOROPHENYL)-3-METHYL UREA

3-(3,4-DICHLOROPHENYL)PROPIONIC ACID 6-AMINO-2H-1,4-BENZOXAZIN-3(4H)-ONE 1-(3,4-DICHLOROPHENYL)-2-THIOUREA 3,3',4,4'-TETRACHLOROAZOBENZENE 5,6-Dichloro-2-benzothiazolamine

5-[(3,4-dichlorophenyl)azo]-1,2-dihydro-6-hydroxy-1,4-dimethyl-2-oxonicotinonitrile C.I. Disperse Yellow 58

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3,4-Dichloroaniline Suppliers

Global( 435)Suppliers

Supplier	Tel	Email	Country	ProdList	Advantage
Hebei Mojin Biotechnology Co., Ltd	+8613288715578	sales@hbmojin.com	China	12453	58
Firsky International Trade (Wuhan) Co., Ltd	+8615387054039	admin@firsky-cn.com	China	436	58
Capot Chemical Co.,Ltd.	571-85586718 +8613336195806	sales@capotchem.com	China	29797	60
Henan Tianfu Chemical Co.,Ltd.	+86-0371-55170693 +86-19937530512	info@tianfuchem.com	China	21695	55
Hangzhou FandaChem Co.,Ltd.	008657128800458; +8615858145714	fandachem@gmail.com	China	9352	55
Hefei TNJ Chemical Industry Co.,Ltd.	+86-0551-65418679 +86-18949832763	info@tnjchem.com	China	2989	55
career henan chemical co	+86-0371-86658258	sales@coreychem.com	China	29914	58
Hubei Jusheng Technology Co.,Ltd.	18871490254	linda@hubeijusheng.com	CHINA	28180	58
Hebei Guanlang Biotechnology Co., Ltd.	+86-19930503282	alice@crovellbio.com	China	8822	58
Xiamen AmoyChem Co., Ltd	+86-592-6051114 +8618959220845	sales@amoychem.com	China	6387	58

Supplier	Advantage
Hebei Mojin Biotechnology Co., Ltd	58
Firsky International Trade (Wuhan) Co., Ltd	58
Capot Chemical Co.,Ltd.	60
Henan Tianfu Chemical Co.,Ltd.	55
Hangzhou FandaChem Co.,Ltd.	55
Hefei TNJ Chemical Industry Co.,Ltd.	55
career henan chemical co	58
Hubei Jusheng Technology Co.,Ltd.	58
Hebei Guanlang Biotechnology Co., Ltd.	58
Xiamen AmoyChem Co., Ltd	58

View Lastest Price from 3,4-Dichloroaniline manufacturers

Update time	Product	Price	Min. Order	Purity	Supply Ability	Manufacturer
2023-10-08	3,4-Dichloroaniline 95-76-1	US $30.00 / KG	1KG	99%	20T	Firsky International Trade (Wuhan) Co., Ltd
2023-08-29	3,4-Dichloroaniline 95-76-1	US $0.00 / KG	1KG	99%	50000KG/month	Hebei Mojin Biotechnology Co., Ltd
2023-07-19	3,4-Dichloroaniline 95-76-1	US $30.00 / KG	1KG	99%	20 Tons	Wuhan wingroup Pharmaceutical Co., Ltd

3,4-Dichloroaniline
95-76-1
US $30.00 / KG
99%
Firsky International Trade (Wuhan) Co., Ltd

3,4-Dichloroaniline
95-76-1
US $0.00 / KG
99%
Hebei Mojin Biotechnology Co., Ltd

3,4-Dichloroaniline
95-76-1
US $30.00 / KG
99%
Wuhan wingroup Pharmaceutical Co., Ltd

3,4-Dichloroaniline Spectrum

3,4-Dichloroaniline(95-76-1)MS 3,4-Dichloroaniline(95-76-1)¹HNMR 3,4-Dichloroaniline(95-76-1)¹³CNMR 3,4-Dichloroaniline(95-76-1)IR1 3,4-Dichloroaniline(95-76-1)IR2 3,4-Dichloroaniline(95-76-1)IR3 3,4-Dichloroaniline(95-76-1)Raman

95-76-1(3,4-Dichloroaniline)Related Search:

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Gefitinib Impurity 11 Gefitinib Chloro Impurity 7-Methoxy-6-(3-morpholin-4-ylpropoxy)quinazolin-4(3H)-one 2-Amino-4-methoxy-5-(3-morpholinopropoxy)benzonitrile Gefitinib Impurity 8

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