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2,6-DIBROMONAPHTHALENE

CAS No.
13720-06-4
Chemical Name:
2,6-DIBROMONAPHTHALENE
Synonyms
DibroMonaphthalene;2,6-DibromonaphthaL;2,6-dibroMophthalene;2,6-Dibromonapthalene;2,6-DIBROMONAPHTHALENE;Naphthalene, 2,6-dibroMo-;2,6-Dibromonaphthalene>2,6-Dibromonaphthalene 99%;2,6-DIBROMONAPHTHALENE, 98.5%;2,6-Dibromonaphthalene in isooctane
CBNumber:
CB5697353
Molecular Formula:
C10H6Br2
Molecular Weight:
285.96
MDL Number:
MFCD01026462
MOL File:
13720-06-4.mol
MSDS File:
SDS
Last updated:2026-01-13 11:25:06
Product description Number Pack Size Price
2,6-Dibromonaphthalene 97% 762652 1g $120
2,6-Dibromonaphthalene >98.0%(GC) D4154 1g $41
2,6-Dibromonaphthalene D425935 1g $75
2,6-Dibromonaphthalene FD62407 1g $79
2,6-Dibromonaphthalene J92481 5g $102
More product size

2,6-DIBROMONAPHTHALENE Properties

Melting point 163-166°C
Boiling point 339.1±15.0 °C(Predicted)
Density 1.834±0.06 g/cm3(Predicted)
storage temp. Sealed in dry,Room Temperature
form powder to crystal
color White to Gray to Brown
Water Solubility Insoluble in water.
InChI InChI=1S/C10H6Br2/c11-9-3-1-7-5-10(12)4-2-8(7)6-9/h1-6H
InChIKey PJZDEYKZSZWFPX-UHFFFAOYSA-N
SMILES C1=C2C(C=C(Br)C=C2)=CC=C1Br
CAS DataBase Reference 13720-06-4(CAS DataBase Reference)
UNSPSC Code 12352100
NACRES NA.22

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictogramsGHS hazard pictograms
GHS05,GHS07,GHS09
Signal word  Danger
Hazard statements  H315-H318-H335-H411
Precautionary statements  P273-P280-P302+P352-P305+P351+P338+P310
target organs Respiratory system
Hazard Codes  Xi,N
Risk Statements  37/38-41-51/53
Safety Statements  22-24/25-61-39-26
RIDADR  UN 3077 9 / PGIII
WGK Germany  3
HS Code  29039990
Storage Class 11 - Combustible Solids
Hazard Classifications Aquatic Chronic 2
Eye Dam. 1
Skin Irrit. 2
STOT SE 3
NFPA 704
1
0 0

2,6-DIBROMONAPHTHALENE price More Price(28)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 762652 2,6-Dibromonaphthalene 97% 13720-06-4 1g $120 2026-04-30 Buy
TCI Chemical D4154 2,6-Dibromonaphthalene >98.0%(GC) 13720-06-4 1g $41 2026-04-30 Buy
TRC D425935 2,6-Dibromonaphthalene 13720-06-4 1g $75 2021-12-16 Buy
Biosynth Carbosynth FD62407 2,6-Dibromonaphthalene 13720-06-4 1g $79 2021-12-16 Buy
AK Scientific J92481 2,6-Dibromonaphthalene 13720-06-4 5g $102 2021-12-16 Buy
Product number Packaging Price Buy
762652 1g $120 Buy
D4154 1g $41 Buy
D425935 1g $75 Buy
FD62407 1g $79 Buy
J92481 5g $102 Buy

2,6-DIBROMONAPHTHALENE Chemical Properties,Uses,Production

Description

2,6-Dibromonaphthalene is an important material intermediate compound used as building blocks to construct small semiconductor molecules or polymers in organic photovoltaic, OLED and OFET devices.

Chemical Properties

Light yellow solid

Uses

2,6-Dibromonaphthalene is an important raw material and intermediate used in organic synthesis, pharmaceuticals and agrochemicals. It reacts with hexylmagnesium bromide to form 2,6-Dihexyl-naphthalene.

Synthesis

2,6-Dibromonaphthalene is synthesised using 6-Bromo-2-naphthol as a raw material by chemical reaction. The specific synthesis steps are as follows:
Bromine (78.8 g, 493 mmol) was added dropwise to a cooled (0 °C) solution of triphenylphosphine (129 g, 493 mmol) in anhydrous CH3CN (200 mL) and the solution was stirred for 30 min at rt. A solution of 6-bromo-2-naphthol (100 g, 448 mmol) in anhydrous acetonitrile (CH3CN) (200 mL) was added, and the reaction mixture was stirred for a further 2 h at 70 °C. After removal of the solvent (bath temp was increased to 140 °C), the residue was heated to 300 °C for 1 h. After being cooled to 100 °C, the black tar was dissolved in toluene (100 mL), and cooled to rt while stirring. The resulting solution was washed with 1 N NaOH and water, followed by drying over MgSO4. The solvent was removed in vacuo and the residue was dissolved in MeOH (50 mL). The precipitate was filtered and washed with MeOH (200 mL) and diisopropylether (iPr2O), successively, to give 2 (37.2 g, 29%) as a grey powder. The analytical sample was obtained by recrystallization from AcOEt (light brown plates). 1H NMR (CDCl3) δ: 7.51-7.62 (4H, m), 7.94 (2H, s). IR (KBr): 1568, 1481, 1175, 1134, 1065, 885, 853, 816 cm-1. Anal. Calcd for C10H6Br2: C, 42.00; H, 2.11. Found: C, 42.28; H, 2.18.
2,6-Dibromonaphthalene synthesis

References

[1] Bioorganic and Medicinal Chemistry, 2011, vol. 19, # 5, p. 1751 - 1770
[2] Synthesis, 1989, # 5, p. 356 - 359
[3] Patent: US6573289, 2003, B1

2,6-DIBROMONAPHTHALENE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 273)Suppliers
Supplier Tel Email Country ProdList Advantage
Suzhou Fenghua New Material Technology Co., Ltd.
+8615952428079 1968798092@qq.com China 176 58
Hebei Yanxi Chemical Co., Ltd.
+8618531123677 faithe@yan-xi.com China 5853 58
Hebei Chuanghai Biotechnology Co,.LTD
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Henan Fengda Chemical Co., Ltd
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Henan Tianfu Chemical Co.,Ltd.
+86-0371-55170693 +86-19937530512 info@tianfuchem.com China 21590 55
Nanjing ChemLin Chemical Industry Co., Ltd.
025-83697070 product@chemlin.com.cn CHINA 3009 60
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 33024 60

View Lastest Price from 2,6-DIBROMONAPHTHALENE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
2,6-DIBROMONAPHTHALENE pictures 2025-09-25 2,6-DIBROMONAPHTHALENE
13720-06-4
US $100.00-1.00 / KG 1KG 99% g-kg-tons, free sample is available Henan Fengda Chemical Co., Ltd
2,6-DIBROMONAPHTHALENE pictures 2025-06-27 2,6-DIBROMONAPHTHALENE
13720-06-4
US $30.00-10.00 / KG 50KG 99% 500000kg Hebei Chuanghai Biotechnology Co., Ltd
2,6-DIBROMONAPHTHALENE pictures 2025-06-20 2,6-DIBROMONAPHTHALENE
13720-06-4
US $20.00-1.00 / kg 1kg 0.99 10 tons Hebei Yanxi Chemical Co., Ltd.

2,6-DIBROMONAPHTHALENE Spectrum

2,6-DIBROMONAPHTHALENE 2,6-DIBROMONAPHTHALENE, 98.5% 2,6-Dibromonapthalene Naphthalene, 2,6-dibroMo- DibroMonaphthalene 2,6-dibroMophthalene 2,6-Dibromonaphthalene 99% 2,6-Dibromonaphthalene> 2,6-DibromonaphthaL 2,6-DIBROMONAPHTHALENE ISO 9001:2015 REACH 2,6-DIBROMONAPHTHALENE 13720-06-4 2,6-Dibromonaphthalene in isooctane 13720-06-4 Dibromonaphthalene