ChemicalBook >> CAS DataBase List >>POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE

POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE

CAS No.
166328-09-2
Chemical Name:
POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE
Synonyms
Potassium (3,5-bis(trifluoromethyl);POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENY&;[3,5-bis(trifluoromethyl)phenyl]-trifluoroboranuide;POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE;Potassium [3,5-bis(trifluoromethyl)pheny]trifluoroborate;potassium,[3,5-bis(trifluoromethyl)phenyl]-trifluoroboranui;Potassium[3,5-bis(trifluoromethyl)phenyl]trifluoroborate96%;Potassium [3,5-bis(trifluoromethyl)phenyl]trifluoroborate 96%;potassium [3,5-bis(trifluoromethyl)phenyl]-trifluoroboranuide;POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE ISO 9001:2015 REACH
CBNumber:
CB5731640
Molecular Formula:
C8H3BF9K
Molecular Weight:
320
MDL Number:
MFCD03701625
MOL File:
166328-09-2.mol
Last updated:2022-12-30 16:20:48

POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE Properties

Melting point >300℃
storage temp. Inert atmosphere,Room Temperature

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P280a-P304+P340-P405-P501a-P261-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
Hazard Note  Irritant
HS Code  2931900090
NFPA 704
1
2 0

POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE price More Price(25)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 571563 Potassium 3,5-bis(trifluoromethyl)phenyltrifluoroborate 166328-09-2 1g $59.8 2023-06-20 Buy
Alfa Aesar H53113 Potassium 3,5-bis(trifluoromethyl)phenytrifluoroborate, 96% 166328-09-2 1g $49.9 2023-06-20 Buy
Alfa Aesar H53113 Potassium 3,5-bis(trifluoromethyl)phenytrifluoroborate, 96% 166328-09-2 5g $205 2023-06-20 Buy
TRC P699195 Potassium 3,5-bis(trifluoromethyl)phenyltrifluoroborate 166328-09-2 500mg $75 2021-12-16 Buy
Matrix Scientific 102348 Potassium 3,5-bistrifluoromethylphenyltrifluoroborate >95% 166328-09-2 1g $83 2021-12-16 Buy
Product number Packaging Price Buy
571563 1g $59.8 Buy
H53113 1g $49.9 Buy
H53113 5g $205 Buy
P699195 500mg $75 Buy
102348 1g $83 Buy

POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE Chemical Properties,Uses,Production

Synthesis

A solution of 3,5-bis(triflfluoromethyl)phenylboronic acid (10 g, 38.8 mmol) in methanol (15 mL) was added to an aqueous solution of KHF2 (4.5 M, 26 mL, 117 mmol) at room temperature. A heavy precipitate was deposited. The resulting suspension was stirred 148 MODERN ORGANIC SYNTHESIS IN THE LABORATORYfor 1 h at room temperature, and the precipitated product was collected and washed with methanol. Recrystallization from a minimum amount of acetone produced 11 g (89%) of potassium 3,5-bis(triflfluoromethyl)phenyltriflfluoroborate. Reference: Molander, G. A.; Biolatto, B. J. Org. Chem. 2003, 68, 4302−4314.

Uses

Thos chemical has been used for inserting a 3,5-bis(trifluoromethyl)phenyl group into the position of a halogen or triflate group of various arenes and various heterocycles in Pd-catalyzed Suzuli-Miyaura cross-coupling reactions.

POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 52)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Wuhan Chemwish Technology Co., Ltd
027-67849912 sales@chemwish.com CHINA 10828 58
Shaanxi Dideu Medichem Co. Ltd
+86-029-89586680 +86-18192503167 1026@dideu.com China 9654 58
CD Chemical Group Limited
+8615986615575 info@codchem.com China 20356 58
Amadis Chemical Company Limited
571-89925085 sales@amadischem.com China 131981 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 94838 76
Alfa Aesar 400-6106006 saleschina@alfa-asia.com China 30132 84
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44751 61
Wuhan Chemwish Technology Co., Ltd 86-027-67849912 sales@chemwish.com China 35906 56
Capot Chemical Co., Ltd +86 (0) 571 85 58 67 18 sales@capotchem.com China 18217 66

POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE Spectrum

POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE Potassium [3,5-bis(trifluoromethyl)phenyl]trifluoroborate 96% Potassium[3,5-bis(trifluoromethyl)phenyl]trifluoroborate96% Potassium [3,5-bis(trifluoromethyl)pheny]trifluoroborate POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENY& Potassium (3,5-bis(trifluoromethyl) potassium [3,5-bis(trifluoromethyl)phenyl]-trifluoroboranuide Borate(1-), [3,5-bis(trifluoromethyl)phenyl]trifluoro-, potassium (1:1), (T-4)- POTASSIUM 3,5-BIS(TRIFLUOROMETHYL)PHENYLTRIFLUOROBORATE ISO 9001:2015 REACH [3,5-bis(trifluoromethyl)phenyl]-trifluoroboranuide potassium,[3,5-bis(trifluoromethyl)phenyl]-trifluoroboranui 166328-09-2 C8H3BF9K CF32C6H3BF3K Organometallic Reagents Trifluoroborate Salts Boronic Acids and Derivatives Aryl Aryl Boronic Acids and Derivatives Trifluoroborate Salts blocks Trifluoroborates Molander Ates Organoborons Aryl Trifluoroborate Salts Boronic Acids and Derivatives Chemical Synthesis Organometallic Reagents Trifluoroborate Salts