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1-PHENYL-1-TRIMETHYLSILOXYETHYLENE

CAS No.
13735-81-4
Chemical Name:
1-PHENYL-1-TRIMETHYLSILOXYETHYLENE
Synonyms
Trimethyl[(1-phenylvinyl)oxy]silane;DK071;α-(trimethylsiloxy)styrene;à-(trimethylsiloxy)styrene;α-(Trimethylsilyloxy)styrene;ALPHA-(TRIMETHYLSILOXY)STYRENE;1-Phenyl-1-trimethylsiloxyethene;ALPHA-(TRIMETHYLSILYLOXY)STYRENE;(1-phenylvinyl)oxyTrimethylsilane;trimethyl(1-phenylethenoxy)silane
CBNumber:
CB5740196
Molecular Formula:
C11H16OSi
Molecular Weight:
192.33
MDL Number:
MFCD00008582
MOL File:
13735-81-4.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

1-PHENYL-1-TRIMETHYLSILOXYETHYLENE Properties

Melting point 122-123 °C
Boiling point 88-89 °C/11 mmHg (lit.)
Density 0.938 g/mL at 25 °C (lit.)
vapor density >1 (vs air)
refractive index n20/D 1.502(lit.)
Flash point 174 °F
storage temp. 2-8°C
form clear liquid
color Colorless to Light orange to Yellow
Specific Gravity 0.938
Water Solubility Reacts with water.
Sensitive Moisture Sensitive
Hydrolytic Sensitivity 7: reacts slowly with moisture/water
BRN 1306914
CAS DataBase Reference 13735-81-4(CAS DataBase Reference)
EPA Substance Registry System Silane, trimethyl[(1-phenylethenyl)oxy]- (13735-81-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS07
Signal word  Warning
Hazard statements  H315-H319-H335
Precautionary statements  P261-P264-P271-P280-P302+P352-P305+P351+P338
Hazard Codes  Xi
Risk Statements  36/37/38
Safety Statements  26-36
WGK Germany  3
10-21
TSCA  No
HS Code  2931900090
NFPA 704
2
2 0

1-PHENYL-1-TRIMETHYLSILOXYETHYLENE price More Price(12)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 235040 1-Phenyl-1-trimethylsiloxyethylene 98% 13735-81-4 5g $108 2024-03-01 Buy
Sigma-Aldrich 235040 1-Phenyl-1-trimethylsiloxyethylene 98% 13735-81-4 25g $483 2024-03-01 Buy
TCI Chemical P1280 1-Phenyl-1-trimethylsilyloxyethylene >95.0%(GC) 13735-81-4 10mL $164 2024-03-01 Buy
Alfa Aesar L05308 1-Phenyl-1-trimethylsiloxyethylene, 97% 13735-81-4 1g $22.65 2024-03-01 Buy
Alfa Aesar L05308 1-Phenyl-1-trimethylsiloxyethylene, 97% 13735-81-4 5g $78.65 2024-03-01 Buy
Product number Packaging Price Buy
235040 5g $108 Buy
235040 25g $483 Buy
P1280 10mL $164 Buy
L05308 1g $22.65 Buy
L05308 5g $78.65 Buy

1-PHENYL-1-TRIMETHYLSILOXYETHYLENE Chemical Properties,Uses,Production

Uses

1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of β-amino ketones in water via Mannich-type reaction and cis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction. It is also used as chemical additives and intermediates.

Uses

1-Phenyl-1-trimethylsiloxyethylene has been used in the synthesis of:

  • β-amino ketones in water via Mannich-type reaction
  • cis-2,6-disubstituted dihydropyrans via three-component, one-pot cascade reaction

General Description

1-Phenyl-1-trimethylsiloxyethylene is a styrene type silyl enol ether, reacts with formaldehyde and 2,4-pentanedione to yield the corresponding dihydropyran. It also undergoes Mukaiyama aldol reaction with aldehydes in water in the presence of amphiphilic calix[6]arene derivatives as surfactants.

1-PHENYL-1-TRIMETHYLSILOXYETHYLENE Preparation Products And Raw materials

Global( 117)Suppliers
Supplier Tel Email Country ProdList Advantage
Shanghai Daken Advanced Materials Co.,Ltd
+86-371-66670886 info@dakenam.com China 15928 58
ATK CHEMICAL COMPANY LIMITED
+undefined-21-51877795 ivan@atkchemical.com China 32480 60
Win-Win Chemical CO., Limited
0086-577-64498589 sales@win-winchemical.com CHINA 998 58
Chongqing Chemdad Co., Ltd
+86-023-61398051 +8613650506873 sales@chemdad.com China 39916 58
career henan chemical co
+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
Zhengzhou Alfa Chemical Co.,Ltd
+8618530059196 sale04@alfachem.cn China 12468 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671 sales@tnjchem.com China 34572 58
WinWin Chemical CO., Limited
+86-0086-577-64498589 +86-15355981851 sales@win-winchemical.com China 13854 58
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739 info@dycnchem.com CHINA 52867 58
LEAP CHEM CO., LTD.
+86-852-30606658 market18@leapchem.com China 24738 58

View Lastest Price from 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
1-Phenyl-1-trimethylsiloxyethylene 98% pictures 2021-07-02 1-Phenyl-1-trimethylsiloxyethylene 98%
13735-81-4
US $15.00-10.00 / KG 1KG 99%+ HPLC Monthly supply of 1 ton Zhuozhou Wenxi import and Export Co., Ltd
1-PHENYL-1-TRIMETHYLSILOXYETHYLENE pictures 2020-01-13 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE
13735-81-4
US $9.80 / KG 1g ≥99% 100kg Career Henan Chemical Co
1-(Trimethylsilyloxy)-1-phenylethene 1-Phenyl-1-trimethylsiloxyethene 1-Phenylvinyl trimethylsilyl ether (1-Phenylethenyloxy)trimethylsilane [(1-Phenylethenyl)oxy]trimethylsilane à-(trimethylsiloxy)styrene α-(trimethylsiloxy)styrene 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE 97% α-(Trimethylsiloxy)styrene, Acetophenone enol trimethylsilyl ether 1-Phenyl-1-(trimethylsilyloxy)ethene Trimethyl(α-methylenebenzyloxy)silane Trimethyl[(1-phenylethenyl)oxy]silane Silane, trimethyl[(1-phenylethenyl)oxy]- Silane, trimethyl[(1-phenylvinyl)oxy]- trimethyl[(1-phenylethenyl)oxy]-silan ALPHA-(TRIMETHYLSILYLOXY)STYRENE ALPHA-(TRIMETHYLSILOXY)STYRENE ACETOPHENONE ENOL TRIMETHYLSILYL ETHER 1-PHENYL-1-TRIMETHYLSILOXYETHYLENE 1-PHENYL-1-TRIMETHYLSILYLOXYETHYLENE (1-phenylvinyl)oxyTrimethylsilane α-(Trimethylsilyloxy)styrene 1-Phenyl-1-trimethylsilyloxyethylene> Benzene, [1-[(trimethylsilyl)oxy]ethenyl]- trimethyl(1-phenylethenoxy)silane Trimethyl[(1-phenylvinyl)oxy]silane DK071 13735-81-4 133735-81-4 C6H5CCH2OSiCH33 CH33SiOCC6H5CH2 C11H15OSi Oxygen Compounds Building Blocks Silicon Compounds (for Synthesis) Monoalkoxysilanes Si-O Compounds Si (Classes of Silicon Compounds) Enol Ethers Organic Building Blocks Building Blocks Chemical Synthesis Enol Ethers Organic Building Blocks Oxygen Compounds Monoalkoxysilanes Si (Classes of Silicon Compounds) Silicon Compounds (for Synthesis) Si-O Compounds Synthetic Organic Chemistry