ChemicalBook >> CAS DataBase List >>2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE
2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE
- CAS No.
- 39085-59-1
- Chemical Name:
- 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE
- Synonyms
- TPSH;TRISYLHYDRAZIDE;TPSH, Trisylhydrazide;TRIISOPROPYLBENZENE SULFONYLHYDRAZIDE;2,4,6-TRIISOPROPYLBENZENESULFONOHYDRAZINE;2,4,6-triisopropylbenzenesulphonohydrazide;2,4,6-TRIISOPROPYLBENZENESULFONO-HYDRAZIDE;2,4,6-Triisopropylphenylsulfonyl hydrazine;2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE;2,4,6-Triisopropyl benzenesulphonohydrazine
- CBNumber:
- CB5753387
- Molecular Formula:
- C15H26N2O2S
- Molecular Weight:
- 298.44
- MDL Number:
- MFCD00014750
- MOL File:
- 39085-59-1.mol
- MSDS File:
- SDS
Last updated:2023-05-09 09:30:45
| Melting point | 110-112 °C (dec.) (lit.) |
|---|---|
| Boiling point | 396.6±52.0 °C(Predicted) |
| Density | 1.075 |
| storage temp. | -20°C |
| solubility | Chloroform (Slightly), Methanol (Slightly) |
| pka | 9.51±0.10(Predicted) |
| form | Solid |
| color | Off-White |
| Sensitive | Moisture Sensitive |
| BRN | 2145001 |
| InChIKey | GBQCDUBJTLROBV-UHFFFAOYSA-N |
| CAS DataBase Reference | 39085-59-1(CAS DataBase Reference) |
| FDA UNII | XE77ZV5VCV |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |  GHS07 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Warning | |||||||||
| Hazard statements | H315-H319-H335 | |||||||||
| Precautionary statements | P261-P280a-P304+P340-P305+P351+P338-P405-P501a | |||||||||
| Hazard Codes | Xi | |||||||||
| Safety Statements | 22-24/25 | |||||||||
| RIDADR | UN 1325 4.1/PG III | |||||||||
| WGK Germany | 3 | |||||||||
| F | 4.8-10 | |||||||||
| HazardClass | 4.1 | |||||||||
| PackingGroup | III | |||||||||
| HS Code | 29350090 | |||||||||
| NFPA 704 |
|
2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE price More Price(36)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 192198 | 2,4,6-Triisopropylbenzenesulfonyl hydrazide 90% | 39085-59-1 | 1g | $58.4 | 2024-03-01 | Buy |
| Sigma-Aldrich | 192198 | 2,4,6-Triisopropylbenzenesulfonyl hydrazide 90% | 39085-59-1 | 5g | $206 | 2024-03-01 | Buy |
| TCI Chemical | T1591 | 2,4,6-Triisopropylbenzenesulfonyl Hydrazide >95.0%(T) | 39085-59-1 | 5g | $154 | 2024-03-01 | Buy |
| TCI Chemical | T1591 | 2,4,6-Triisopropylbenzenesulfonyl Hydrazide >95.0%(T) | 39085-59-1 | 25g | $495 | 2024-03-01 | Buy |
| Alfa Aesar | 017976 | 2,4,6-Triisopropylbenzenesulfonyl hydrazide | 39085-59-1 | 0.5g | $40.65 | 2024-03-01 | Buy |
2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Chemical Properties,Uses,Production
Chemical Properties
White crystal
Uses
2,4,6-Triisopropylbenzenesulfonyl hydrazide (TPSH) is a best source of diazene. It can be used as a selective reducing agent for the reduction of alkenes and other double bonds via in situ formation of diazene (diimide) in the presence of base. TPSH reduction method is efficiently used in the synthesis of polymers and natural products as it tolerates sensitive groups such as esters, ketones, or organometal complexes. It also undergoes condensation reaction with ketones and aldehydes to produce corresponding hydrazones that can be converted into reactive intermediates such as diazoalkanes, carbenes, carbenium ions, and alkyllithiums.
It can be used as a reagent to synthesize:
- Nitrogen-containing polycyclic compounds by intramolecular cyclopropanation of N-alkyl indoles/pyrroles.
- Vinyl sulfones by sulfonylation reaction of vinyl bromides.
- Nitrile derivatives from carbonyl compounds via formation of corresponding hydrazones.
Uses
As a reagent for generation of diimide
2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE Preparation Products And Raw materials
Raw materials
Preparation Products
Global( 136)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Shanghai Daken Advanced Materials Co.,Ltd | +86-371-66670886 | info@dakenam.com | China | 15928 | 58 |
| ATK CHEMICAL COMPANY LIMITED | +undefined-21-51877795 | ivan@atkchemical.com | China | 32480 | 60 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 | sales@sdzschem.com | China | 2931 | 58 |
| Changzhou Ditong Chemical Co.,Ltd | +86-0519-88299272 | info@edengenechem.com | China | 2169 | 58 |
| Chongqing Chemdad Co., Ltd | +86-023-61398051 +8613650506873 | sales@chemdad.com | China | 39916 | 58 |
| Alchem Pharmtech,Inc. | 8485655694 | sales@alchempharmtech.com | United States | 63711 | 58 |
| CONIER CHEM AND PHARMA LIMITED | +8618523575427 | sales@conier.com | China | 47465 | 58 |
| Jinan Liheng Biotechnology Co., Ltd. | 15865262812 | info@lihengpharm.com | CHINA | 938 | 58 |
| Antai Fine Chemical Technology Co.,Limited | 18503026267 | info@antaichem.com | CHINA | 9641 | 58 |
View Lastest Price from 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2019-07-06 | 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE
39085-59-1
|
US $1.00 / KG | 1KG | 99% | Customized | Career Henan Chemical Co |
-
- 2,4,6-TRIISOPROPYLBENZENESULFONYL HYDRAZIDE
39085-59-1
- US $1.00 / KG
- 99%
- Career Henan Chemical Co
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39085-59-1
CH32CH3C6H2SO2NHNH2
C15H26N2O2S
Building Blocks
Organic Building Blocks
Sulfonyl Hydrazides
Sulfur Compounds
Building Blocks
Chemical Synthesis
Organic Building Blocks
Sulfonyl Hydrazides
Sulfur Compounds