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D(+)-10-Camphorsulfonyl chloride

D(+)-10-Camphorsulfonyl chloride
D(+)-10-Camphorsulfonyl chloride structure
CAS No.
21286-54-4
Chemical Name:
D(+)-10-Camphorsulfonyl chloride
Synonyms
Camphor-10-suL;D(+)CAMPHOR SULFONYL CHLORIDE;D-CAMPHOR-10-SULFONYL CHLORIDE;S-(+)-caMphorsulfonyl chloride;(+)-10-CAMPHORSULFONYL CHLORIDE;D(+)-1-CaMphorsulfonyl chloride;(+)-CAMPHOR-10-SULFONYL CHLORIDE;D(+)-10-CAMPHORSULFONYL CHLORIDE;D-CAMPHOR-10-SULFONYL CHLORIDE 96%;Dextro-10-camphorsulfonyl chloride
CBNumber:
CB5775185
Molecular Formula:
C10H15ClO3S
Formula Weight:
250.74
MOL File:
21286-54-4.mol

D(+)-10-Camphorsulfonyl chloride Properties

Melting point:
67-68 °C
Boiling point:
349.4±15.0 °C(Predicted)
alpha 
33 º (c=1, CHCl3 22 ºC)
Density 
1.2078 (estimate)
refractive index 
32 ° (C=1, CHCl3)
storage temp. 
Keep in dark place,Inert atmosphere,Room temperature
form 
Crystalline Powder
color 
Off-white to beige
optical activity
[α]22/D +33°, c = 1 in chloroform
Sensitive 
Moisture Sensitive
BRN 
3205974
InChIKey
BGABKEVTHIJBIW-UHFFFAOYSA-N
CAS DataBase Reference
21286-54-4(CAS DataBase Reference)
NIST Chemistry Reference
(+)-Camphor-10-sulfonyl chloride(21286-54-4)
SAFETY
  • Risk and Safety Statements
Symbol(GHS) 
GHS05
Signal word  Danger
Hazard statements  H318-H314
Precautionary statements  P280-P305+P351+P338-P310-P260h-P301+P330+P331-P303+P361+P353-P405-P501a
Hazard Codes  C
Risk Statements  34
Safety Statements  26-36/37/39-45
RIDADR  UN 3261 8/PG 2
WGK Germany  3
10-21
HazardClass  8
PackingGroup  II
HS Code  29147000

D(+)-10-Camphorsulfonyl chloride price More Price(5)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 219576 (1S)-(+)-10-Camphorsulfonyl chloride 97% 21286-54-4 5g $33.2 2021-03-22 Buy
Sigma-Aldrich 219576 (1S)-(+)-10-Camphorsulfonyl chloride 97% 21286-54-4 25g $131 2021-03-22 Buy
TCI Chemical C0998 (+)-10-Camphorsulfonyl Chloride >97.0%(GC)(T) 21286-54-4 25g $74 2021-03-22 Buy
TCI Chemical C0998 (+)-10-Camphorsulfonyl Chloride >97.0%(GC)(T) 21286-54-4 5g $24 2021-03-22 Buy
Sigma-Aldrich 219576 (1S)-(+)-10-Camphorsulfonyl chloride 97% 21286-54-4 100g $406 2021-03-22 Buy

D(+)-10-Camphorsulfonyl chloride Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powde

Uses

As a useful synthetic intermediate, D(+)-10-Camphorsulfonyl chloride can be used for asymmetric hydroxylation

Uses

A chiral derivative of Camphor

Purification Methods

If free from OH bands in the IR, then recrystallise it from Et2O or pet ether; otherwise treat it with SOCl2 at 50o for 30minutes, evaporate, dry the residue over KOH in a vacuum and recrystallise it. The (±)-acid chloride has m 85o [Bartlett & Knox Org Synth 45 14 1965]. Itis characterised as the amide (prisms from EtOH) m 132o, [ ] 17 (+) and (-) 1.5o (EtOH). On repeated recrystallisation from EtOH the anilide has m 120.5-121o, [] 25 +76o (c 1, CHCl3). [Read & Storey J Chem Soc 2761 1930, Sutherland & Shriner J Am Chem Soc 58 62 1936, Halterman et al. J Am Chem Soc 109 8105 1987, Bartlet & Knox Org Synth 45 55 1945, Beilstein 11 IV 650.]

D(+)-10-Camphorsulfonyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products


D(+)-10-Camphorsulfonyl chloride Suppliers

Global( 162)Suppliers
Supplier Tel Fax Email Country ProdList Advantage
Xi'an Kono chem co., Ltd.,
13289246953 029-86107037
info@konochemical.com CHINA 3000 58
Alchem Pharmtech,Inc.
8485655694
sales@alchempharmtech.com United States 63726 58
CONIER CHEM AND PHARMA LIMITED
86-18523575427
sales@conier.com CHINA 47498 58
career henan chemical co
13203830695 0086-371-86658258
0086-371-86658258 factory@coreychem.com CHINA 29864 58
SHANGHAI T&W PHARMACEUTICAL CO., LTD.
86-021-61999440
contact@trustwe.com CHINA 10005 58
SIMAGCHEM CORP
13806087780 +86 13806087780
shaobowang@simagchem.com CHINA 17453 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671
0551-65418697 sales@tnjchem.com CHINA 37441 58
AFINE CHEMICALS LIMITED
008657185134551
008657185134895 info@afinechem.com CHINA 15559 58
Finetech Industry Limited
86 27 87465837
86 27 87772287 info@finetechnology-ind.com CHINA 9373 58
Dayang Chem (Hangzhou) Co.,Ltd.
17705817739 +86-571-88938639
+86-571-88938652,+86-571- 88492614 info@dycnchem.com CHINA 52932 58

View Lastest Price from D(+)-10-Camphorsulfonyl chloride manufacturers

Image Release date Product Price Min. Order Purity Supply Ability Manufacturer
2020-01-09 D(+)-10-Camphorsulfonyl chloride
21286-54-4
US $1.00 / KG 1KG 99% 200kg Career Henan Chemical Co

D(+)-10-Camphorsulfonyl chloride Spectrum


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