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D(+)-10-Camphorsulfonyl chloride

CAS No.
21286-54-4
Chemical Name:
D(+)-10-Camphorsulfonyl chloride
Synonyms
Camphor-10-suL;D(+)CAMPHOR SULFONYL CHLORIDE;D-CAMPHOR-10-SULFONYL CHLORIDE;S-(+)-caMphorsulfonyl chloride;(+)-10-CAMPHORSULFONYL CHLORIDE;D(+)-1-CaMphorsulfonyl chloride;(+)-10-Camphorsulfonyl Chloride;(+)-CAMPHOR-10-SULFONYL CHLORIDE;D(+)-10-CAMPHORSULFONYL CHLORIDE;D-CAMPHOR-10-SULFONYL CHLORIDE 96%
CBNumber:
CB5775185
Molecular Formula:
C10H15ClO3S
Molecular Weight:
250.74
MDL Number:
MFCD00064156
MOL File:
21286-54-4.mol
MSDS File:
SDS
Last updated:2023-04-23 13:52:06

D(+)-10-Camphorsulfonyl chloride Properties

Melting point 67-68 °C
Boiling point 349.4±15.0 °C(Predicted)
alpha 33 º (c=1, CHCl3 22 ºC)
Density 1.2078 (estimate)
refractive index 32 ° (C=1, CHCl3)
storage temp. Keep in dark place,Inert atmosphere,Room temperature
solubility Chloroform (Slightly), Ethyl Acetate (Slightly)
form Crystalline Powder
color Off-white to beige
optical activity [α]22/D +33°, c = 1 in chloroform
Sensitive Moisture Sensitive
BRN 3205974
InChIKey BGABKEVTHIJBIW-UHFFFAOYSA-N
CAS DataBase Reference 21286-54-4(CAS DataBase Reference)
NIST Chemistry Reference (+)-Camphor-10-sulfonyl chloride(21286-54-4)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictograms
GHS05
Signal word  Danger
Hazard statements  H314
Precautionary statements  P260-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338-P363
Hazard Codes  C
Risk Statements  34
Safety Statements  26-36/37/39-45
RIDADR  UN 3261 8/PG 2
WGK Germany  3
10-21
HazardClass  8
PackingGroup  II
HS Code  29147000
NFPA 704
0
3 0

D(+)-10-Camphorsulfonyl chloride price More Price(22)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 219576 (1S)-(+)-10-Camphorsulfonyl chloride 97% 21286-54-4 5g $43.7 2024-03-01 Buy
Sigma-Aldrich 219576 (1S)-(+)-10-Camphorsulfonyl chloride 97% 21286-54-4 25g $159 2024-03-01 Buy
TCI Chemical C0998 (+)-10-Camphorsulfonyl Chloride >97.0%(GC)(T) 21286-54-4 5g $26 2024-03-01 Buy
TCI Chemical C0998 (+)-10-Camphorsulfonyl Chloride >97.0%(GC)(T) 21286-54-4 25g $77 2024-03-01 Buy
Sigma-Aldrich 219576 (1S)-(+)-10-Camphorsulfonyl chloride 97% 21286-54-4 100g $587 2024-03-01 Buy
Product number Packaging Price Buy
219576 5g $43.7 Buy
219576 25g $159 Buy
C0998 5g $26 Buy
C0998 25g $77 Buy
219576 100g $587 Buy

D(+)-10-Camphorsulfonyl chloride Chemical Properties,Uses,Production

Chemical Properties

white to light yellow crystal powde

Uses

As a useful synthetic intermediate, D(+)-10-Camphorsulfonyl chloride can be used for asymmetric hydroxylation

Uses

A chiral derivative of Camphor.

Purification Methods

If free from OH bands in the IR, then recrystallise it from Et2O or pet ether; otherwise treat it with SOCl2 at 50o for 30minutes, evaporate, dry the residue over KOH in a vacuum and recrystallise it. The (±)-acid chloride has m 85o [Bartlett & Knox Org Synth 45 14 1965]. Itis characterised as the amide (prisms from EtOH) m 132o, [ ] 17 (+) and (-) 1.5o (EtOH). On repeated recrystallisation from EtOH the anilide has m 120.5-121o, [] 25 +76o (c 1, CHCl3). [Read & Storey J Chem Soc 2761 1930, Sutherland & Shriner J Am Chem Soc 58 62 1936, Halterman et al. J Am Chem Soc 109 8105 1987, Bartlet & Knox Org Synth 45 55 1945, Beilstein 11 IV 650.]

D(+)-10-Camphorsulfonyl chloride Preparation Products And Raw materials

Raw materials

Preparation Products

Global( 212)Suppliers
Supplier Tel Email Country ProdList Advantage
Capot Chemical Co.,Ltd.
571-85586718 +8613336195806 sales@capotchem.com China 29797 60
Xi'an Kono chem co., Ltd.,
029-86107037 13289246953 info@konochemical.com China 2995 58
Alchem Pharmtech,Inc.
8485655694 sales@alchempharmtech.com United States 63711 58
CONIER CHEM AND PHARMA LIMITED
+8618523575427 sales@conier.com China 47465 58
career henan chemical co
+86-0371-86658258 15093356674; factory@coreychem.com China 29826 58
SIMAGCHEM CORP
+86-13806087780 sale@simagchem.com China 17368 58
Hefei TNJ Chemical Industry Co.,Ltd.
0551-65418671 sales@tnjchem.com China 34572 58
AFINE CHEMICALS LIMITED
0571-85134551 info@afinechem.com CHINA 15377 58
Dayang Chem (Hangzhou) Co.,Ltd.
571-88938639 +8617705817739 info@dycnchem.com CHINA 52867 58
CD Chemical Group Limited
+8615986615575 info@codchem.com China 20356 58

View Lastest Price from D(+)-10-Camphorsulfonyl chloride manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
D(+)-10-Camphorsulfonyl chloride pictures 2022-01-27 D(+)-10-Camphorsulfonyl chloride
21286-54-4
US $0.00 / KG 1KG 98.9% 100 tons Honest Joy Holdings Limited
D(+)-10-Camphorsulfonyl chloride pictures 2020-01-09 D(+)-10-Camphorsulfonyl chloride
21286-54-4
US $1.00 / KG 1KG 99% 200kg Career Henan Chemical Co
(+)-10-CAMPHORSULFONYL CHLORIDE d-2-oxobornane-10-sulphonyl chloride (1S)-(+)-10-CAMPHORSULFONYL CHLORIDE (1S)-CAMPHOR-10-SULFONIC ACID CHLORIDE (1S)-(+)-CAMPHOR-10-SULFONYL CHLORIDE (1S)-(+)-CAMPHOR-10-SULPHONYL CHLORIDE D-CAMPHOR-10-SULFONYL CHLORIDE D(+)-10-CAMPHORSULFONYL CHLORIDE (+) CAMPHOR-10-SULFONIC ACID CHLORIDE (+)-CAMPHOR-10-SULFONYL CHLORIDE (1S)-(+)-10-CAMPHORSULFONYL CHLORIDE, 97 % D-CAMPHOR-10-SULFONYL CHLORIDE 96% (S)-(+)-Camphor-10-SulfonylChloride D(+)CAMPHOR SULFONYL CHLORIDE (+)-Camphor-10-sulfonyl chloride, (1S)-Camphor-10-sulfonic acid chloride Bicyclo[2.2.1]heptane-1-methanesulfonyl chloride, 7,7-dimethyl-2-oxo- D-2-Oxobornane-10-sulfonyl chloride D(+)-1-CaMphorsulfonyl chloride (1S,4R)-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfochloride [1S,4R,(+)]-7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfonic acid chloride D(+)-10-Camphorsulfonyl chloride,97% (+)-10-CaMphorsulfonic Acid Chloride (1S,4R)-7,7-DiMethyl-2-oxo-bicyclo[2.2.1]heptane-1-Methanesulfonyl Chloride S-(+)-caMphorsulfonyl chloride ((1S,4R)-7,7-DiMethyl-2-oxobicyclo[2.2.1]heptan-1-yl)Methanesulfonyl chloride Bicyclo[2.2.1]heptane-1-methanesulfonyl chloride, 7,7-dimethyl-2-oxo-, (1S)- Dextro-10-camphorsulfonyl chloride D(+)-10-CaMphorsulfonyl chloride, 97% 5GR (1S)-(+)-10-Camphorsulfonyl chloride 97% [(1R,4S)-7,7-dimethyl-3-oxo-4-bicyclo[2.2.1]heptanyl]methanesulfonyl chloride (7,7-dimethyl-3-oxo-4-bicyclo[2.2.1]heptanyl)methanesulfonyl chloride (1S)-(+)-10-Camphorsulphonyl Chloride Camphor-10-suL Bicyclo[2.2.1]heptane-1-methanesulfonyl chloride, 7,7-dimethyl-2-oxo-, (1S,4R)- (+)-10-Camphorsulfonyl Chloride 21286-54-4 2186-54-4 C10H15ClO3S UV-VIS Chiral Resolving Reagents Chiral Resolution Reagents Optical Resolution Asymmetric Synthesis for Resolution of Alcohols & Thiols Bicyclic Monoterpenes Terpenes for Resolution of Bases chiral Chiral Reagents Bicyclic Monoterpenes Biochemistry for Resolution of Alcohols & Thiols for Resolution of Bases Optical Resolution Synthetic Organic Chemistry Terpenes Intermediates & Fine Chemicals Pharmaceuticals