ChemicalBook >> CAS DataBase List >>(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
- CAS No.
- 133545-25-2
- Chemical Name:
- (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
- Synonyms
- SL-A102-2;(S)-p-Tol-MeOBIPHEP;(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl;(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl;(S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(4-methylphenyl)phosphine];(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%;(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%;[(1S)-6,6'-Dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[bis(4-methylphenyl)phosphine;(S)-(-)-2,2''-BIS(DI-P-TOLYLPHOSPHINO)-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%;1,1'-[(1S)-6,6'-Dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis(4-methylphenyl)-phosphine
- CBNumber:
- CB61180989
- Molecular Formula:
- C42H40O2P2
- Molecular Weight:
- 638.71
- MDL Number:
- MFCD09753006
- MOL File:
- 133545-25-2.mol
Last updated:2023-04-23 13:52:06
(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% price More Price(15)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Strem Chemicals | 15-0157 | (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% | 133545-25-2 | 100mg | $96 | 2024-03-01 | Buy |
| Strem Chemicals | 15-0157 | (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% | 133545-25-2 | 500mg | $355 | 2024-03-01 | Buy |
| Strem Chemicals | 15-0157 | (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% | 133545-25-2 | 2g | $1207 | 2024-03-01 | Buy |
| Strem Chemicals | 15-0157 | (S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl, min. 97% | 133545-25-2 | 10g | $4824 | 2024-03-01 | Buy |
| American Custom Chemicals Corporation | ING0001340 | (S)-(-)-2,2'-BIS(DI-P-TOLYLPHOSPHINO)-6,6'-DIMETHOXY-1,1'-BIPHENYL 95.00% | 133545-25-2 | 1G | $1269.75 | 2021-12-16 | Buy |
(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Chemical Properties,Uses,Production
Reactions
In many respects the catalytic profile of the MeOBIPHEP ligands is similar to that of other atropisomeric diphosphines such as binap and its many analogs. The nature of the PR2 group strongly influences the catalytic performance of the metal complexes. The rhodium and ruthenium MeO-BIPHEP catalysts are highly effective for the hydrogenation of various C=O, C=C and C=N bonds and several synthetically useful C-C coupling reactions.
- Ru and Ir catalyzed dynamic kinetic resolution for the synthesis of hydroxy, amino acid derivatives.
- Ru-catalyzed asymmetric hydrogenation of ketones and alkenes.
- Ir catalyzed enantioselective hydrogenation of heteroaromatic compounds.
- Conjugate addition using 2-heteroaryl titanates and zinc reagents.
- Enantio- and regioselective heck-type reaction of aryl boronic acids with 2,3-dihydrofuran
- Rhodium-catalyzed carbonyl Z-dienylation.
- Rhodium-catalyzed asymmetric 1,4 addition of arylboronic acids to maleimides and enones.
Chemical Properties
Off-white powder
Uses
General Description
sold in collaboration with Solvias AG
(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Preparation Products And Raw materials
Raw materials
Preparation Products
(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97% Suppliers
Global( 31)Suppliers
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Suzhou Origin Specialty Chemicals Co., Ltd. | +86-512-68662322 +86-17312436797 | hanqun@origsc.com | China | 776 | 58 |
| Aladdin Scientific | +1-833-552-7181 | sales@aladdinsci.com | United States | 57511 | 58 |
| J & K SCIENTIFIC LTD. | 010-82848833 400-666-7788 | jkinfo@jkchemical.com | China | 96815 | 76 |
| Daicel Chiral Technologies (China)CO.,LTD | 021-50460086-9 15921403865 | han_yajun@dctc.daicel.com | China | 6818 | 65 |
| Bide Pharmatech Ltd. | 400-1647117 15221909166 | product02@bidepharm.com | China | 41438 | 60 |
| Sigma-Aldrich | 021-61415566 800-8193336 | orderCN@merckgroup.com | China | 51471 | 80 |
| Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. | 0371-0371-65511006 18625597674 | sales@kingorgchem.com | China | 950 | 55 |
| LaaJoo | 021-60702684 18516024827 | huang.jiayi@sinocompound.com | China | 2654 | 58 |
| Greenherbs Science and Technology Development Co., Ltd. | 010-61136123 | pub02@greenherbs.com.cn | China | 4049 | 58 |
| Shanghai Anyinuo Biomedical Technology Co., Ltd. | 021-88888888 | 420970979@qq.com | China | 2806 | 58 |
133545-25-2((S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%)Related Search:
(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
(S)-(-)-2,2''-BIS(DI-P-TOLYLPHOSPHINO)-6,6''-DIMETHOXY-1,1''-BIPHENYL, MIN. 97%
(S)-(6,6μ-Dimethoxybiphenyl-2,2μ-diyl)bis[bis(4-methylphenyl)phosphine]
(S)-p-Tol-MeOBIPHEP, SL-A102-2, (S)-2,2μ-Bis(di-p-tolylphosphino)-6,6μ-dimethoxy-1,1μ-biphenyl
(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl
[(1S)-6,6'-Dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[bis(4-methylphenyl)phosphine
(S)-p-Tol-MeOBIPHEP
SL-A102-2
(S)-(6,6'-Dimethoxybiphenyl-2,2'-diyl)bis[bis(4-methylphenyl)phosphine] >=97%, optical purity ee: >=99%
[2-[2-bis(4-methylphenyl)phosphanyl-6-methoxyphenyl]-3-methoxyphenyl]-bis(4-methylphenyl)phosphane
1,1'-[(1S)-6,6'-Dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis(4-methylphenyl)-phosphine
Phosphine, 1,1'-[(1S)-6,6'-dimethoxy[1,1'-biphenyl]-2,2'-diyl]bis[1,1-bis(4-methylphenyl)-
(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl,min.97%
(S)-(-)-2,2'-Bis(di-p-tolylphosphino)-6,6'-dimethoxy-1,1'-biphenyl
133545-25-2
Chiral Phosphine
MeOBIPHEP Series