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4-Chlorothiophenol

CAS No.
106-54-7
Chemical Name:
4-Chlorothiophenol
Synonyms
4-CHLOROBENZENETHIOL;4-Chloro;PARA-CHLOROTHIOPHENOL;NSC 229564;orothiophenoL;p-Chlorthiofenol;4-CHLOROTHIOPENOL;4-chlorthiophenol;AKOS BBS-00004252;CHLOROTHIOPHENOL-4
CBNumber:
CB6130893
Molecular Formula:
C6H5ClS
Molecular Weight:
144.62
MDL Number:
MFCD00004847
MOL File:
106-54-7.mol
MSDS File:
SDS
Last updated:2023-06-21 21:49:59

4-Chlorothiophenol Properties

Melting point 49-51 °C(lit.)
Boiling point 205-207 °C(lit.)
Density 1.1911
refractive index 1.5480
Flash point >230 °F
storage temp. 2-8°C
solubility methanol: soluble
pka pK1:5.9 (25°C)
form Crystalline Solid
color White to almost white
Water Solubility insoluble
Sensitive Stench/Lachrymatory
BRN 605971
InChIKey VZXOZSQDJJNBRC-UHFFFAOYSA-N
CAS DataBase Reference 106-54-7(CAS DataBase Reference)
EWG's Food Scores 1
FDA UNII 1O71UA6O72
NIST Chemistry Reference Benzenethiol, 4-chloro-(106-54-7)
EPA Substance Registry System Benzenethiol, 4-chloro- (106-54-7)

SAFETY

Risk and Safety Statements

Symbol(GHS)  GHS hazard pictogramsGHS hazard pictograms
GHS05,GHS07
Signal word  Danger
Hazard statements  H302-H314
Precautionary statements  P260-P270-P280-P301+P312-P303+P361+P353-P305+P351+P338
Hazard Codes  C
Risk Statements  22-34-36/37-20/21/22
Safety Statements  26-36/37/39-45-27
RIDADR  UN 3261 8/PG 2
WGK Germany  3
RTECS  DC1050000
9-13-23
Hazard Note  Corrosive/Lachrymatory/Stench
TSCA  Yes
HazardClass  8
PackingGroup  III
HS Code  29309090
NFPA 704
1
3 0

4-Chlorothiophenol price More Price(29)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Sigma-Aldrich 125237 4-Chlorothiophenol 97% 106-54-7 5g $45.8 2024-03-01 Buy
Sigma-Aldrich 125237 4-Chlorothiophenol 97% 106-54-7 100g $110 2024-03-01 Buy
TCI Chemical C0129 4-Chlorobenzenethiol >98.0%(GC)(T) 106-54-7 25g $41 2024-03-01 Buy
TCI Chemical C0129 4-Chlorobenzenethiol >98.0%(GC)(T) 106-54-7 500g $140 2024-03-01 Buy
Alfa Aesar B23838 4-Chlorothiophenol, 97% 106-54-7 25g $24.65 2024-03-01 Buy
Product number Packaging Price Buy
125237 5g $45.8 Buy
125237 100g $110 Buy
C0129 25g $41 Buy
C0129 500g $140 Buy
B23838 25g $24.65 Buy

4-Chlorothiophenol Chemical Properties,Uses,Production

Chemical Properties

white to almost white crystalline solid

Uses

4-Chlorothiophenol was used to modify poly(vinyl chloride) and to synthesize poly(vinyl chloride) with halogen groups.

Uses

Oil additives, agricultural chemicals, plasticizers, rubber chemical, dyes, wetting agents, and stabilizers.

Synthesis Reference(s)

The Journal of Organic Chemistry, 27, p. 4455, 1962 DOI: 10.1021/jo01059a081
Synthetic Communications, 18, p. 575, 1988 DOI: 10.1080/00397918808064014

General Description

4-Chlorothiophenol undergoes oxidative coupling catalyzed by iron(III)-tetra phenyl prophyrin to form disulfides.

Hazard

Toxic by ingestion.

Purification Methods

Recrystallise the thiophenol from aqueous EtOH. The SMe ether has m 129o and the SEt ether has m 64o. [D'Sousa et al. J Org Chem 52 1720 1987, Beilstein 6 H 326, 6 I 149, 6 III 1034.]

Global( 286)Suppliers
Supplier Tel Email Country ProdList Advantage
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18871490254 linda@hubeijusheng.com CHINA 28180 58
Hebei Guanlang Biotechnology Co., Ltd.
+86-19930503282 alice@crovellbio.com China 8822 58

View Lastest Price from 4-Chlorothiophenol manufacturers

Image Update time Product Price Min. Order Purity Supply Ability Manufacturer
4-Chlorothiophenol pictures 2023-06-22 4-Chlorothiophenol
106-54-7
US $0.00 / KG 1KG 99% 50000KG/month Hebei Mojin Biotechnology Co., Ltd
4-Chlorothiophenol  pictures 2022-09-06 4-Chlorothiophenol
106-54-7
US $1.10 / g 1g 99.00% 100 Tons Min Dideu Industries Group Limited
4-Chlorothiophenol pictures 2021-05-08 4-Chlorothiophenol
106-54-7
US $10.00 / PCS 1KG 99% 100 mt Hebei Guanlang Biotechnology Co., Ltd.
4-Chlorothiophenol/4-Chlorobenzenethiol 4-Cyano-Acetophonene/4-CA 4-Chlorothiophenol 99% 4-chlorthiophenol BENZENETHIOL,PARA-CHLORO- 4-CHLOROTHIOPENOL 4-Chlorobenzenethiol, 4-Chlorophenyl mercaptan 1-Chloro-4-mercaptobenzene p-Chlorothiophenol 10g [106-54-7] 4-Chlorothiophenol,4-Chlorobenzenethiol, 4-Chlorophenyl mercaptan 4-Chlorothiophenol, 98% 100GR 4-Chlorothiophenol, 98% 5GR 4-Chloromercaptobenzene 4-Chlorothiophenol NSC 229564 p-Chlorophenylthiol Chlorobenzene thiophenol 4-chloro-benzenethio Benzenethiol, p-chloro- Benzenethiol,4-chloro- p-chloro-benzenethio p-Chlorthiofenol Phenyl mercaptan, p-chloro- p-Mercaptochlorobenzene CHLOROTHIOPHENOL-4 AKOS BBS-00004252 4-CHLOROPHENYL MERCAPTAN 4-CHLOROTHIOPHENOL 4-CHLOROMERCAPTOBENZENE 4-Chlorophenylthiol 4-Chlorothiophenol,98% P-CHLOROBENZENETHIOL P-CHLOROTHIOPHENOL P-CHLOROPHENYL MERCAPTAN 4-Chlorobenzenethiol > 4-Chlorothiophenol ISO 9001:2015 REACH orothiophenoL 4-Chloro PARA-CHLOROTHIOPHENOL 4-CHLOROBENZENETHIOL 106-54-7 C6Cl1H5S1 C6H5SCl Thiols/Mercaptans Sulfur Compounds Organic Building Blocks Building Blocks Phenol&Thiophenol&Mercaptan Phenoles and thiophenoles Aromatic Phenols K00001