Chinese Japanese Germany Korea
ChemicalBook >> CAS DataBase List >>(R)-C3-TUNEPHOS

(R)-C3-TUNEPHOS

(R)-C3-TUNEPHOS Structure
(R)-C3-TUNEPHOS structure
CAS No.
486429-99-6
Chemical Name:
(R)-C3-TUNEPHOS
Synonyms
(R)-C3-TUNEPHOS;(S)-C3-TUNEPHOS;(S)-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin;1,13-Bis(diphenylphosphanyl)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine;1,13-bis(diphenylphosphaneyl)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine;(R)-(6,6'-O-(1,3-PROPYLENE)-OXYLBIPHENYL-2,2'-DIYL)BIS(DIPHENYL)PHOSPHINE;(S)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine;R-(-)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN;(S)-(+)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN;Phosphine, 1,1'-[(13aS)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin-1,13-diyl]bis[1,1-diphenyl-
CBNumber:
CB6139371
Molecular Formula:
C39H32O2P2
Molecular Weight:
594.62
MDL Number:
MFCD06658115
MOL File:
486429-99-6.mol
Last updated:2023-04-23 13:52:06
Request For Quotation

(R)-C3-TUNEPHOS Properties

Melting point 153-161 °C(lit.)
Boiling point 709.9±60.0 °C(Predicted)
storage temp. Inert atmosphere,Room Temperature
form Powder
color white
Sensitive air sensitive

SAFETY

Risk and Safety Statements

WGK Germany  3

(R)-C3-TUNEPHOS price More Price(7)

Manufacturer Product number Product description CAS number Packaging Price Updated Buy
Strem Chemicals 15-0176 (S)-(+)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin, 95% (S)-C3-TUNEPHOS 486429-99-6 100mg $130 2024-03-01 Buy
Strem Chemicals 15-0176 (S)-(+)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin, 95% (S)-C3-TUNEPHOS 486429-99-6 500mg $518 2024-03-01 Buy
American Custom Chemicals Corporation ING0001361 (S)-(+)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN 95.00% 486429-99-6 1G $630 2021-12-16 Buy
Crysdot CD51000906 (S)-C3-TunePhos 95+% 486429-99-6 1g $1409 2021-12-16 Buy
Aaron Chemicals AR003DCB (S)-C3-TunePhos 98% 486429-99-6 250mg $233 2021-12-16 Buy
Product number Packaging Price Buy
15-0176 100mg $130 Buy
15-0176 500mg $518 Buy
ING0001361 1G $630 Buy
CD51000906 1g $1409 Buy
AR003DCB 250mg $233 Buy

(R)-C3-TUNEPHOS Chemical Properties,Uses,Production

Reaction

  1. New generation of chiral biaryl phosphine ligands with tunable dihedral angles. The ability to modify the dihedral angle allows for the fine tuning of the catalyst system and optimization of enantioselectivity.
  2. Ru-C3-TUNEPHOS complexes are used for asymmetric hydrogenation of β-ketoesters , enol acetates , cyclic β-amino acids , α-phthalimide ketones , and α-keto esters .
  3. Rh-catalyzed hydroformylation of cyclopropenes.
Reactions of 486429-99-6

Uses

Chiral Quest Phosphine Ligands for Asymmetric Hydrogenation

Reactant for:

  • Asymmetric hydrogenation of ketones with TunePhos/diamine/ruthenium complexes
  • Stereoselective preparation of arylalkyl esters via enantioselective hydrogenation of enol acetates

Precatalyst for:
  • Enantioselective iridium-catalyzed carbonyl allylation from alcohol or aldehyde by transfer hydrogenative coupling of allyl acetate

Catalyst for:
  • Enantioselective hydrogenation of a-keto esters to a-hydroxy esters using Ru-tunephos catalysts

(R)-C3-TUNEPHOS Preparation Products And Raw materials

Raw materials

Preparation Products

(R)-C3-TUNEPHOS Suppliers

Global( 26)Suppliers
Supplier Tel Email Country ProdList Advantage
Suzhou Origin Specialty Chemicals Co., Ltd. 		+86-512-68662322 +86-17312436797 hanqun@origsc.com China 733 58
Aladdin Scientific 		+1-833-552-7181 sales@aladdinsci.com United States 57511 58
J & K SCIENTIFIC LTD. 010-82848833 400-666-7788 jkinfo@jkchemical.com China 96815 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 4006608290; 18621169109 market03@meryer.com China 40241 62
Energy Chemical 021-021-58432009 400-005-6266 sales8178@energy-chemical.com China 44751 61
Bide Pharmatech Ltd. 400-1647117 15221909166 product02@bidepharm.com China 41132 60
Sigma-Aldrich 021-61415566 800-8193336 orderCN@merckgroup.com China 51471 80
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 0371-0371-65511006 18625597674 sales@kingorgchem.com China 949 55
LaaJoo 021-60702684 18516024827 huang.jiayi@sinocompound.com China 2654 58
Aikon International Limited 025-66113011 18112977050 sales01@aikonchem.com China 16028 58
Supplier Advantage
Suzhou Origin Specialty Chemicals Co., Ltd. 		58
Aladdin Scientific 		58
J & K SCIENTIFIC LTD. 76
Meryer (Shanghai) Chemical Technology Co., Ltd. 62
Energy Chemical 61
Bide Pharmatech Ltd. 60
Sigma-Aldrich 80
Zhengzhou Kingorgchem Chemical Technology Co., Ltd.gy Co., Ltd. 55
LaaJoo 58
Aikon International Limited 58

486429-99-6((R)-C3-TUNEPHOS)Related Search:

Phosphine [CHLORO(R)-C3-TUNEPHOS)(P-CYMENE)RUTHENIUM(II)] CHLORIDE,(R)-C3-TUNEPHOS-RUTHENIUM COMPLEX (R)-C3-TUNEPHOS
(S)-(+)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin, 97% (S)-C3-TUNEPHOS (R)-C3-TUNEPHOS (R)-(6,6'-O-(1,3-PROPYLENE)-OXYLBIPHENYL-2,2'-DIYL)BIS(DIPHENYL)PHOSPHINE R-(-)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN (S)-(+)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN (S)-C3-TUNEPHOS (S)-(+)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin,95%(S)-C3-TUNEPHOS (S)-(+)-1,13-BIS(DIPHENYLPHOSPHINO)-7,8-DIHYDRO-6H-DIBENZO[F,H][1,5]DIOXONIN (S)-C3-TUNEPHOS (S)-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin Phosphine, 1,1'-[(13aS)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonin-1,13-diyl]bis[1,1-diphenyl- 1,13-bis(diphenylphosphaneyl)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine (S)-1,13-Bis(diphenylphosphino)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine 1,13-Bis(diphenylphosphanyl)-7,8-dihydro-6H-dibenzo[f,h][1,5]dioxonine 486429-99-6 C39H32O2P2 Privileged Ligands ChiralQuest Ligands Chiral Catalysts, Ligands, and Reagents Asymmetric Synthesis organophosphine ligand