Boron trifluoride diethyl etherate
- CAS No.
- 109-63-7
- Chemical Name:
- Boron trifluoride diethyl etherate
- Synonyms
- BORON TRIFLUORIDE ETHERATE;BF3 ETHERATE;BORON TRIFLUORIDE ETHER;Trifluoroboron etherate;Boron fluoride etherate;Boron fluoride monoetherate;BORON TRIFLUORIDE ETHYL ETHER;(diethyloxonio)trifluoroborate;Boron fluoride diethyl etherate;BORON TRIFLUORIDE-DIETHYL ETHER
- CBNumber:
- CB6174297
- Molecular Formula:
- C4H10BF3O
- Molecular Weight:
- 141.93
- MDL Number:
- MFCD00013194
- MOL File:
- 109-63-7.mol
- MSDS File:
- SDS
| Melting point | −58 °C(lit.) |
|---|---|
| Boiling point | 126-129 °C(lit.) |
| Density | 1.15 g/mL(lit.) |
| vapor density | 4.9 (vs air) |
| vapor pressure | 4.2 mm Hg ( 20 °C) |
| refractive index |
n |
| Flash point | 118 °F |
| storage temp. | Store below +30°C. |
| solubility | Miscible with ether and alcohol. |
| form | liquid |
| Specific Gravity | 1.126 (20/4℃) |
| color | brown |
| explosive limit | 5.1-18.2%(V) |
| Water Solubility | Reacts |
| Sensitive | Moisture Sensitive |
| Hydrolytic Sensitivity | 7: reacts slowly with moisture/water |
| Merck | 14,1350 |
| BRN | 3909607 |
| Exposure limits | ACGIH: TWA 0.1 ppm; Ceiling 0.7 ppm |
| Stability | Stable. Highly flammable. May form explosive peroxides in contact with air or oxygen. Reacts exothermically with water to form extremely flammable diethyl ether and toxic, corrosive boron trifluoride hydrates. Also incompatible with bases, amines, alkali metals. |
| InChIKey | MZTVMRUDEFSYGQ-UHFFFAOYSA-N |
| CAS DataBase Reference | 109-63-7(CAS DataBase Reference) |
| FDA UNII | 422VHH19IT |
| NIST Chemistry Reference | Boron trifluoride etherate(109-63-7) |
| EPA Substance Registry System | Boron, trifluoro[1,1'-oxybis[ethane]]-, (T-4)- (109-63-7) |
SAFETY
Risk and Safety Statements
| Symbol(GHS) |     GHS02,GHS05,GHS06,GHS08 |
|||||||||
|---|---|---|---|---|---|---|---|---|---|---|
| Signal word | Danger | |||||||||
| Hazard statements | H226-H302-H314-H330-H372-H412 | |||||||||
| Precautionary statements | P210-P273-P280-P303+P361+P353-P304+P340+P310-P305+P351+P338 | |||||||||
| Hazard Codes | T,C | |||||||||
| Risk Statements | 10-14-20/22-35-48/23-34-14/15-23-22 | |||||||||
| Safety Statements | 16-23-26-36/37/39-45-8-28A-43 | |||||||||
| RIDADR | UN 2604 8/PG 1 | |||||||||
| WGK Germany | 3 | |||||||||
| F | 10 | |||||||||
| Autoignition Temperature | 185 °C DIN 51794 | |||||||||
| TSCA | Yes | |||||||||
| HazardClass | 8 | |||||||||
| PackingGroup | I | |||||||||
| HS Code | 29319090 | |||||||||
| NFPA 704 |
|
Boron trifluoride diethyl etherate price More Price(34)
| Manufacturer | Product number | Product description | CAS number | Packaging | Price | Updated | Buy |
|---|---|---|---|---|---|---|---|
| Sigma-Aldrich | 8.01647 | Boron trifluoride-diethyl ether complex for synthesis | 109-63-7 | 250ML | $46.1 | 2024-03-01 | Buy |
| Sigma-Aldrich | 8.01647 | Boron trifluoride-diethyl ether complex for synthesis | 109-63-7 | 1L | $138 | 2024-03-01 | Buy |
| Sigma-Aldrich | 8.01647 | Boron trifluoride-diethyl ether complex for synthesis | 109-63-7 | 25kg | $1560 | 2024-03-01 | Buy |
| Sigma-Aldrich | 175501 | Boron trifluoride diethyl etherate for synthesis | 109-63-7 | 1l | $128 | 2024-03-01 | Buy |
| Sigma-Aldrich | 175501 | Boron trifluoride diethyl etherate for synthesis | 109-63-7 | 4l | $379 | 2024-03-01 | Buy |
Boron trifluoride diethyl etherate Chemical Properties,Uses,Production
Chemical Properties
Colorless to brown fuming liquid.
uses
Boron trifluoride diethyl etherate is used as a Lewis acid catalyst in Mukaiyama aldol addition, alkylation, acetylation, isomerization, dehydrations and condensation reactions. It is involved in the prepattion of polyethers in polymerization reactions. As a catalyst, it is used in the preparation of cyclopentyl- and cycloheptyl[b]indoles and other diborane. It is also used in sensitive neutron detectors in ionization chambers as well as monitoring radiation levels in earths atmosphere.
Preparation
Boron trifluoride gas, produced by heating the sulfuric acid, calcium fluoride (fluorite) and boric acid together, reacts with ether boron to produce the trifluoride etherate crude product, thus we can refine it to get the finished product. The consumption of raw material is as followed: boric acid (≥98%), 560kg/t; calcium fluoride(≥90%) 1150kg/t; fuming sulfuric acid (104.5%), 4100kg/t; ether(≥99%) 725kg/t.
In absorption method shown in the chemical equations as followed, diethyl ether absorb boron trifluoride gas, produced by heating the sulfuric acid, calcium fluoride (fluorite) and boric acid together, to produce trifluoride etherate crude complex compound by vacuum distillation.
3H2SO4+2H33BO3+3CaF2→2BF3+3CaSO4+6H2O
BF3+(C2H5)2O→(C2H5)2O•BF3
Toxicity
See boron trifluoride.
Chemical Properties
Boron trifluoride etherates: (compounded with methyl ether) is moisture-sensitive, corrosive, flammable liquid.
Physical properties
Fuming liquid; stable at ambient temperatures but hydrolyzed on exposure to moist air; density 1.125 g/mL; refractive index 1.348; solidifies at -60.4°C; boils at 125.7°C; flash point (open cup) 147°F (68.8°C); decomposes in water.
Uses
Boron trifluoride diethyl etherate is used as a Lewis acid catalyst in Mukaiyama aldol addition, alkylation, acetylation, isomerization, dehydrations and condensation reactions. It is involved in the prepattion of polyethers in polymerization reactions. As a catalyst, it is used in the preparation of cyclopentyl- and cycloheptyl[b]indoles and other diborane. It is also used in sensitive neutron detectors in ionization chambers as well as monitoring radiation levels in earth?s atmosphere.
Uses
Catalyst in acetylation, alkylation, polymerization, dehydration, and condensation reactions.
Application
Catalyst in the synthesis of polyol chains. Reagent for the coupling of imines to allylstannanes and 4′-nitrobenzenesulfenanilide to alkenes and alkynes.
Lewis acid reagent with broad application
Catalyst used in the preparation of cyclopentyl- and cycloheptyl[b]indoles from aryl cyclopropyl ketones via [3+2] cycloaddition.
Preparation
Boron trifluoride etherate is prepared by the reaction of vapors of boron trifluoride with that of anhydrous diethyl ether:
BF3 (g) + (C2H5)2O (g) → (C2H5)2O?BF3.
General Description
Boron trifluoride etherate is a fuming liquid. Boron trifluoride etherate may be corrosive to skin, eyes and mucous membranes. Boron trifluoride etherate may be toxic by inhalation. Upon exposure to water Boron trifluoride etherate may emit flammable and corrosive vapors. Boron trifluoride etherate is used as a catalyst in chemical reactions.
Air & Water Reactions
Highly flammable. Fuming liquid, immediately hydrolyzed by moisture in air to form hydrogen fluoride [Merck 11th ed. 1989].
Reactivity Profile
Boron trifluoride diethyl ether complex is a stable, highly flammable, colourless to brown fuming, corrosive liquid with a sharp pungent odour. It forms explosive peroxides in contact with air or oxygen. It reacts exothermically with water to form extremely flammable diethyl ether and toxic, corrosive boron trifluoride hydrates. The chemical is incompatible with bases, amines, and alkali metals. It immediately gets hydrolysed by moisture in air to form hydrogen fluoride. Boron trifluoride diethyl ether has applications in chemical laboratory as a catalyst in chemical reactions.
Hazard
The compound is highly toxic by inhalation. Skin contact causes burns.
Health Hazard
May cause toxic effects if inhaled or ingested/swallowed. Contact with substance may cause severe burns to skin and eyes. Fire will produce irritating, corrosive and/or toxic gases. Vapors may cause dizziness or suffocation. Runoff from fire control or dilution water may cause pollution.
Fire Hazard
Flammable/combustible material. May be ignited by heat, sparks or flames. Vapors may form explosive mixtures with air. Vapors may travel to source of ignition and flash back. Most vapors are heavier than air. They will spread along ground and collect in low or confined areas (sewers, basements, tanks). Vapor explosion hazard indoors, outdoors or in sewers. Runoff to sewer may create fire or explosion hazard. Containers may explode when heated. Many liquids are lighter than water.
Flammability and Explosibility
Flammable
Potential Exposure
Used as a catalyst.
Shipping
Diethyl: UN2604 Boron trifluoride diethyl etherate, Hazard class: 8; Labels: 8—Corrosive material, 3—Flammable liquid. Dimethyl: UN2965 Boron trifluoride dimethyl etherate, Hazard class: 4.3; Labels: 4.3— Dangerous when wet, 8—Corrosive material, 3— Flammable liquid.
Incompatibilities
Reacts with air forming corrosive hydrogen fluoride vapors. Incompatible with oxidizers (may cause fire and explosion), water, steam or heat, forming corrosive and flammable vapors. Peroxide containing etherate reacts explosively with aluminum lithium hydride, magnesium tetrahydroaluminate. Mixtures with phenol react explosively with 1,3-butadiene. Presumed to form explosive peroxides.
Boron trifluoride diethyl etherate Preparation Products And Raw materials
Raw materials
1of2
Preparation Products
1of7
| Supplier | Tel | Country | ProdList | Advantage | |
|---|---|---|---|---|---|
| Hebei Mojin Biotechnology Co., Ltd | +8613288715578 | sales@hbmojin.com | China | 12453 | 58 |
| Capot Chemical Co.,Ltd. | 571-85586718 +8613336195806 | sales@capotchem.com | China | 29797 | 60 |
| Henan Tianfu Chemical Co.,Ltd. | +86-0371-55170693 +86-19937530512 | info@tianfuchem.com | China | 21695 | 55 |
| Hefei TNJ Chemical Industry Co.,Ltd. | +86-0551-65418679 +86-18949832763 | info@tnjchem.com | China | 2989 | 55 |
| career henan chemical co | +86-0371-86658258 | sales@coreychem.com | China | 29914 | 58 |
| SHANDONG ZHI SHANG CHEMICAL CO.LTD | +86 18953170293 | sales@sdzschem.com | China | 2931 | 58 |
| Hubei Jusheng Technology Co.,Ltd. | 18871490254 | linda@hubeijusheng.com | CHINA | 28180 | 58 |
| Jinan Finer Chemical Co., Ltd | +86-531-88989536 +86-15508631887 | sales@finerchem.com | China | 2966 | 58 |
| Hebei Guanlang Biotechnology Co., Ltd. | +86-19930503282 | alice@crovellbio.com | China | 8822 | 58 |
| Xiamen AmoyChem Co., Ltd | +86-592-6051114 +8618959220845 | sales@amoychem.com | China | 6387 | 58 |
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- Nov 25，2019
View Lastest Price from Boron trifluoride diethyl etherate manufacturers
| Image | Update time | Product | Price | Min. Order | Purity | Supply Ability | Manufacturer | |
|---|---|---|---|---|---|---|---|---|
 |
2024-04-19 | Boron trifluoride etherate
109-63-7
|
US $0.00 / kg | 1kg | ≥47% | 200mt/year | Jinan Finer Chemical Co., Ltd | |
 |
2023-11-27 | Boron trifluoride diethyl etherate
109-63-7
|
US $0.00-0.00 / ml | 100ml | 99% | 60L | Wuhan Senwayer Century Chemical Co.,Ltd | |
 |
2023-10-09 | Boron trifluoride diethyl etherate
109-63-7
|
US $0.00 / KG | 1KG | 99% | 50000KG/month | Hebei Mojin Biotechnology Co., Ltd |
-
- Boron trifluoride etherate
109-63-7
- US $0.00 / kg
- ≥47%
- Jinan Finer Chemical Co., Ltd
-
- Boron trifluoride diethyl etherate
109-63-7
- US $0.00-0.00 / ml
- 99%
- Wuhan Senwayer Century Chemical Co.,Ltd
-
- Boron trifluoride diethyl etherate
109-63-7
- US $0.00 / KG
- 99%
- Hebei Mojin Biotechnology Co., Ltd